**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 26299-14-9 |Pyridinium chlorochromate | 98% | 247-595-5 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: T O N
Risk Phrases: 43 8 49 50/53
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
May cause sensitization by skin contact. Contact with combustible
material may cause fire. May cause cancer by inhalation. Very toxic
to aquatic organisms, may cause long-term adverse effects in the
aquatic environment.Moisture sensitive.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation. May cause skin sensitization, an allergic
reaction, which becomes evident upon re-exposure to this material.
May be harmful if absorbed through the skin.
Ingestion:
May cause irritation of the digestive tract. May be harmful if
swallowed.
Inhalation:
May cause respiratory tract irritation. May be harmful if inhaled.
Chronic:
May cause cancer in humans.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes.
Ingestion:
Get medical aid immediately. Wash mouth out with water.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Oxidizer. Greatly increases the burning rate of
combustible materials.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on
skin, or on clothing. Use only in a chemical fume hood.
Storage:
Do not store near combustible materials. Store in a cool, dry place.
Store in a tightly closed container.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 26299-14-9:
United Kingdom, WEL - TWA: (listed as chromium (vi) compounds): 0
mg/m3 TWA (as Cr)
United Kingdom, WEL - STEL: (listed as chromium (vi) compounds):
mg/m3 STEL (as Cr)
Belgium - TWA: (listed as chromium (vi) compounds (certain water
insoluble forms)): 0.01 mg/m3 VLE (as Cr)
France - VME: (listed as chromium (vi) compounds): 0.05 mg/m3 VME
Cr)
Germany: (listed as chromium (vi) compounds): 0.05 mg/m3 VME (as
Japan: (listed as chromium (vi) compounds): 0.05 mg/m3 OEL (as Cr
0.01 mg/m3 OEL (certain compounds, as Cr)
Spain: (listed as chromium (vi) compounds (certain water insolubl
forms)): 0.01 mg/m3 VLA-ED (as Cr)
Personal Protective Equipment
Eyes:
Not available.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Crystalline powder
Color: orange
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 205 deg C(decom)
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: 205 deg C
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C5H6ClCrNO3
Molecular Weight: 215.56
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, dust generation, exposure to moist air or
water.
Incompatibilities with Other Materials:
Strong reducing agents, strong acids, alcohols.
Hazardous Decomposition Products:
Hydrogen chloride, nitrogen oxides, carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 26299-14-9 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Pyridinium chlorochromate -
California: carcinogen, initial date 2/27/87 (listed as Chromium (VI)
NTP: Known carcinogen (listed as Chromium (VI) compounds).
IARC: Group 1 carcinogen (listed as Chromium (VI) compounds).
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: OXIDIZING SOLID, N.O.S.*
Hazard Class: 5.1
UN Number: 1479
Packing Group: II
IMO
Shipping Name: OXIDIZING SOLID, N.O.S.
Hazard Class: 5.1
UN Number: 1479
Packing Group: II
RID/ADR
Shipping Name: OXIDIZING SOLID, N.O.S.
Hazard Class: 5.1
UN Number: 1479
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T O N
Risk Phrases:
R 49 May cause cancer by inhalation.
R 43 May cause sensitization by skin contact.
R 50/53 Very toxic to aquatic organisms, may cause
long-term adverse effects in the aquatic environment.
R 8 Contact with combustible material may cause
fire.
Safety Phrases:
S 53 Avoid exposure - obtain special instructions
before use.
S 17 Keep away from combustible material.
S 24 Avoid contact with skin.
S 37 Wear suitable gloves.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
S 60 This material and its container must be
disposed of as hazardous waste.
S 61 Avoid release to the environment. Refer to
special instructions/safety data sheets.
WGK (Water Danger/Protection)
CAS# 26299-14-9: No information available.
Canada
CAS# 26299-14-9 is listed on Canada's NDSL List.
