**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 1885-14-9 |Phenyl chloroformate | 97 | 217-547-8 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: T+ C
Risk Phrases: 26 34 38
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Very toxic by inhalation. Causes burns. Irritating to skin.Moisture
sensitive.Corrosive.
Potential Health Effects
Eye:
Causes eye burns.
Skin:
Causes skin burns.
Ingestion:
May cause severe and permanent damage to the digestive tract. May be
harmful if swallowed. Causes digestive tract irritation with possible
burns.
Inhalation:
Causes respiratory tract irritation with possible burns.
Chronic:
No information found.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately. Do NOT allow victim to rub eyes or keep eyes closed.
Extensive irrigation with water is required (at least 30 minutes).
Skin:
Get medical aid immediately. Flush skin with plenty of water for at
least 15 minutes while removing contaminated clothing and shoes.
Wash clothing before reuse. Destroy contaminated shoes.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid immediately. May cause
methemoglobinemia, cyanosis (bluish discoloration of skin due to
deficient oxygenation of the blood), convulsions, and death.
Inhalation:
Remove from exposure and move to fresh air immediately. If breathing
is difficult, give oxygen. Get medical aid. Do NOT use mouth-to-mouth
resuscitation. If breathing has ceased apply artificial respiration
using oxygen and a suitable mechanical device such as a bag and a
mask.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Vapors can travel to a source of ignition and flash
back. During a fire, irritating and highly toxic gases may be
generated by thermal decomposition or combustion. Use water spray to
keep fire-exposed containers cool. Combustible liquid. Vapors may be
heavier than air. They can spread along the ground and collect in
low or confined areas. Contact with metals may evolve flammable
hydrogen gas. Substance may react with water, and may release
corrosive and/or toxic gases. Containers may explode when heated.
Extinguishing Media:
For large fires, use water spray, fog, or alcohol-resistant foam. Do
NOT use water directly on fire. Use water spray to cool fire-exposed
containers. Do NOT use straight streams of water. For small fires,
use carbon dioxide, dry chemical, dry sand, or alcohol-resistant
foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Avoid runoff into storm sewers and ditches which lead to waterways.
Clean up spills immediately, observing precautions in the Protective
Equipment section. Remove all sources of ignition. Use a spark-proof
tool. Provide ventilation. A vapor suppressing foam may be used to
reduce vapors. Cover with dry earth, dry sand, or other
non-combustible material followed with plastic sheet to minimize
spreading and contact with water.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Do not get in eyes, on skin, or on
clothing. Empty containers retain product residue, (liquid and/or
vapor), and can be dangerous. Keep container tightly closed. Keep
away from heat, sparks and flame. Do not ingest or inhale. Use with
adequate ventilation. Discard contaminated shoes. Do not pressurize,
cut, weld, braze, solder, drill, grind, or expose empty containers
to heat, sparks or open flames.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of
ignition. Keep container closed when not in use. Store in a tightly
closed container. Store in a cool, dry, well-ventilated area away
from incompatible substances. Keep refrigerated. (Store below
4C/39F.)
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 1885-14-9:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: clear colorless to faint colored
Odor: None reported.
pH: Not available.
Vapor Pressure: 20 mmHg @ 83 C
Viscosity: Not available.
Boiling Point: 74.0 - 75.0 deg C
Freezing/Melting Point: Not available.
Autoignition Temperature: 560 deg C ( 1,040.00 deg F)
Flash Point: 69 deg C ( 156.20 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: decomposes
Specific Gravity/Density: 1.2480g/cm3
Molecular Formula: C7H5ClO2
Molecular Weight: 156.57
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures. May decompose on
exposure to moist air or water.
Conditions to Avoid:
Incompatible materials, ignition sources, moisture, excess heat.
Incompatibilities with Other Materials:
Oxidizing agents, strong bases, bases, alcohols, amines.
Hazardous Decomposition Products:
Hydrogen chloride, phosgene, carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 1885-14-9: FG3850000
LD50/LC50:
CAS# 1885-14-9: Draize test, rabbit, eye: 50 ug/24H Severe; Draize
test, rabbit, skin: 500 mg/24H Mild; Oral, rat: LD50 = 1410 uL/kg;
Skin, rabbit: LD50 = 3970 uL/kg.
Oral,Rat: LD50 = 1410 mg/kg
mg/kg
Carcinogenicity:
Phenyl chloroformate -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: PHENYL CHLOROFORMATE
Hazard Class: 6.1 (8)
UN Number: 2746
Packing Group: II
IMO
Shipping Name: PHENYL CHLOROFORMATE
Hazard Class: 6.1 (8)
UN Number: 2746
Packing Group: II
RID/ADR
Shipping Name: PHENYL CHLOROFORMATE
Hazard Class: 6.1
UN Number: 2746
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T+ C
Risk Phrases:
R 26 Very toxic by inhalation.
