**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 10025-87-3 |Phosphorus Oxychloride | 99+ | 233-046-7 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XI C
Risk Phrases: 34 37
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Causes burns. Irritating to respiratory
system.Corrosive.Water-reactive.
Potential Health Effects
Eye:
Causes severe eye irritation and burns.
Skin:
Causes severe skin irritation and burns. Causes redness and pain.
Ingestion:
Harmful if swallowed. Causes gastrointestinal irritation with
nausea, vomiting and diarrhea. Causes digestive tract burns with
immediate pain, swelling of the throat, convulsions, and possible
coma.
Inhalation:
May be fatal if inhaled. May cause severe irritation of the
respiratory tract with sore throat, coughing, shortness of breath
and delayed lung edema. May cause severe irritation of the upper
respiratory tract with pain, burns, and inflammation. Vapors may
cause dizziness or suffocation. May cause nausea, dizziness, and
headache. Exposure may produce pulmonary edema which may progress to
pneumonia, and cardiac failure may intervene.
Chronic:
May cause liver and kidney damage. Chronic exposure can lead to
necrosis of the jaw, or 'phossy-jaw'.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Get medical aid immediately. Do NOT allow victim to rub eyes or keep
eyes closed. Extensive irrigation with water is required (at least 30
minutes).
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes. Wash clothing before reuse. Remove all contaminated
clothing immediately.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical
aid immediately. Do NOT induce vomiting. If conscious and alert,
rinse mouth and drink 2-4 cupfuls of milk or water. Call a poison
control center.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If breathing is difficult, give oxygen. Do NOT use
mouth-to-mouth resuscitation.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
Evacuate area and fight fire from a safe distance. As in any fire,
wear a self-contained breathing apparatus in pressure-demand,
MSHA/NIOSH (approved or equivalent), and full protective gear. During
a fire, irritating and highly toxic gases may be generated by thermal
decomposition or combustion. Water Reactive. Material will react with
water and may release a flammable and/or toxic gas. Substance is
noncombustible. Contact with water can cause violent liberation of
heat and splattering of the material. Water Reactive.
Extinguishing Media:
DO NOT USE WATER! Use dry chemical or carbon dioxide.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Avoid runoff into storm sewers and ditches which lead to waterways.
Sweep up or absorb material, then place into a suitable clean, dry,
closed container for disposal. Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Wash hands before eating. Remove
contaminated clothing and wash before reuse. Use only in a
well-ventilated area. Follow all MSDS and label precautions even
after container is emptied because they may contain product residues.
Do not get in eyes, on skin, or on clothing. Keep container tightly
closed. Do not ingest or inhale. Do not allow contact with water.
Storage:
Store in a cool, dry, well-ventilated area away from incompatible
substances. Corrosives area. Store in a suitable container in a dry
area above the substance's freezing point. Keep containers tightly
closed.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use adequate general or local exhaust ventilation to keep airborne
concentrations below the permissible exposure limits.
Exposure Limits
CAS# 10025-87-3:
United Kingdom, WEL - TWA: 0.2 ppm TWA; 1.3 mg/m3 TWA
United Kingdom, WEL - STEL: 0.6 ppm STEL; 3.8 mg/m3 STEL
Belgium - TWA: 0.1 ppm VLE; 0.64 mg/m3 VLE
France - VME: 0.1 ppm VME; 0.6 mg/m3 VME
Germany: 0.2 ppm TWA; 1.3 mg/m3 TWA
Malaysia: 0.1 ppm TWA; 0.63 mg/m3 TWA
Netherlands: 0.1 ppm MAC; 0.6 mg/m3 MAC
Russia: 0.05 mg/m3 TWA
Spain: 0.1 ppm VLA-ED; 0.64 mg/m3 VLA-ED
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: colorless
Odor: musty hay - pungent odor
pH: Not available.
Vapor Pressure: 40 mm Hg @ 27.3
Viscosity: Not available.
Boiling Point: 105.8 deg C
Freezing/Melting Point: 34.0 deg F
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: Reacts.
Specific Gravity/Density: 1.7000g/cm3
Molecular Formula: Cl3OP
Molecular Weight: 153.33
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable at room temperature in closed containers under normal storage
and handling conditions. Combines vigorously with water with the
evolution of heat.
Conditions to Avoid:
Incompatible materials, contact with water, electrical sparks.
Incompatibilities with Other Materials:
Metals, acids, alcohols, aluminum, amines, phenols. Explosive
reactions with 2,6-Dimethylpyridine N-Oxide, Dimethyl Sulfoxide,
Ferrocene-1,1'Dicarboxylic Acid, Pyridine N-Oxide (above 60C),
Sodium + Heat. Violent reactions with BI3, Carbon Disulfide,
2,5-Dimethylpyrrole + Dimethyl Formamide, Organic Matter, Zinc
Powder. Reacts violently with water and/or steam to produce heat and
toxic corrosive fumes.
Hazardous Decomposition Products:
Hydrogen chloride, phosphine, oxides of phosphorus, irritating and
toxic fumes and gases, phosphorous fumes.
Hazardous Polymerization: Will not occur.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 10025-87-3: TH4897000
LD50/LC50:
CAS# 10025-87-3: Inhalation, mouse: LC50 = 404 mg/m3/2H; Inhalation,
rat: LC50 = 32 ppm/4H; Oral, mouse: LD50 = 327 mg/kg; Oral, rat: LD50
= 36 mg/kg; Oral, rat: LD50 = 380 mg/kg.