CAS# 26299-14-9 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 26299-14-9 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/02/1997 Revision #2 Date: 6/10/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
2-Amino-4-Chlorobenzothiazole, 97%
| 19952-47-7 |
|
Lead(II) perchlorate trihydrate
| 13453-62-8 |
|
Palladium(ii)acetylacetonate, 35% pd
| 14024-61-4 |
|
Ethylenediaminetetraacetic Acid, Dicalcium Salt, 94% (Titr.)
| 19709-85-4 |
|
2-Benzoyl-5-norbornene, tech., 90% mixture of endo and exo
| 6056-35-5 |
|
alpha-Toluenethiol, 99% (gc)
| 100-53-8 |
|
Acid yellow 17
| 6359-98-4 |
|
1H-pyrrole-2,5-dicarboxaldehyde, 94% (gc)
| |
|
1-Ethyl-2-pyrrolidinone, 98%
| 2687-91-4 |
|
Iodo-PDSMTSC-Iron(IV) complex
| 0-00-0 |
|
Acetoacetanilide, 99%
| 102-01-2 |
|
2,2-Dichloro-1,4-Butanediol, 99%
| 0-00-1 |
|
Tetra-N-Pentylcalix[4]Resorcinolarene, 97% (TLC)
| 118629-59-7 |
|
Ethyl Nipecotate, 97%
| 71962-74-8 |
|
3,5-Dimethoxy-4-Hydroxycinnamic Acid, 98%, Predominantly Trans Isomer
| 530-59-6 |
|
Trioctylpropylammonium Chloride (Pract), 95% (Titr.)
| 40739-43-3 |
|
Isonicotinic Acid, 99%
| 55-22-1 |
|
Diethyl Terephthalate, 98% (GC)
| 636-09-9 |
|
7-Methoxy-2-tetralone, 95%
| 4133-34-0 |
|
Thallic acetate, 98% (GC)
| 2570-63-0 |
|
Isobutylamine, 99%
| 78-81-9 |
|
1-(3-Chlorophenyl)Piperazine Hydrochloride ,95%(HPLC)
| 65369-76-8 |
|
cis-2-Amino-1-cyclohexanecarboxylic acid 98%
| 5691-20-3 |
|
Chloroacetic acid sodium salt, 98% (titr.)
| 3926-62-3 |
|
Pyridinium chlorochromate, 98%
| 26299-14-9 |
|
2-(Phenylsulfonyl)aniline, 99%
| 4273-98-7 |
|
2-Methylbenzylamine, 96%
| 89-93-0 |
|
(R)-(-)-Citramalic Acid, 98+%
| 6236-10-8 |
|
4-Pentenoic acid, 99%
| 591-80-0 |
|
Citraconic Acid, 99+%
| 498-23-7 |
|
Palladium hydroxide on carbon powder, 20% pd, moisture ca 50%
| 12135-22-7 |
|
n-Hexadecyl mercaptan, tech., 92%
| 2917-26-2 |
|
Methylcyclopentane, 99+%
| 96-37-7 |
|
Epiandrosterone, 99% (HP:C)
| 481-29-8 |
|
2,3,4,5,6,6-Hexachloro-2,4-Cyclohexadien-1-One,99%
| 21306-21-8 |
|
Tributyl phosphite, 94%
| 102-85-2 |
|
4-Carboxybenzenesulfonamide, 98%
| 138-41-0 |
|
Propargyltriphenylphosphonium Bromide,99+%
| 2091-46-5 |
|
N-Methylhydroxylamine hydrochloride, 98%
| 4229-44-1 |
|
D,L-2-pyrrolidone-5-carboxylic acid,98%
| 149-87-1 |
|
Peanut Oil
| 8002-03-7 |
|
Diisopropyl Azodicarboxylate, 97%
| 2446-83-5 |
|
DL-2-Pentanol
| 6032-29-7 |
|
3,4,5-Trichloroaniline, 97%
| 634-91-3 |
|
Cyanourea, Sodium Salt, 98%
| 76989-89-4 |
|
4-Chlorophenylacetic Acid, 98% (GC)
| 1878-66-6 |
|
3-Fluorophenylacetonitrile, 99+%
| 501-00-8 |
|
Decahydroquinoline, 98%, Mixture of Cis and Trans
| 2051-28-7 |
|
Diphenylmethane, P.A.
| 101-81-5 |
|
Trans 2, cis 6-Nonadienal
| 557-48-2 |
|
|