**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
|----------------|--------------------------------------|----------|-----------|
| 67-63-0 |Isopropyl alcohol | 20.8 | 200-661-7 |
|----------------|--------------------------------------|----------|-----------|
| 71-23-8 |N-propyl alcohol | 20.8 | 200-746-9 |
|----------------|--------------------------------------|----------|-----------|
| 108-11-2 |Methyl isobutyl carbinol | 20.8 | 203-551-7 |
|----------------|--------------------------------------|----------|-----------|
| 111-27-3 |N-hexanol | 20.8 | 203-852-3 |
|----------------|--------------------------------------|----------|-----------|
| 111-70-6 |N-heptyl alcohol | 16.7 | 203-897-9 |
+----------------+--------------------------------------+----------+-----------+
Text for R-phrases: see Section 16
Hazard Symbols: XN
Risk Phrases: 10 21/22 36 37
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Flammable. Harmful in contact with skin and if swallowed. Irritating
to eyes. Irritating to respiratory system.Flammable liquid.
Potential Health Effects
Eye:
May result in corneal injury. Vapors may cause eye irritation.
May cause conjunctivitis. May cause eye irritation and possible
burns.
Skin:
May cause skin sensitization, an allergic reaction, which becomes
evident upon re-exposure to this material. Prolonged and/or repeated
contact may cause defatting of the skin and dermatitis. Causes
symptoms similar to those of inhalation. May be harmful if absorbed
through the skin. Excessive drying of the skin may result from
repeated or prolonged contact. May cause skin irritation and possible
burns.
Ingestion:
Harmful if swallowed. May cause irritation of the digestive tract.
May cause liver and kidney damage. May cause central nervous system
depression, characterized by excitement, followed by headache,
dizziness, drowsiness, and nausea. Advanced stages may cause
collapse, unconsciousness, coma and possible death due to
respiratory failure. May cause effects similar to those for
inhalation exposure.
Inhalation:
Inhalation of high concentrations may cause central nervous system
effects characterized by nausea, headache, dizziness, unconsciousness
and coma. May cause respiratory tract irritation. Irritation may lead
to chemical pneumonitis and pulmonary edema. Aspiration may cause
respiratory swelling and pneumonitis. May cause kidney damage. May
cause drowsiness, unconsciousness, and central nervous system
depression.
Chronic:
Chronic inhalation and ingestion may cause effects similar to those
of acute inhalation and ingestion. Prolonged or repeated skin
contact may cause defatting and dermatitis. May cause allergic skin
reaction in some individuals.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Possible aspiration hazard. Get medical aid
immediately.
Inhalation:
Remove from exposure and move to fresh air immediately. If breathing
is difficult, give oxygen. Get medical aid. Do NOT use mouth-to-mouth
resuscitation. If breathing has ceased apply artificial respiration
using oxygen and a suitable mechanical device such as a bag and a
mask.
Notes to Physician:
Urine acetone test may be helpful in diagnosis. Treat
symptomatically and supportively.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
Containers can build up pressure if exposed to heat and/or fire. As
in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Vapors may form an explosive mixture with air.
Combustion generates toxic fumes. During a fire, irritating and
highly toxic gases may be generated by thermal decomposition or
combustion. Will burn if involved in a fire. Use water spray to keep
fire-exposed containers cool. Flammable liquid and vapor. May form
explosive peroxides. Containers may explode when heated.
Extinguishing Media:
Use water spray to cool fire-exposed containers. Water may be
ineffective. Use agent most appropriate to extinguish fire. Cool
containers with flooding quantities of water until well after fire is
out.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Clean up spills immediately, observing precautions in the Protective
Equipment section. Remove all sources of ignition. Absorb spill using
an absorbent, non-combustible material such as earth, sand, or
vermiculite. Do not use combustible materials such as sawdust. Use a
spark-proof tool. Provide ventilation. A vapor suppressing foam may
be used to reduce vapors. Water spray may reduce vapor but may not
prevent ignition in closed spaces.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use only in a well-ventilated area. Ground and
bond containers when transferring material. Use spark-proof tools and
explosion proof equipment. Avoid contact with eyes, skin, and
clothing. Empty containers retain product residue, (liquid and/or
vapor), and can be dangerous. Keep container tightly closed. Keep
away from heat, sparks and flame. Avoid ingestion and inhalation. Do
not pressurize, cut, weld, braze, solder, drill, grind, or expose
empty containers to heat, sparks or open flames.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of
ignition. Keep container closed when not in use. Store in a tightly
closed container. Store in a cool, dry, well-ventilated area away
from incompatible substances. Flammables-area.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate general or
local explosion-proof ventilation to keep airborne levels to
acceptable levels.
Personal Protective Equipment
Eyes:
Wear safety glasses and chemical goggles if splashing
is possible. Wear appropriate protective eyeglasses or
chemical safety goggles as described by OSHA's eye and
face protection regulations in 29 CFR 1910.133 or
European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant a respirator's use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: colorless
Odor: alcohol-like
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: Alcohol Blend
Molecular Weight:
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures. This material may be
sensitive to peroxide formation.
