**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 110-89-4 |Piperidine | 99 | 203-813-0 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: T F C
Risk Phrases: 11 23/24 34
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Highly flammable. Toxic by inhalation and in contact with skin.
Causes burns.
Potential Health Effects
Eye:
Causes eye burns. Causes redness and pain.
Skin:
Causes skin burns. Causes redness and pain. Toxic in contact with
skin. Absorbed through the skin.
Ingestion:
Harmful if swallowed. Causes gastrointestinal tract burns. May cause
central nervous system effects. May cause burning sensations,
coughing, wheezing, laryngitis, shortness of breath and headache.
Inhalation:
Causes chemical burns to the respiratory tract. Inhalation may be
fatal as a result of spasm, inflammation, edema of the larynx and
bronchi, chemical pneumonitis and pulmonary edema. Toxic if inhaled.
May cause liver damage.
Chronic:
Not available.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen.
Notes to Physician:
Treat symptomatically and supportively.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Vapors may form an explosive mixture with air.
Vapors can travel to a source of ignition and flash back. During a
fire, irritating and highly toxic gases may be generated by thermal
decomposition or combustion. Will burn if involved in a fire.
Flammable liquid and vapor.
Extinguishing Media:
Use water spray to cool fire-exposed containers. Use foam, dry
chemical, or carbon dioxide.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Do not flush into a sewer. Remove
all sources of ignition. Use a spark-proof tool.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Use spark-proof tools and explosion proof equipment. Do not breathe
dust, vapor, mist, or gas. Do not get in eyes, on skin, or on
clothing. Take precautionary measures against static discharges. Use
only in a chemical fume hood.
Storage:
Keep away from sources of ignition. Store in a cool, dry place.
Store in a tightly closed container. Flammables-area.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate general or
local explosion-proof ventilation to keep airborne levels to
acceptable levels.
Exposure Limits
CAS# 110-89-4:
United Kingdom, WEL - TWA: 1 ppm TWA; 3.5 mg/m3 TWA
United Kingdom, WEL - STEL: 3 ppm STEL; 10.5 mg/m3 STEL
Russia: 0.2 mg/m3 TWA
Personal Protective Equipment
Eyes:
Not available.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Clear liquid
Color: colorless
Odor: amine-like
pH: 12.6(100g/l aq.sol.)
Vapor Pressure: 24.75 mm Hg @20 deg C
Viscosity: 1.46 mPa@ 20 deg C
Boiling Point: 106 deg C @ 760 mmHg
Freezing/Melting Point: -11 deg C
Autoignition Temperature: 320 deg C ( 608.00 deg F)
Flash Point: 16 deg C ( 60.80 deg F)
Explosion Limits, lower: 1.15 Vol%
Explosion Limits, upper: 8.7 Vol%
Decomposition Temperature: >500 deg C
Solubility in water: Miscible.
Specific Gravity/Density: 0.8622g/cm3
Molecular Formula: C5H11N
Molecular Weight: 85.15
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, ignition sources.
Incompatibilities with Other Materials:
Strong oxidizing agents, acids, acid chlorides, aluminum, carbon
dioxide, zinc, acid anhydrides, sulfur trioxide.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, carbon dioxide.
Hazardous Polymerization: Will not occur.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 110-89-4: TM3500000
LD50/LC50:
CAS# 110-89-4: Draize test, rabbit, eye: 250 ug/24H Severe; Draize
test, rabbit, skin: 5 mg/24H Severe; Inhalation, mouse: LC50 = 6000
mg/m3/2H; Oral, mouse: LD50 = 30 mg/kg; Oral, rabbit: LD50 = 145
mg/kg; Oral, rat: LD50 = 400 mg/kg; Skin, rabbit: LD50 = 276 mg/kg.
Carcinogenicity:
Piperidine -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Ecotoxicity:
log POW = 0.84
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: PIPERIDINE
Hazard Class: 8 (3)
UN Number: 2401
Packing Group: I
IMO
Shipping Name: PIPERIDINE
Hazard Class: 8 (8)
UN Number: 2401
Packing Group: I
RID/ADR
Shipping Name: PIPERIDINE
Hazard Class: 8
UN Number: 2401
Packing group: I
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T F C
Risk Phrases:
R 11 Highly flammable.
R 23/24 Toxic by inhalation and in contact with
skin.
R 34 Causes burns.
Safety Phrases:
S 16 Keep away from sources of ignition - No
smoking.
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 27 Take off immediately all contaminated clothing.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 110-89-4: 1
Canada
CAS# 110-89-4 is listed on Canada's DSL List.
