**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 102-85-2 |Tributyl phosphite | 94 | 203-061-3 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN
Risk Phrases: 21 36/37/38
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful in contact with skin. Irritating to eyes, respiratory system
and skin.Moisture sensitive.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes severe skin irritation. May be harmful if absorbed through
the skin.
Ingestion:
May cause irritation of the digestive tract. May be harmful if
swallowed.
Inhalation:
May cause respiratory tract irritation.
Chronic:
No information found.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical
aid immediately.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Use with adequate ventilation. Avoid
contact with eyes, skin, and clothing. Keep container tightly closed.
Avoid ingestion and inhalation.
Storage:
Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 102-85-2:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: Clear
Odor: Not available.
pH: Not available.
Vapor Pressure: < 0.1 mm Hg @ 20C
Viscosity: Not available.
Boiling Point: 118 - 125 deg C @ 7.00mm Hg
Freezing/Melting Point: -80 deg C
Autoignition Temperature: Not available.
Flash Point: 121 deg C ( 249.80 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: may decompose in water
Specific Gravity/Density: .9250g/cm3
Molecular Formula: C12H27O3P
Molecular Weight: 250.32
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable.
Conditions to Avoid:
Incompatible materials, exposure to moist air or water.
Incompatibilities with Other Materials:
Strong oxidizing agents - strong bases.
Hazardous Decomposition Products:
Phosphine, carbon monoxide, oxides of phosphorus, carbon dioxide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 102-85-2: TH0875000
LD50/LC50:
CAS# 102-85-2: Draize test, rabbit, eye: 500 mg Moderate; Draize
test, rabbit, skin: 5 mg/24H Severe; Oral, rat: LD50 = 3 gm/kg; Skin,
rabbit: LD50 = 2 gm/kg.
Skin, rabbit:
Carcinogenicity:
Tributyl phosphite -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 21 Harmful in contact with skin.
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 37/39 Wear suitable gloves and eye/face
protection.
WGK (Water Danger/Protection)
CAS# 102-85-2: 1
Canada
CAS# 102-85-2 is listed on Canada's DSL List.
CAS# 102-85-2 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 102-85-2 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/02/1997 Revision #3 Date: 4/23/2004
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
2-Amino-4-Chlorobenzothiazole, 97%
| 19952-47-7 |
|
Lead(II) perchlorate trihydrate
| 13453-62-8 |
|
Palladium(ii)acetylacetonate, 35% pd
| 14024-61-4 |
|
Ethylenediaminetetraacetic Acid, Dicalcium Salt, 94% (Titr.)
| 19709-85-4 |
|
2-Benzoyl-5-norbornene, tech., 90% mixture of endo and exo
| 6056-35-5 |
|
alpha-Toluenethiol, 99% (gc)
| 100-53-8 |
|
Acid yellow 17
| 6359-98-4 |
|
1H-pyrrole-2,5-dicarboxaldehyde, 94% (gc)
| |
|
1-Ethyl-2-pyrrolidinone, 98%
| 2687-91-4 |
|
Iodo-PDSMTSC-Iron(IV) complex
| 0-00-0 |
|
Acetoacetanilide, 99%
| 102-01-2 |
|
2,2-Dichloro-1,4-Butanediol, 99%
| 0-00-1 |
|
Tetra-N-Pentylcalix[4]Resorcinolarene, 97% (TLC)
| 118629-59-7 |
|
Ethyl Nipecotate, 97%
| 71962-74-8 |
|
3,5-Dimethoxy-4-Hydroxycinnamic Acid, 98%, Predominantly Trans Isomer
| 530-59-6 |
|
Trioctylpropylammonium Chloride (Pract), 95% (Titr.)
| 40739-43-3 |
|
Isonicotinic Acid, 99%
| 55-22-1 |
|
Diethyl Terephthalate, 98% (GC)
| 636-09-9 |
|
7-Methoxy-2-tetralone, 95%
| 4133-34-0 |
|
Thallic acetate, 98% (GC)
| 2570-63-0 |
|
Isobutylamine, 99%
| 78-81-9 |
|
1-(3-Chlorophenyl)Piperazine Hydrochloride ,95%(HPLC)
| 65369-76-8 |
|
cis-2-Amino-1-cyclohexanecarboxylic acid 98%
| 5691-20-3 |
|
Chloroacetic acid sodium salt, 98% (titr.)
| 3926-62-3 |
|
Pyridinium chlorochromate, 98%
| 26299-14-9 |
|
2-(Phenylsulfonyl)aniline, 99%
| 4273-98-7 |
|
2-Methylbenzylamine, 96%
| 89-93-0 |
|
(R)-(-)-Citramalic Acid, 98+%
| 6236-10-8 |
|
4-Pentenoic acid, 99%
| 591-80-0 |
|
Citraconic Acid, 99+%
| 498-23-7 |
|
Palladium hydroxide on carbon powder, 20% pd, moisture ca 50%
| 12135-22-7 |
|
n-Hexadecyl mercaptan, tech., 92%
| 2917-26-2 |
|
Methylcyclopentane, 99+%
| 96-37-7 |
|
Epiandrosterone, 99% (HP:C)
| 481-29-8 |
|
2,3,4,5,6,6-Hexachloro-2,4-Cyclohexadien-1-One,99%
| 21306-21-8 |
|
Tributyl phosphite, 94%
| 102-85-2 |
|
4-Carboxybenzenesulfonamide, 98%
| 138-41-0 |
|
Propargyltriphenylphosphonium Bromide,99+%
| 2091-46-5 |
|
N-Methylhydroxylamine hydrochloride, 98%
| 4229-44-1 |
|
D,L-2-pyrrolidone-5-carboxylic acid,98%
| 149-87-1 |
|
Peanut Oil
| 8002-03-7 |
|
Diisopropyl Azodicarboxylate, 97%
| 2446-83-5 |
|
DL-2-Pentanol
| 6032-29-7 |
|
3,4,5-Trichloroaniline, 97%
| 634-91-3 |
|
Cyanourea, Sodium Salt, 98%
| 76989-89-4 |
|
4-Chlorophenylacetic Acid, 98% (GC)
| 1878-66-6 |
|
3-Fluorophenylacetonitrile, 99+%
| 501-00-8 |
|
Decahydroquinoline, 98%, Mixture of Cis and Trans
| 2051-28-7 |
|
Diphenylmethane, P.A.
| 101-81-5 |
|
Trans 2, cis 6-Nonadienal
| 557-48-2 |
|
|