**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 100-14-1 |Benzene, 1-(chloromethyl)-4-nitro- | 99 | 202-822-7 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XI
Risk Phrases: 36/37/38
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Irritating to eyes, respiratory system and skin.Lachrymator
(substance which increases the flow of tears).
Potential Health Effects
Eye:
Causes eye irritation. Lachrymator (substance which increases the
flow of tears). May cause chemical conjunctivitis.
Skin:
Causes skin irritation.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea.
Inhalation:
Causes respiratory tract irritation. Can produce delayed pulmonary
edema. Inhalation may produce burning sensation, coughing, wheezing,
laryngitis, shortness of breath, headache, nausea, and vomiting.
Chronic:
Effects may be delayed.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and
drink 2-4 cupfuls of milk or water.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen.
Notes to Physician:
Treat symptomatically and supportively.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Water
hydrolyzes material liberating acidic gas which in contact with metal
surfaces can generate flammable and/or explosive hydrogen gas.
Extinguishing Media:
DO NOT USE WATER! Use water spray, dry chemical, carbon dioxide, or
appropriate foam. In case of fire, use carbon dioxide, dry chemical
powder or appropriate foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Clean up spills immediately, observing precautions in the Protective
Equipment section. Cover with sand, dry lime or soda ash and place in
a closed container for disposal. Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Keep container tightly closed. Do not get on skin or in eyes. Do not
ingest or inhale. Use with adequate ventilation. Use only in a
chemical fume hood. Wash clothing before reuse. Discard contaminated
shoes.
Storage:
Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 100-14-1:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Crystals
Color: slightly yellow
Odor: None reported.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 70.00 - 73.00 deg C
Autoignition Temperature: Not applicable.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: Not available.
Solubility in water: insoluble
Specific Gravity/Density: Not available.
Molecular Formula: C7H6ClNO2
Molecular Weight: 171.58
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable, however, may violently decompose at temperatures above
125C.
Conditions to Avoid:
Incompatible materials, moisture, metals, excess heat, oxidizers,
amines, bases.
Incompatibilities with Other Materials:
Oxidizing agents, bases, alcohols, amines, steel, moisture.
Hazardous Decomposition Products:
Hydrogen chloride, nitrogen oxides, carbon monoxide, carbon dioxide,
chloride fumes.
Hazardous Polymerization: Has not been reported
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 100-14-1: XS9093000
LD50/LC50:
CAS# 100-14-1: Oral, rat: LD50 = 1809 mg/kg.
LD50: Oral, rat = 1809
Carcinogenicity:
Benzene, 1-(chloromethyl)-4-nitro- -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: TOXIC SOLID, ORGANIC, N.O.S.*
Hazard Class: 6.1
UN Number: 2811
Packing Group: II
IMO
Shipping Name: TOXIC SOLID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2811
Packing Group: II
RID/ADR
Shipping Name: TOXIC SOLID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2811
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI
Risk Phrases:
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
WGK (Water Danger/Protection)
CAS# 100-14-1: No information available.
Canada
CAS# 100-14-1 is listed on Canada's NDSL List.
CAS# 100-14-1 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 100-14-1 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 6/10/1999 Revision #4 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
L-Epicatechin, Mixture of ca.60% (-)-Epicatechin and ca.40% Catechin
| 490-46-0 |
|
2,4,6-Tri-2-Pyridyl-S-Triazine, 99%
| 3682-35-7 |
|
Oxalacetic acid, 96%
| 328-42-7 |
|
Nile Blue Hydrochloride
| 2381-85-3 |
|
Dimethylsulfamoyl Chloride, 97%
| 13360-57-1 |
|
Adenine Sulfate 98%
| 321-30-2 |
|
3,3'-Diethylthiatricarbocyanine Iodide
| 3071-70-3 |
|
7-Chlortetracycline Monohydrochloride, Potency 900 mu/mg
| 64-72-2 |
|
4-Aminobenzoic Acid, Sodium Salt, 99%
| 555-06-6 |
|
Sodium Thiocarbonate (40% in Water)
| 534-18-9 |
|
n-Acetyl-s-benzyl-l-cysteine
| 19542-77-9 |
|
3-Hydroxypropionitrile, 98%
| 109-78-4 |
|
2-Ethylhexanoic acid, 99%
| 149-57-5 |
|
Trans,Trans-1,4-Diphenyl-1,3-Butadiene, 99%
| 886-65-7 |
|
Benzyl chloride, stabilized, 99.5+% (with 0.25% propylene oxide)
| 75-56-9 |
|
Benzyl chloride, pract., 90%
| 100-44-7 |
|
Azure b, high purity biological stain
| 531-55-5 |
|
4-Amino-3-Hydroxy-1-Naphthalenesulfonic Acid, 95%
| 116-63-2 |
|
2-Bromoethylamine Hydrobromide, 99%
| 2576-47-8 |
|
2-Nitrophenol, 99%
| 88-75-5 |
|
Diethoxydimethylsilane, 97%
| 78-62-6 |
|
Calcium sulfate, anhydrous, 99%
| 7778-18-9 |
|
Drierite, 6 mesh, without indicator
| 7778-18-9 |
|
Drierite, 8 mesh, without indicator
| 7778-18-9 |
|
Drierite, 10-20 mesh, without indicator
| 7778-18-9 |
|
Drierite, 20-40 mesh, without indicator
| 7778-18-9 |
|
Drierite, 4 mesh, with indicator
| 7778-18-9 |
|
Drierite, 8 mesh, with indicator
| 7778-18-9 |
|
Drierite, 20-40 mesh, with indicator
| 7778-18-9 |
|
4,4,4-Trifluoro-1-phenyl-1,3-butanedione, 99%
| 326-06-7 |
|
2-Bromoethanesulfonic Acid, Sodium Salt, 98%
| 4263-52-9 |
|
Sodium 4-Nitrophenoxide, Hydrate, 98% (On Dry Basis)
| 824-78-2 |
|
2-Octylamine
| 693-16-3 |
|
4-Nitrobenzyl chloride, 99%
| 100-14-1 |
|
Palmitic Acid, 98% (GC)
| 57-10-3 |
|
n-Butyllithium, 1.6M solution in hexanes
| 109-72-8 |
|
n-Butyllithium (15% in heptane)
| 109-72-8 |
|
Barium Fluoride, 99.99%
| 7787-32-8 |
|
Decanoic Acid (Capric Acid), 96%
| 334-48-5 |
|
trans-4-Butyl-alpha-chloro-4'-etoxystilben 99+%
| 54513-47-2 |
|
Cyclohexanepropionic Acid, 99%
| 701-97-3 |
|
Carbon tetrachloride, 99%
| 56-23-5 |
|
Carbon Tetrachloride, P.A.
| 56-23-5 |
|
Carbon Tetrachloride, Low Absorbance at 2900 to 3050 cm-1
| 56-23-5 |
|
Lauric Acid, 95%
| 143-07-7 |
|
N,N,N',N'-Tetraethylethylenediamine
| 150-77-6 |
|
Phenyl chloroformate, 99% (gc)
| 1885-14-9 |
|
Methyl-p-benzoquinone, 99+%
| 553-97-9 |
|
1-Phenylpiperazine, 97%
| 92-54-6 |
|
3,4-Dimercaptotoluene, 99%
| 496-74-2 |
|
|