**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
|----------------|--------------------------------------|----------|-----------|
| 75-56-9 |Propylene oxide | 0.25 | 200-879-2
|----------------|--------------------------------------|----------|-----------|
| 100-44-7 |Benzyl chloride | > 99.5 | 202-853-6
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: T
Risk Phrases: 22 23 37/38 41 45 48/22
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful if swallowed. Toxic by inhalation. Irritating to respiratory
system and skin. Risk of serious damage to eyes. May cause cancer.
Harmful : danger of serious damage to health by prolonged exposure
if swallowed.Moisture sensitive.Cancer suspect agent.Lachrymator
(substance which increases the flow of tears).
Potential Health Effects
Eye:
Causes eye irritation. Lachrymator (substance which increases the
flow of tears). May cause chemical conjunctivitis and corneal
damage.
Skin:
Causes skin irritation.
Ingestion:
Harmful if swallowed. May cause severe irritation of the digestive
tract.
Inhalation:
May be fatal if inhaled. Causes respiratory tract irritation.
Chronic:
Potential cancer hazard.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
In case of contact, immediately flush eyes with plenty of water for
at least 15 minutes. Get medical aid immediately.
Skin:
In case of contact, immediately flush skin with plenty of water for
at least 15 minutes while removing contaminated clothing and shoes.
Get medical aid immediately. Wash clothing before reuse.
Ingestion:
If swallowed, do NOT induce vomiting. Get medical aid immediately.
If victim is fully conscious, give a cupful of water. Never give
anything by mouth to an unconscious person.
Inhalation:
Poison material. If inhaled, get medical aid immediately. Remove
victim to fresh air. If not breathing, give artificial respiration.
If breathing is difficult, give oxygen.
Notes to Physician:
Treat symptomatically and supportively.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Use water spray to keep fire-exposed containers
cool. May accumulate static electrical charges, and may cause
ignition of its own vapors. Fire or excessive heat may result in
violent rupture of the container due to bulk polymerization.
Combustible liquid and vapor. Approach fire from upwind to avoid
hazardous vapors and toxic decomposition products. Vapors are
heavier than air and may travel to a source of ignition and flash
back. Vapors can spread along the ground and collect in low or
confined areas.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or appropriate foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Clean up spills immediately,
observing precautions in the Protective Equipment section. Remove all
sources of ignition. Use a spark-proof tool. Provide ventilation.
Approach spill from upwind.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Ground and bond containers when
transferring material. Do not get in eyes, on skin, or on clothing.
Empty containers retain product residue, (liquid and/or vapor), and
can be dangerous. Do not pressurize, cut, weld, braze, solder,
drill, grind, or expose empty containers to heat, sparks or open
flames. Use only with adequate ventilation. Keep away from heat and
flame. Do not breathe vapor or mist. Keep dry and use promptly.
Handle only in corrosion resistant equipment avoiding iron,
aluminum, and brass.
Storage:
Keep away from sources of ignition. Store in a cool, dry,
well-ventilated area away from incompatible substances. Storage for
long periods is not recommended. Store protected from moisture. Vent
periodically. Keep away from oxidizing agents.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate general or
local exhaust ventilation to keep airborne concentrations below the
permissible exposure limits.
Personal Protective Equipment
Eyes:
Wear chemical goggles.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Always use
a NIOSH or European Standard EN 149 approved
respirator when necessary.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: clear, colorless
Odor: pungent odor - unpleasant odor
pH: Not available.
Vapor Pressure: 1.3 mm Hg @ 25 deg C
Viscosity: 1.27 cps @ 20 deg C
Boiling Point: 179 deg C @ 760 mm Hg
Freezing/Melting Point: -39 deg C
Autoignition Temperature: 627 deg C ( 1,160.60 deg F)
Flash Point: 67 deg C ( 152.60 deg F)
Explosion Limits, lower: 1.3 %
Explosion Limits, upper: 7.1 %
Decomposition Temperature:
Solubility in water: Hydrolyzes slowly
Specific Gravity/Density: 1.1000 g/cm3
Molecular Formula: C7H7Cl
Molecular Weight: 126.59
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Unstabilized benzyl chloride undergoes a self-condensation reaction
in the presence of all common metals (except nickel and lead) with
the liberation of heat and hydrogen chloride. Decomposition and
polymerization reactions are inhibited to a limited extent by
addition of triethylamine, propylene oxide, or sodium carbonate.
Inhibition decreases during storage. Do not store for extended
period of time.
Conditions to Avoid:
Light, ignition sources, moisture, excess heat, excessive aging.
