**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 6651-43-0 |1-Trimethylsilyloxy-1,3-butadiene | ca. 100 | unlisted |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XI
Risk Phrases: 10 36/37/38
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Flammable. Irritating to eyes, respiratory system and skin.Moisture
sensitive.
Potential Health Effects
Eye:
Causes eye irritation. May cause conjunctivitis. Contact with the
eyes may cause corneal damage.
Skin:
Causes skin irritation. May be harmful if absorbed through the skin.
Effects may be delayed. May cause contact dermatitis.
Ingestion:
May cause irritation of the digestive tract. May be harmful if
swallowed.
Inhalation:
Causes respiratory tract irritation. May be harmful if inhaled. Can
produce delayed pulmonary edema.
Chronic:
Effects may be delayed.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and
drink 2-4 cupfuls of milk or water. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid. Do NOT use mouth-to-mouth
resuscitation.
Notes to Physician:
Treat symptomatically and supportively.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Vapors can travel to a source of ignition and flash
back. During a fire, irritating and highly toxic gases may be
generated by thermal decomposition or combustion. Will burn if
involved in a fire. Flammable liquid and vapor. Vapors may be
heavier than air. They can spread along the ground and collect in
low or confined areas. Containers may explode if exposed to fire.
Runoff from fire control or dilution water may cause pollution.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam. Do
NOT get water inside containers.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Avoid runoff into storm sewers and
ditches which lead to waterways. Clean up spills immediately,
observing precautions in the Protective Equipment section. Remove all
sources of ignition. Use a spark-proof tool. Provide ventilation. Do
not get water inside containers.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Ground and bond containers when transferring material. Use
spark-proof tools and explosion proof equipment. Avoid breathing
dust, vapor, mist, or gas. Avoid contact with eyes, skin, and
clothing. Empty containers retain product residue, (liquid and/or
vapor), and can be dangerous. Keep container tightly closed. Avoid
ingestion and inhalation. Use with adequate ventilation. Wash
clothing before reuse. Do not pressurize, cut, weld, braze, solder,
drill, grind, or expose empty containers to heat, sparks or open
flames. Keep from contact with moist air and steam. Keep away from
heat, sparks and flame.
Storage:
Keep away from sources of ignition. Store in a cool, dry place.
Store in a tightly closed container. Flammables-area.
Refrigerator/flammables. Store protected from moisture.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate general or
local explosion-proof ventilation to keep airborne levels to
acceptable levels.
Exposure Limits
CAS# 6651-43-0:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: clear, colorless to straw
Odor: mild odor
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 131 deg C
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: 25 deg C ( 77.00 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: Insoluble.
Specific Gravity/Density: .8110g/cm3
Molecular Formula: (CH3)3SiOCH=CHCH=CH2
Molecular Weight: 142.28
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable at room temperature in closed containers under normal storage
and handling conditions. Moisture sensitive.
Conditions to Avoid:
Ignition sources, excess heat, exposure to moist air or water.
Incompatibilities with Other Materials:
Strong oxidizing agents, peroxides, strong acids.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide, silicon dioxide.
Hazardous Polymerization: Has not been reported
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 6651-43-0 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
1-Trimethylsilyloxy-1,3-butadiene -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: FLAMMABLE LIQUID, N.O.S.*
Hazard Class: 3
UN Number: 1993
Packing Group: II
IMO
Shipping Name: FLAMMABLE LIQUID, N.O.S.
Hazard Class: 3.2
UN Number: 1993
Packing Group: II
RID/ADR
Shipping Name: FLAMMABLE LIQUID, N.O.S.
Hazard Class: 3
UN Number: 1993
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI
Risk Phrases:
R 10 Flammable.
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 9 Keep container in a well-ventilated place.
S 16 Keep away from sources of ignition - No
smoking.
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 33 Take precautionary measures against static
discharges.
S 37/39 Wear suitable gloves and eye/face
protection.