Conditions to Avoid:
High temperatures, mechanical shock, incompatible materials, ignition
sources, excess heat, strong oxidants.
Incompatibilities with Other Materials:
Acids (mineral, non-oxidizing, e.g. hydrochloric acid, hydrofluoric
acid, muriatic acid, phosphoric acid), acids (mineral, oxidizing,
e.g. chromic acid, hypochlorous acid, nitric acid, sulfuric acid),
acids (organic, e.g. acetic acid, benzoic acid, formic acid,
methanoic acid, oxalic acid), azo, diazo, and hydrazines (e.g.
dimethyl hydrazine, hydrazine, methyl hydrazine), isocyanates (e.g.
methyl isocyanate), metals (alkali and alkaline, e.g. cesium,
potassium, sodium), nitrides (e.g. potassium nitride, sodium
nitride), peroxides and hydroperoxides (organic, e.g. acetyl
peroxide, benzoyl peroxide, butyl peroxide, methyl ethyl ketone
peroxide), epoxides (e.g. butyl glycidyl ether), oxidizing agents
(strong, e.g. bromine, hydrogen peroxide, nitrogen dioxide,
potassium nitrate), reducing agents (strong, e.g. aluminum carbide,
chlorosilane, hydrogen phosphide, lithium hydride), water reactive
substances (e.g. acetic anyhdride, alkyl aluminum chloride, calcium
carbide, ethyl dichlorosilane).
Hazardous Decomposition Products:
Carbon monoxide, irritating and toxic fumes and gases, carbon
dioxide.
Hazardous Polymerization: Has not been reported
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 67-63-0: NT8050000
CAS# 71-23-8: UH8225000
CAS# 108-11-2: SA7350000
CAS# 111-27-3: MQ4025000
CAS# 111-70-6: MK0350000
LD50/LC50:
CAS# 67-63-0: Draize test, rabbit, eye: 100 mg Severe; Draize test,
rabbit, eye: 10 mg Moderate; Draize test, rabbit, eye: 100 mg/24H
Moderate; Draize test, rabbit, skin: 500 mg Mild; Inhalation, mouse:
LC50 = 53000 mg/m3; Inhalation, rat: LC50 = 16000 ppm/8H; Inhalation,
rat: LC50 = 72600 mg/m3; Oral, mouse: LD50 = 3600 mg/kg; Oral, mouse:
LD50 = 3600 mg/kg; Oral, rabbit: LD50 = 6410 mg/kg; Oral, rat: LD50 =
5045 mg/kg; Oral, rat: LD50 = 5000 mg/kg; Skin, rabbit: LD50 = 12800
mg/kg.
CAS# 71-23-8: Draize test, rabbit, eye: 20 mg/24H Moderate;
Inhalation, mouse: LC50 = 48 gm/m3; Inhalation, mouse: LC50 = 48000
mg/m3; Oral, mouse: LD50 = 6800 mg/kg; Oral, rabbit: LD50 = 2825
mg/kg; Oral, rat: LD50 = 1870 mg/kg; Oral, rat: LD50 = 2200 mg/kg;
Skin, rabbit: LD50 = 5040 mg/kg.
CAS# 108-11-2: Oral, rat: LD50 = 2590 mg/kg; Skin, rabbit: LD50 =
3560 uL/kg.
CAS# 111-27-3: Oral, mouse: LD50 = 1950 mg/kg; Oral, mouse: LD50 =
1950 mg/kg; Oral, rat: LD50 = 720 mg/kg; Oral, rat: LD50 = 710 mg/kg;
Skin, rabbit: LD50 = 3100 uL/kg.
CAS# 111-70-6: Inhalation, mouse: LC50 = 6600 mg/m3/2H; Inhalation,
mouse: LC50 = 6000 mg/kg/2H; Oral, mouse: LD50 = 1500 mg/kg; Oral,
mouse: LD50 = 6000 mg/kg; Oral, rabbit: LD50 = 750 mg/kg; Oral, rat:
LD50 = 500 mg/kg; Oral, rat: LD50 = 3800 mg/kg; Skin, rabbit: LD50 =
2 gm/kg.
Carcinogenicity:
Isopropyl alcohol -
Not listed by ACGIH, IARC, or NTP.
N-propyl alcohol -
ACGIH: A3 - Confirmed animal carcinogen with unknown relevance to
Methyl isobutyl carbinol -
Not listed by ACGIH, IARC, or NTP.
N-hexanol -
Not listed by ACGIH, IARC, or NTP.
N-heptyl alcohol -
Not listed by ACGIH, IARC, or NTP.
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Other
No information available.
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
No information available.
IMO
No information available.
RID/ADR
No information available.
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 10 Flammable.
R 21/22 Harmful in contact with skin and if
swallowed.
R 36 Irritating to eyes.