CAS# 110-89-4 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 110-89-4 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 11/12/1997 Revision #1 Date: 3/20/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
tert-Butyl (2S,3S)-3-Amino-2-Hydroxy-3-Phenylpropanoate, 97%
| 0-01-1 |
|
Diethyl-5-amino-3-methyl-2,4-thiophene-dicarboxylate, 97%
| 4815-30-9 |
|
tert-Butyl (2R,3R)-3-amino-2-hydroxy-3-phenylpropanoate, 97%
| 135981-02-1 |
|
tert-Butyl (2R,3S)-3-Amino-2-Hydroxy-4-Phenylbutanoate, 97%
| 119626-06-1 |
|
tert-Butyl (2S,3R)-3-Amino-2-Hydroxy-4-Phenylbutanoate, 97%
| 0-01-1 |
|
tert-Butyl (2S,3S)-3-Amino-2-Hydroxybutanoate, 97%
| 0-01-1 |
|
tert-Butyl (2R,3R)-3-Amino-2-Hydroxybutanoate, 97%
| 204587-91-7 |
|
Allyl(chloromethyl)dimethylsilane, 96%
| 75422-66-1 |
|
Phenol, 99+%, Loose Crystals, Biochemical Grade
| 108-95-2 |
|
Allyldichloromethylsilane, 97%
| 1873-92-3 |
|
Dichloromethyloctadecylsilane, 95%
| 5157-75-5 |
|
Chlorocyclohexyldimethylsilane, 97%
| 71864-47-6 |
|
Chloromethylphenylsilane, 98%
| 1631-82-9 |
|
Diethylmethylsilane, 97%
| 760-32-7 |
|
1,1-Dichlorosilacyclobutane, 97%
| 2351-33-9 |
|
1,1-Bis(trichlorosilylmethyl)ethylene
| 78948-04-6 |
|
Phenol, Reagent ACS
| 108-95-2 |
|
1,6-Bis(trichlorosilyl)hexane, 97%
| 13083-94-8 |
|
Tris(trimethylsilyl)germanium hydride, 96%
| 104164-54-7 |
|
2-Amino-1,3,4-Thiadiazole, 97%
| 4005-51-0 |
|
1,2-Epoxydecane, 96%
| 2404-44-6 |
|
1,2-Epoxyoctane, 96%
| 2984-50-1 |
|
Phenolphthalein, Reagent ACS
| 77-09-8 |
|
Phenol red, indicator
| 143-74-8 |
|
Phenylacetic acid, 98.5%
| 103-82-2 |
|
Phosphoric acid, reagent ACS, 85+%
| 7664-38-2 |
|
1,2-Epoxydodecane, 96%
| 2855-19-8 |
|
Ammonium Citrate Dibasic
| 3012-65-5 |
|
TRIS-(TRIMETHYLSILYLOXY)-ETHYLENE, 95%
| 69097-20-7 |
|
1-Trimethylsilyloxy-1,3-butadiene
| 6651-43-0 |
|
Phosphorus Pentoxide, P.A.
| 1314-56-3 |
|
1,1,5-Triacetoxy-2,2-dichloropentane, 97%
| 0-01-1 |
|
4-(Hydroxymethyl)imidazole hydrochloride, 99%
| 32673-41-9 |
|
Phosphorus Oxychloride, Reagent, 99+% (Titr.)
| 10025-87-3 |
|
DL-4-Hydroxy-3-Methoxyphenylglycol, Piperazine Salt, Tech., 90%
| 67423-45-4 |
|
Phosphotungstic Acid Hydrate, p.a.
| 12067-99-1 |
|
o-Phthalaldehyde, 98% (gc)
| 643-79-8 |
|
Ammonium dichromate
| 7789-09-5 |
|
Picric Acid, Reagent ACS
| 88-89-1 |
|
(4R)-N-(tert.-Butyldimethylsilyl)azetidin-2-one-4-carboxylic acid,
| 162856-35-1 |
|
(1R,2R)-Diaminomethylcyclohexane, 95%
| 68737-65-5 |
|
Piperidine, 99%
| 110-89-4 |
|
(R)-(-)-2-Amino-6-Phosphonohexanoic Acid, 95% (97%e.e.)
| 131177-53-2 |
|
1-Methyladenine, 99%
| 5142-22-3 |
|
Potassium hexachloroplatinate(iv) ca.40% pt
| 16921-30-5 |
|
(-)-Dibutyl-D-tartrate
| 0-01-1 |
|
Poly(Ethylene Glycol), Average M.W. 400
| 25322-68-3 |
|
Dioctyl phthalate, 99+%
| 117-81-7 |
|
Poly(Ethylene Glycol), Average M.W. 600
| 25322-68-3 |
|
(Carboethoxymethyl)Triphenylphosphonium Chloride Hydrate, 97%
| 17577-28-5 |
|
|