WGK (Water Danger/Protection)
CAS# 6651-43-0: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 6651-43-0 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 6651-43-0 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 2/14/2000 Revision #5 Date: 10/14/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
tert-Butyl (2S,3S)-3-Amino-2-Hydroxy-3-Phenylpropanoate, 97%
| 0-01-1 |
|
Diethyl-5-amino-3-methyl-2,4-thiophene-dicarboxylate, 97%
| 4815-30-9 |
|
tert-Butyl (2R,3R)-3-amino-2-hydroxy-3-phenylpropanoate, 97%
| 135981-02-1 |
|
tert-Butyl (2R,3S)-3-Amino-2-Hydroxy-4-Phenylbutanoate, 97%
| 119626-06-1 |
|
tert-Butyl (2S,3R)-3-Amino-2-Hydroxy-4-Phenylbutanoate, 97%
| 0-01-1 |
|
tert-Butyl (2S,3S)-3-Amino-2-Hydroxybutanoate, 97%
| 0-01-1 |
|
tert-Butyl (2R,3R)-3-Amino-2-Hydroxybutanoate, 97%
| 204587-91-7 |
|
Allyl(chloromethyl)dimethylsilane, 96%
| 75422-66-1 |
|
Phenol, 99+%, Loose Crystals, Biochemical Grade
| 108-95-2 |
|
Allyldichloromethylsilane, 97%
| 1873-92-3 |
|
Dichloromethyloctadecylsilane, 95%
| 5157-75-5 |
|
Chlorocyclohexyldimethylsilane, 97%
| 71864-47-6 |
|
Chloromethylphenylsilane, 98%
| 1631-82-9 |
|
Diethylmethylsilane, 97%
| 760-32-7 |
|
1,1-Dichlorosilacyclobutane, 97%
| 2351-33-9 |
|
1,1-Bis(trichlorosilylmethyl)ethylene
| 78948-04-6 |
|
Phenol, Reagent ACS
| 108-95-2 |
|
1,6-Bis(trichlorosilyl)hexane, 97%
| 13083-94-8 |
|
Tris(trimethylsilyl)germanium hydride, 96%
| 104164-54-7 |
|
2-Amino-1,3,4-Thiadiazole, 97%
| 4005-51-0 |
|
1,2-Epoxydecane, 96%
| 2404-44-6 |
|
1,2-Epoxyoctane, 96%
| 2984-50-1 |
|
Phenolphthalein, Reagent ACS
| 77-09-8 |
|
Phenol red, indicator
| 143-74-8 |
|
Phenylacetic acid, 98.5%
| 103-82-2 |
|
Phosphoric acid, reagent ACS, 85+%
| 7664-38-2 |
|
1,2-Epoxydodecane, 96%
| 2855-19-8 |
|
Ammonium Citrate Dibasic
| 3012-65-5 |
|
TRIS-(TRIMETHYLSILYLOXY)-ETHYLENE, 95%
| 69097-20-7 |
|
1-Trimethylsilyloxy-1,3-butadiene
| 6651-43-0 |
|
Phosphorus Pentoxide, P.A.
| 1314-56-3 |
|
1,1,5-Triacetoxy-2,2-dichloropentane, 97%
| 0-01-1 |
|
4-(Hydroxymethyl)imidazole hydrochloride, 99%
| 32673-41-9 |
|
Phosphorus Oxychloride, Reagent, 99+% (Titr.)
| 10025-87-3 |
|
DL-4-Hydroxy-3-Methoxyphenylglycol, Piperazine Salt, Tech., 90%
| 67423-45-4 |
|
Phosphotungstic Acid Hydrate, p.a.
| 12067-99-1 |
|
o-Phthalaldehyde, 98% (gc)
| 643-79-8 |
|
Ammonium dichromate
| 7789-09-5 |
|
Picric Acid, Reagent ACS
| 88-89-1 |
|
(4R)-N-(tert.-Butyldimethylsilyl)azetidin-2-one-4-carboxylic acid,
| 162856-35-1 |
|
(1R,2R)-Diaminomethylcyclohexane, 95%
| 68737-65-5 |
|
Piperidine, 99%
| 110-89-4 |
|
(R)-(-)-2-Amino-6-Phosphonohexanoic Acid, 95% (97%e.e.)
| 131177-53-2 |
|
1-Methyladenine, 99%
| 5142-22-3 |
|
Potassium hexachloroplatinate(iv) ca.40% pt
| 16921-30-5 |
|
(-)-Dibutyl-D-tartrate
| 0-01-1 |
|
Poly(Ethylene Glycol), Average M.W. 400
| 25322-68-3 |
|
Dioctyl phthalate, 99+%
| 117-81-7 |
|
Poly(Ethylene Glycol), Average M.W. 600
| 25322-68-3 |
|
(Carboethoxymethyl)Triphenylphosphonium Chloride Hydrate, 97%
| 17577-28-5 |
|
|