**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 88-75-5 |2-Nitrophenol | 98 | 201-857-5 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN
Risk Phrases: 20/21/22 33
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful by inhalation, in contact with skin and if swallowed. Danger
of cumulative effects.
Potential Health Effects
Eye:
Causes eye irritation and possible burns.
Skin:
Causes skin irritation. May be absorbed through the skin.
Ingestion:
Harmful if swallowed. May cause irritation of the digestive tract.
Inhalation:
Causes respiratory tract irritation.
Chronic:
Absorption into the body leads to the formation of methemoglobin
which in sufficient concentrations causes cyanosis (bluish
discoloration of skin due to deficient oxygenation of the blood).
Kidney, lung and central nervous system effects may also occur.
Chronic ingestion or inhalation may cause headache, drowsiness, blue
color in the lips, ear, and fingernails.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Immediately flush skin with plenty of water for at
least 15 minutes while removing contaminated clothing and shoes.
Wash clothing before reuse.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If breathing is difficult, give oxygen. Do NOT use
mouth-to-mouth resuscitation. If breathing has ceased apply
artificial respiration using oxygen and a suitable mechanical device
such as a bag and a mask.
Notes to Physician:
Effects may be delayed. Absorption of this product into the body may
cause cyanosis (bluish discoloration of skin due to deficient
oxygenation of the blood). Moderate degrees of cyanosis need to be
treated only by supportive measures: bed rest and oxygen inhalation.
For methemoglobinemia, administer oxygen alone or with Methylene Blue
depending on the methemoglobin concentration in the blood. Ingestion
of large quantities of this material can depress the central nervous
system. Stimulants may be useful in certain situations; however, a
professional decision is required.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion.
Extinguishing Media:
Use agent most appropriate to extinguish fire. Do NOT get water
inside containers. Use water fog, dry chemical, carbon dioxide or
alcohol type foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Avoid runoff into storm sewers and ditches which lead to waterways.
Clean up spills immediately, observing precautions in the Protective
Equipment section. Sweep up, then place into a suitable container for
disposal. Avoid generating dusty conditions. Provide ventilation. Do
not get water inside containers. Stop leak only if you can do so
without risk.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Remove contaminated clothing and wash before reuse. Use only in a
well-ventilated area. Minimize dust generation and accumulation.
Avoid contact with eyes, skin, and clothing. Keep container tightly
closed. Keep away from heat, sparks and flame. Do not ingest or
inhale.
Storage:
Keep away from heat, sparks, and flame. Store in a tightly closed
container. Store in a cool, dry, well-ventilated area away from
incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 88-75-5:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Needles
Color: light yellow
Odor: aromatic odor
pH: 5.0 - 7.0
Vapor Pressure: 1 mm Hg @49.3 C
Viscosity: Not available.
Boiling Point: 214.6 deg C @ 760.00mm Hg
Freezing/Melting Point: 44 deg C
Autoignition Temperature: 485 deg C ( 905.00 deg F)
Flash Point: 102 deg C ( 215.60 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: Soluble in hot water.
Specific Gravity/Density:
Molecular Formula: C6H5NO3
Molecular Weight: 139.11
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Volatile in steam. Reacts violently with potassium hydroxide.
Conditions to Avoid:
Incompatible materials, dust generation, excess heat, oxidizers,
steam.
Incompatibilities with Other Materials:
Potassium hydroxide, strong oxidizing agents, strong bases.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, carbon dioxide, nitrogen.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 88-75-5: SM2100000
LD50/LC50:
CAS# 88-75-5: Oral, mouse: LD50 = 1297 mg/kg; Oral, rat: LD50 = 334
mg/kg; Skin, rabbit: LD50 = >7940 mg/kg.
Carcinogenicity:
2-Nitrophenol -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Ecotoxicity:
Fish: Bluegill/Sunfish: 46.3-67 mg/L; 24-48 Hr; TLmDaphnia: Shrimp:
210,000 ug/L; 24 Hr; LC50Estimated BCF value = 14. This value
suggests that there is little tendency for 2-Nitrophenol to
bioconcentrate in fish.
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: NITROPHENOLS
Hazard Class: 6.1
UN Number: 1663
Packing Group: III
IMO
Shipping Name: NITROPHENOLS (O-, M-, P-)
Hazard Class: 6.1
UN Number: 1663
Packing Group: III
RID/ADR
Shipping Name: NITROPHENOLS
Hazard Class: 6.1
UN Number: 1663
Packing group: III
USA RQ: CAS# 88-75-5: 100 lb final RQ (Listed under Nitrophenol, mixed); 45.4 kg
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 20/21/22 Harmful by inhalation, in contact with
skin and if swallowed.