Carcinogenicity:
Phosphorus Oxychloride -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.
USA RQ: CAS# 10025-87-3: 1000 lb final RQ; 454 kg final RQ
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI C
Risk Phrases:
R 34 Causes burns.
R 37 Irritating to respiratory system.
Safety Phrases:
S 7/8 Keep container tightly closed and dry.
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 10025-87-3: 1
Canada
CAS# 10025-87-3 is listed on Canada's DSL List.
CAS# 10025-87-3 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 10025-87-3 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 4/06/1998 Revision #3 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
tert-Butyl (2S,3S)-3-Amino-2-Hydroxy-3-Phenylpropanoate, 97%
| 0-01-1 |
|
Diethyl-5-amino-3-methyl-2,4-thiophene-dicarboxylate, 97%
| 4815-30-9 |
|
tert-Butyl (2R,3R)-3-amino-2-hydroxy-3-phenylpropanoate, 97%
| 135981-02-1 |
|
tert-Butyl (2R,3S)-3-Amino-2-Hydroxy-4-Phenylbutanoate, 97%
| 119626-06-1 |
|
tert-Butyl (2S,3R)-3-Amino-2-Hydroxy-4-Phenylbutanoate, 97%
| 0-01-1 |
|
tert-Butyl (2S,3S)-3-Amino-2-Hydroxybutanoate, 97%
| 0-01-1 |
|
tert-Butyl (2R,3R)-3-Amino-2-Hydroxybutanoate, 97%
| 204587-91-7 |
|
Allyl(chloromethyl)dimethylsilane, 96%
| 75422-66-1 |
|
Phenol, 99+%, Loose Crystals, Biochemical Grade
| 108-95-2 |
|
Allyldichloromethylsilane, 97%
| 1873-92-3 |
|
Dichloromethyloctadecylsilane, 95%
| 5157-75-5 |
|
Chlorocyclohexyldimethylsilane, 97%
| 71864-47-6 |
|
Chloromethylphenylsilane, 98%
| 1631-82-9 |
|
Diethylmethylsilane, 97%
| 760-32-7 |
|
1,1-Dichlorosilacyclobutane, 97%
| 2351-33-9 |
|
1,1-Bis(trichlorosilylmethyl)ethylene
| 78948-04-6 |
|
Phenol, Reagent ACS
| 108-95-2 |
|
1,6-Bis(trichlorosilyl)hexane, 97%
| 13083-94-8 |
|
Tris(trimethylsilyl)germanium hydride, 96%
| 104164-54-7 |
|
2-Amino-1,3,4-Thiadiazole, 97%
| 4005-51-0 |
|
1,2-Epoxydecane, 96%
| 2404-44-6 |
|
1,2-Epoxyoctane, 96%
| 2984-50-1 |
|
Phenolphthalein, Reagent ACS
| 77-09-8 |
|
Phenol red, indicator
| 143-74-8 |
|
Phenylacetic acid, 98.5%
| 103-82-2 |
|
Phosphoric acid, reagent ACS, 85+%
| 7664-38-2 |
|
1,2-Epoxydodecane, 96%
| 2855-19-8 |
|
Ammonium Citrate Dibasic
| 3012-65-5 |
|
TRIS-(TRIMETHYLSILYLOXY)-ETHYLENE, 95%
| 69097-20-7 |
|
1-Trimethylsilyloxy-1,3-butadiene
| 6651-43-0 |
|
Phosphorus Pentoxide, P.A.
| 1314-56-3 |
|
1,1,5-Triacetoxy-2,2-dichloropentane, 97%
| 0-01-1 |
|
4-(Hydroxymethyl)imidazole hydrochloride, 99%
| 32673-41-9 |
|
Phosphorus Oxychloride, Reagent, 99+% (Titr.)
| 10025-87-3 |
|
DL-4-Hydroxy-3-Methoxyphenylglycol, Piperazine Salt, Tech., 90%
| 67423-45-4 |
|
Phosphotungstic Acid Hydrate, p.a.
| 12067-99-1 |
|
o-Phthalaldehyde, 98% (gc)
| 643-79-8 |
|
Ammonium dichromate
| 7789-09-5 |
|
Picric Acid, Reagent ACS
| 88-89-1 |
|
(4R)-N-(tert.-Butyldimethylsilyl)azetidin-2-one-4-carboxylic acid,
| 162856-35-1 |
|
(1R,2R)-Diaminomethylcyclohexane, 95%
| 68737-65-5 |
|
Piperidine, 99%
| 110-89-4 |
|
(R)-(-)-2-Amino-6-Phosphonohexanoic Acid, 95% (97%e.e.)
| 131177-53-2 |
|
1-Methyladenine, 99%
| 5142-22-3 |
|
Potassium hexachloroplatinate(iv) ca.40% pt
| 16921-30-5 |
|
(-)-Dibutyl-D-tartrate
| 0-01-1 |
|
Poly(Ethylene Glycol), Average M.W. 400
| 25322-68-3 |
|
Dioctyl phthalate, 99+%
| 117-81-7 |
|
Poly(Ethylene Glycol), Average M.W. 600
| 25322-68-3 |
|
(Carboethoxymethyl)Triphenylphosphonium Chloride Hydrate, 97%
| 17577-28-5 |
|
|