Incompatibilities with Other Materials:
Metals, strong oxidizing agents.
Hazardous Decomposition Products:
Hydrogen chloride, carbon monoxide, irritating and toxic fumes and
gases, carbon dioxide.
Hazardous Polymerization: May occur.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 75-56-9: TZ2975000
CAS# 100-44-7: XS8925000
LD50/LC50:
Not available.
Not available.
Carcinogenicity:
Propylene oxide -
Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
Benzyl chloride -
Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Ecotoxicity:
Fish: Fathead Minnow: 34.7 ppm; 96 hr; LC50Water flea Daphnia: 6.1
ppm; 48 hr; LC50
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: BENZYL CHLORIDE
Hazard Class: 6.1
UN Number: 1738
Packing Group: II
IMO
Shipping Name: BENZYL CHLORIDE
Hazard Class: 6.1
UN Number: 1738
Packing Group: II
RID/ADR
Shipping Name: BENZYL CHLORIDE
Hazard Class: 6.1
UN Number: 1738
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T
Risk Phrases:
R 22 Harmful if swallowed.
R 23 Toxic by inhalation.
R 37/38 Irritating to respiratory system and skin.
R 41 Risk of serious damage to eyes.
R 45 May cause cancer.
R 48/22 Harmful : danger of serious damage to health
by prolonged exposure if swallowed.
Safety Phrases:
S 53 Avoid exposure - obtain special instructions
before use.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 75-56-9: 2
CAS# 100-44-7: 3
United Kingdom Occupational Exposure Limits
United Kingdom Maximum Exposure Limits
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 75-56-9 is not listed on Canada's Ingredient Disclosure List.
CAS# 100-44-7 is not listed on Canada's Ingredient Disclosure List.
Exposure Limits
CAS# 75-56-9: OEL-AUSTRALIA:TWA 20 ppm (50 mg/m3);Carcinogen
OEL-BELGIUM:TWA 20 ppm (48 mg/m3)
OEL-DENMARK:TWA 5 ppm (12 mg/m3);Skin;Carcinogen
OEL-FINLAND:TWA 5 ppm (12 mg/m3);Carcinogen
OEL-FRANCE:TWA 20 ppm (50 mg/m3)
OEL-GERMANY;Carcinogen
OEL-THE NETHERLANDS:TWA 100 ppm (240 mg/m3)
OEL-THE PHILIPPINES:TWA 100 ppm (240 mg/m3)
OEL-RUSSIA:STEL 1 mg/m3;Skin
OEL-SWEDEN:TWA 5 ppm (12 mg/m3);STEL 10 ppm (25 mg/m3)
OEL-SWITZERLAND:TWA 2.5 ppm (6 mg/m3);Carcinogen
OEL-TURKEY:TWA 100 ppm (240 mg/m3)
OEL-UNITED KINGDOM:TWA 20 ppm (50 mg/m3);STEL 100 ppm
OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV
OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGI TLV
CAS# 100-44-7: OEL-AUSTRALIA:TWA 1 ppm (5 mg/m3)
OEL-AUSTRIA:TWA 1 ppm (5 mg/m3)
OEL-BELGIUM:TWA 1 ppm (5.2 mg/m3)
OEL-DENMARK:STEL 1 ppm (5 mg/m3)
OEL-DENMARK:TWA 1 ppm (5 mg/m3)
OEL-FINLAND:TWA 1 ppm (5 mg/m3);STEL 3 ppm (15 mg/m3)
OEL-FRANCE:TWA 1 ppm (5 mg/m3);STEL 2 ppm (11 mg/m3);Skin
OEL-FRANCE:TWA 1 ppm (5 mg/m3);STEL 3 ppm (15 mg/m3);CAR
OEL-GERMANY:TWA 1 ppm (5 mg/m3);Carcinogen
OEL-HUNGARY:STEL 0.5 mg/m3;Skin
OEL-THE NETHERLANDS:TWA 1 ppm (5 mg/m3)
OEL-THE PHILIPPINES:TWA 1 ppm (5 mg/m3)
OEL-RUSSIA:STEL 0.5 mg/m3
OEL-SWEDEN:TWA 1 ppm (5 mg/m3);STEL 2 ppm (11 mg/m3)
OEL-SWEDEN:TWA 1 ppm (5 mg/m3);STEL 2 ppm (11 mg/m3);CAR
OEL-SWITZERLAND:TWA 1 ppm (5 mg/m3);STEL 2 ppm (1 mg/m3)
OEL-TURKEY:TWA 1 ppm (5 mg/m3)
OEL-UNITED KINGDOM:TWA 1 ppm (3 mg/m3);STEL 2 ppm (6 mg/m3)
OEL-UNITED KINGDOM:TWA 1 ppm (5 mg/m3)
OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV
OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGI TLV
US FEDERAL
TSCA
CAS# 75-56-9 is not listed on the TSCA inventory.