R 33 Danger of cumulative effects.
Safety Phrases:
S 28A After contact with skin, wash immediately with
plenty of water.
WGK (Water Danger/Protection)
CAS# 88-75-5: 2
Canada
CAS# 88-75-5 is listed on Canada's DSL List.
CAS# 88-75-5 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 88-75-5 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 1/29/1999 Revision #3 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
L-Epicatechin, Mixture of ca.60% (-)-Epicatechin and ca.40% Catechin
| 490-46-0 |
|
2,4,6-Tri-2-Pyridyl-S-Triazine, 99%
| 3682-35-7 |
|
Oxalacetic acid, 96%
| 328-42-7 |
|
Nile Blue Hydrochloride
| 2381-85-3 |
|
Dimethylsulfamoyl Chloride, 97%
| 13360-57-1 |
|
Adenine Sulfate 98%
| 321-30-2 |
|
3,3'-Diethylthiatricarbocyanine Iodide
| 3071-70-3 |
|
7-Chlortetracycline Monohydrochloride, Potency 900 mu/mg
| 64-72-2 |
|
4-Aminobenzoic Acid, Sodium Salt, 99%
| 555-06-6 |
|
Sodium Thiocarbonate (40% in Water)
| 534-18-9 |
|
n-Acetyl-s-benzyl-l-cysteine
| 19542-77-9 |
|
3-Hydroxypropionitrile, 98%
| 109-78-4 |
|
2-Ethylhexanoic acid, 99%
| 149-57-5 |
|
Trans,Trans-1,4-Diphenyl-1,3-Butadiene, 99%
| 886-65-7 |
|
Benzyl chloride, stabilized, 99.5+% (with 0.25% propylene oxide)
| 75-56-9 |
|
Benzyl chloride, pract., 90%
| 100-44-7 |
|
Azure b, high purity biological stain
| 531-55-5 |
|
4-Amino-3-Hydroxy-1-Naphthalenesulfonic Acid, 95%
| 116-63-2 |
|
2-Bromoethylamine Hydrobromide, 99%
| 2576-47-8 |
|
2-Nitrophenol, 99%
| 88-75-5 |
|
Diethoxydimethylsilane, 97%
| 78-62-6 |
|
Calcium sulfate, anhydrous, 99%
| 7778-18-9 |
|
Drierite, 6 mesh, without indicator
| 7778-18-9 |
|
Drierite, 8 mesh, without indicator
| 7778-18-9 |
|
Drierite, 10-20 mesh, without indicator
| 7778-18-9 |
|
Drierite, 20-40 mesh, without indicator
| 7778-18-9 |
|
Drierite, 4 mesh, with indicator
| 7778-18-9 |
|
Drierite, 8 mesh, with indicator
| 7778-18-9 |
|
Drierite, 20-40 mesh, with indicator
| 7778-18-9 |
|
4,4,4-Trifluoro-1-phenyl-1,3-butanedione, 99%
| 326-06-7 |
|
2-Bromoethanesulfonic Acid, Sodium Salt, 98%
| 4263-52-9 |
|
Sodium 4-Nitrophenoxide, Hydrate, 98% (On Dry Basis)
| 824-78-2 |
|
2-Octylamine
| 693-16-3 |
|
4-Nitrobenzyl chloride, 99%
| 100-14-1 |
|
Palmitic Acid, 98% (GC)
| 57-10-3 |
|
n-Butyllithium, 1.6M solution in hexanes
| 109-72-8 |
|
n-Butyllithium (15% in heptane)
| 109-72-8 |
|
Barium Fluoride, 99.99%
| 7787-32-8 |
|
Decanoic Acid (Capric Acid), 96%
| 334-48-5 |
|
trans-4-Butyl-alpha-chloro-4'-etoxystilben 99+%
| 54513-47-2 |
|
Cyclohexanepropionic Acid, 99%
| 701-97-3 |
|
Carbon tetrachloride, 99%
| 56-23-5 |
|
Carbon Tetrachloride, P.A.
| 56-23-5 |
|
Carbon Tetrachloride, Low Absorbance at 2900 to 3050 cm-1
| 56-23-5 |
|
Lauric Acid, 95%
| 143-07-7 |
|
N,N,N',N'-Tetraethylethylenediamine
| 150-77-6 |
|
Phenyl chloroformate, 99% (gc)
| 1885-14-9 |
|
Methyl-p-benzoquinone, 99+%
| 553-97-9 |
|
1-Phenylpiperazine, 97%
| 92-54-6 |
|
3,4-Dimercaptotoluene, 99%
| 496-74-2 |
|
|