R 34 Causes burns.
R 38 Irritating to skin.
Safety Phrases:
S 33 Take precautionary measures against static
discharges.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 1885-14-9: 2
Canada
CAS# 1885-14-9 is listed on Canada's DSL List.
CAS# 1885-14-9 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 1885-14-9 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 10/08/1998 Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
L-Epicatechin, Mixture of ca.60% (-)-Epicatechin and ca.40% Catechin
| 490-46-0 |
|
2,4,6-Tri-2-Pyridyl-S-Triazine, 99%
| 3682-35-7 |
|
Oxalacetic acid, 96%
| 328-42-7 |
|
Nile Blue Hydrochloride
| 2381-85-3 |
|
Dimethylsulfamoyl Chloride, 97%
| 13360-57-1 |
|
Adenine Sulfate 98%
| 321-30-2 |
|
3,3'-Diethylthiatricarbocyanine Iodide
| 3071-70-3 |
|
7-Chlortetracycline Monohydrochloride, Potency 900 mu/mg
| 64-72-2 |
|
4-Aminobenzoic Acid, Sodium Salt, 99%
| 555-06-6 |
|
Sodium Thiocarbonate (40% in Water)
| 534-18-9 |
|
n-Acetyl-s-benzyl-l-cysteine
| 19542-77-9 |
|
3-Hydroxypropionitrile, 98%
| 109-78-4 |
|
2-Ethylhexanoic acid, 99%
| 149-57-5 |
|
Trans,Trans-1,4-Diphenyl-1,3-Butadiene, 99%
| 886-65-7 |
|
Benzyl chloride, stabilized, 99.5+% (with 0.25% propylene oxide)
| 75-56-9 |
|
Benzyl chloride, pract., 90%
| 100-44-7 |
|
Azure b, high purity biological stain
| 531-55-5 |
|
4-Amino-3-Hydroxy-1-Naphthalenesulfonic Acid, 95%
| 116-63-2 |
|
2-Bromoethylamine Hydrobromide, 99%
| 2576-47-8 |
|
2-Nitrophenol, 99%
| 88-75-5 |
|
Diethoxydimethylsilane, 97%
| 78-62-6 |
|
Calcium sulfate, anhydrous, 99%
| 7778-18-9 |
|
Drierite, 6 mesh, without indicator
| 7778-18-9 |
|
Drierite, 8 mesh, without indicator
| 7778-18-9 |
|
Drierite, 10-20 mesh, without indicator
| 7778-18-9 |
|
Drierite, 20-40 mesh, without indicator
| 7778-18-9 |
|
Drierite, 4 mesh, with indicator
| 7778-18-9 |
|
Drierite, 8 mesh, with indicator
| 7778-18-9 |
|
Drierite, 20-40 mesh, with indicator
| 7778-18-9 |
|
4,4,4-Trifluoro-1-phenyl-1,3-butanedione, 99%
| 326-06-7 |
|
2-Bromoethanesulfonic Acid, Sodium Salt, 98%
| 4263-52-9 |
|
Sodium 4-Nitrophenoxide, Hydrate, 98% (On Dry Basis)
| 824-78-2 |
|
2-Octylamine
| 693-16-3 |
|
4-Nitrobenzyl chloride, 99%
| 100-14-1 |
|
Palmitic Acid, 98% (GC)
| 57-10-3 |
|
n-Butyllithium, 1.6M solution in hexanes
| 109-72-8 |
|
n-Butyllithium (15% in heptane)
| 109-72-8 |
|
Barium Fluoride, 99.99%
| 7787-32-8 |
|
Decanoic Acid (Capric Acid), 96%
| 334-48-5 |
|
trans-4-Butyl-alpha-chloro-4'-etoxystilben 99+%
| 54513-47-2 |
|
Cyclohexanepropionic Acid, 99%
| 701-97-3 |
|
Carbon tetrachloride, 99%
| 56-23-5 |
|
Carbon Tetrachloride, P.A.
| 56-23-5 |
|
Carbon Tetrachloride, Low Absorbance at 2900 to 3050 cm-1
| 56-23-5 |
|
Lauric Acid, 95%
| 143-07-7 |
|
N,N,N',N'-Tetraethylethylenediamine
| 150-77-6 |
|
Phenyl chloroformate, 99% (gc)
| 1885-14-9 |
|
Methyl-p-benzoquinone, 99+%
| 553-97-9 |
|
1-Phenylpiperazine, 97%
| 92-54-6 |
|
3,4-Dimercaptotoluene, 99%
| 496-74-2 |
|
|