It is for research and development use only.
CAS# 100-44-7 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 4/28/1999 Revision #5 Date: 7/11/2002
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
L-Epicatechin, Mixture of ca.60% (-)-Epicatechin and ca.40% Catechin
| 490-46-0 |
|
2,4,6-Tri-2-Pyridyl-S-Triazine, 99%
| 3682-35-7 |
|
Oxalacetic acid, 96%
| 328-42-7 |
|
Nile Blue Hydrochloride
| 2381-85-3 |
|
Dimethylsulfamoyl Chloride, 97%
| 13360-57-1 |
|
Adenine Sulfate 98%
| 321-30-2 |
|
3,3'-Diethylthiatricarbocyanine Iodide
| 3071-70-3 |
|
7-Chlortetracycline Monohydrochloride, Potency 900 mu/mg
| 64-72-2 |
|
4-Aminobenzoic Acid, Sodium Salt, 99%
| 555-06-6 |
|
Sodium Thiocarbonate (40% in Water)
| 534-18-9 |
|
n-Acetyl-s-benzyl-l-cysteine
| 19542-77-9 |
|
3-Hydroxypropionitrile, 98%
| 109-78-4 |
|
2-Ethylhexanoic acid, 99%
| 149-57-5 |
|
Trans,Trans-1,4-Diphenyl-1,3-Butadiene, 99%
| 886-65-7 |
|
Benzyl chloride, stabilized, 99.5+% (with 0.25% propylene oxide)
| 75-56-9 |
|
Benzyl chloride, pract., 90%
| 100-44-7 |
|
Azure b, high purity biological stain
| 531-55-5 |
|
4-Amino-3-Hydroxy-1-Naphthalenesulfonic Acid, 95%
| 116-63-2 |
|
2-Bromoethylamine Hydrobromide, 99%
| 2576-47-8 |
|
2-Nitrophenol, 99%
| 88-75-5 |
|
Diethoxydimethylsilane, 97%
| 78-62-6 |
|
Calcium sulfate, anhydrous, 99%
| 7778-18-9 |
|
Drierite, 6 mesh, without indicator
| 7778-18-9 |
|
Drierite, 8 mesh, without indicator
| 7778-18-9 |
|
Drierite, 10-20 mesh, without indicator
| 7778-18-9 |
|
Drierite, 20-40 mesh, without indicator
| 7778-18-9 |
|
Drierite, 4 mesh, with indicator
| 7778-18-9 |
|
Drierite, 8 mesh, with indicator
| 7778-18-9 |
|
Drierite, 20-40 mesh, with indicator
| 7778-18-9 |
|
4,4,4-Trifluoro-1-phenyl-1,3-butanedione, 99%
| 326-06-7 |
|
2-Bromoethanesulfonic Acid, Sodium Salt, 98%
| 4263-52-9 |
|
Sodium 4-Nitrophenoxide, Hydrate, 98% (On Dry Basis)
| 824-78-2 |
|
2-Octylamine
| 693-16-3 |
|
4-Nitrobenzyl chloride, 99%
| 100-14-1 |
|
Palmitic Acid, 98% (GC)
| 57-10-3 |
|
n-Butyllithium, 1.6M solution in hexanes
| 109-72-8 |
|
n-Butyllithium (15% in heptane)
| 109-72-8 |
|
Barium Fluoride, 99.99%
| 7787-32-8 |
|
Decanoic Acid (Capric Acid), 96%
| 334-48-5 |
|
trans-4-Butyl-alpha-chloro-4'-etoxystilben 99+%
| 54513-47-2 |
|
Cyclohexanepropionic Acid, 99%
| 701-97-3 |
|
Carbon tetrachloride, 99%
| 56-23-5 |
|
Carbon Tetrachloride, P.A.
| 56-23-5 |
|
Carbon Tetrachloride, Low Absorbance at 2900 to 3050 cm-1
| 56-23-5 |
|
Lauric Acid, 95%
| 143-07-7 |
|
N,N,N',N'-Tetraethylethylenediamine
| 150-77-6 |
|
Phenyl chloroformate, 99% (gc)
| 1885-14-9 |
|
Methyl-p-benzoquinone, 99+%
| 553-97-9 |
|
1-Phenylpiperazine, 97%
| 92-54-6 |
|
3,4-Dimercaptotoluene, 99%
| 496-74-2 |
|
|