R 37 Irritating to respiratory system.
Safety Phrases:
S 7 Keep container tightly closed.
S 16 Keep away from sources of ignition - No
smoking.
S 24/25 Avoid contact with skin and eyes.
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
WGK (Water Danger/Protection)
CAS# 67-63-0: 1
CAS# 71-23-8: 1
CAS# 108-11-2: 1
CAS# 111-27-3: 1
CAS# 111-70-6: 1
United Kingdom Occupational Exposure Limits
CAS# 67-63-0: OES-United Kingdom, TWA 400 ppm TWA; 999 mg/m3 TWA
CAS# 67-63-0: OES-United Kingdom, STEL 500 ppm STEL; 1250 mg/m3 STEL
CAS# 71-23-8: OES-United Kingdom, TWA 200 ppm TWA; 500 mg/m3 TWA
CAS# 71-23-8: OES-United Kingdom, STEL 250 ppm STEL; 625 mg/m3 STEL
CAS# 108-11-2: OES-United Kingdom, TWA 25 ppm TWA; 106 mg/m3 TWA
CAS# 108-11-2: OES-United Kingdom, STEL 40 ppm STEL; 170 mg/m3 STEL
CAS# 108-11-2: OES-United Kingdom, STEL 40 ppm STEL; 170 mg/m3 STEL
United Kingdom Maximum Exposure Limits
Canada
CAS# 67-63-0 is listed on Canada's DSL List.
CAS# 71-23-8 is listed on Canada's DSL List.
CAS# 108-11-2 is listed on Canada's DSL List.
CAS# 111-27-3 is listed on Canada's DSL List.
CAS# 111-70-6 is listed on Canada's DSL List.
CAS# 67-63-0 is listed on Canada's Ingredient Disclosure List.
CAS# 71-23-8 is listed on Canada's Ingredient Disclosure List.
CAS# 108-11-2 is listed on Canada's Ingredient Disclosure List.
CAS# 111-27-3 is listed on Canada's Ingredient Disclosure List.
CAS# 111-70-6 is not listed on Canada's Ingredient Disclosure List.
Exposure Limits
CAS# 67-63-0: OEL-AUSTRALIA:TWA 400 ppm (980 mg/m3);STEL 500 ppm (1225
mg/m3)
OEL-BELGIUM:TWA 400 ppm (985 mg/m3);STEL 500 ppm (1230 mg/m3)
OEL-DENMARK:TWA 200 ppm (490 mg/m3);Skin
OEL-FRANCE:STEL 400 ppm (980 mg/m3)
OEL-GERMANY:TWA 400 ppm (980 mg/m3)
OEL-JAPAN:STEL 400 ppm (980 mg/m3)
OEL-THE NETHERLANDS:TWA 400 ppm (980 mg/m3);Skin
OEL-THE PHILIPPINES:TWA 400 ppm (980 mg/m3)
OEL-RUSSIA:STEL 400 ppm (10 mg/m3)
OEL-SWEDEN:TWA 150 ppm (350 mg/m3);STEL 250 ppm (600 mg/m3)
OEL-SWITZERLAND:TWA 400 ppm (980 mg/m3);STEL 800 ppm
OEL-TURKEY:TWA 200 ppm (500 mg/m3)
OEL-UNITED KINGDOM:TWA 400 ppm (980 mg/m3);STEL 500 ppm;Skin
OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV
OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGI TLV
CAS# 71-23-8: OEL-AUSTRALIA:TWA 200 ppm (500 mg/m3);STEL 250 ppm;Skin
CAS# 108-11-2: OEL-AUSTRALIA:TWA 25 ppm (100 mg/m3);STEL 40 ppm;Skin
OEL-BELGIUM:TWA 25 ppm (104 mg/m3);STEL 40 ppm (166 mg/m3);Skin
OEL-DENMARK:TWA 25 ppm (100 mg/m3);Skin
OEL-FINLAND:TWA 25 ppm (100 mg/m3);STEL 40 ppm (170 mg/m3);Skin
OEL-FRANCE:TWA 25 ppm (100 mg/m3);Skin
OEL-GERMANY:TWA 25 ppm (100 mg/m3);Skin
OEL-RUSSIA:STEL 10 mg/m3;Skin
OEL-SWITZERLAND:TWA 25 ppm (100 mg/m3);STEL 125 ppm;Skin
OEL-UNITED KINGDOM:TWA 25 ppm (100 mg/m3);STEL 40 ppm;Skin
OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV
OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGI TLV
CAS# 111-70-6: OEL-RUSSIA:STEL 10 mg/m3;Skin
US FEDERAL
TSCA
CAS# 67-63-0 is listed on the TSCA inventory.
CAS# 71-23-8 is listed on the TSCA inventory.
CAS# 108-11-2 is listed on the TSCA inventory.
CAS# 111-27-3 is listed on the TSCA inventory.
CAS# 111-70-6 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/08/1999 Revision #5 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
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