**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
|----------------|--------------------------------------|----------|-----------|
| 103-11-7 |2-Ethylhexyl acrylate | > 99 | 203-080-7 |
|----------------|--------------------------------------|----------|-----------|
| 150-76-5 |4-Methoxyphenol | .0015 | 205-769-8 |
|----------------|--------------------------------------|----------|-----------|
| 7732-18-5 |Water | <0.05 | 231-791-2 |
+----------------+--------------------------------------+----------+-----------+
Text for R-phrases: see Section 16
Hazard Symbols: XI
Risk Phrases: 37/38 43
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Irritating to respiratory system and skin. May cause sensitization
by skin contact.Heat sensitive.
Potential Health Effects
Eye:
Causes severe eye irritation.
Skin:
Causes severe skin irritation. May cause skin sensitization, an
allergic reaction, which becomes evident upon re-exposure to this
material.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea.
Inhalation:
Causes respiratory tract irritation. Inhalation may produce burning
sensation, coughing, wheezing, laryngitis, shortness of breath,
headache, nausea, and vomiting.
Chronic:
No information found.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Remove
contaminated clothing and shoes.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical
aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen.
Notes to Physician:
Antidote:
None reported.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Use water
spray to keep fire-exposed containers cool. Combustible liquid.
Containers may explode when heated.
Extinguishing Media:
In case of fire, use water, dry chemical, chemical foam, or
alcohol-resistant foam. Water or foam may cause frothing. Use water
spray to cool fire-exposed containers.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Clean up spills immediately,
observing precautions in the Protective Equipment section. Remove all
sources of ignition.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use only in a well-ventilated area. Avoid contact
with eyes, skin, and clothing. Empty containers retain product
residue, (liquid and/or vapor), and can be dangerous. Keep container
tightly closed. Keep away from heat, sparks and flame. Avoid
ingestion and inhalation. Do not pressurize, cut, weld, braze,
solder, drill, grind, or expose empty containers to heat, sparks or
open flames.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of
ignition. Keep container closed when not in use. Store in a tightly
closed container. Store in a cool, dry, well-ventilated area away
from incompatible substances. Keep refrigerated. (Store below
4C/39F.)
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 103-11-7:
Germany: 10 ppm TWA; 82 mg/m3 TWA
Russia: 1 mg/m3 TWA
CAS# 150-76-5:
Belgium - TWA: 5 mg/m3 VLE
France - VME: 5 mg/m3 VME
Germany: 5 mg/m3 TWA
Malaysia: 5 mg/m3 TWA
Netherlands: 5 mg/m3 MAC
Spain: 5 mg/m3 VLA-ED
CAS# 7732-18-5:
Personal Protective Equipment
Eyes:
Wear chemical splash goggles.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: clear, colorless
Odor: acrid odor
pH: Not available.
Vapor Pressure: 0.14 mm Hg @ 20 deg C
Viscosity: cP 25 deg C
Boiling Point: 184 deg C @ 760mm Hg
Freezing/Melting Point: -90 deg C
Autoignition Temperature: 245 deg C ( 473.00 deg F)
Flash Point: 82 deg C ( 179.60 deg F)
Explosion Limits, lower: 0.7%
Explosion Limits, upper: 8.2%
Decomposition Temperature:
Solubility in water: insoluble
Specific Gravity/Density: .8800g/cm3
Molecular Formula: C11H20O2
Molecular Weight: 184.28
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable only if stored and handled under recommended conditions. The
stability of the product depends upon the availability of both
dissolved oxygen and MEHQ inhibitor(CAS=150-76-5). The presence of
oxygen is necessary for the MEHQ to function effectively. The
product should never be stored under an inert gas atmosphere, but
should always be stored under an atmosphere containing 5-21% oxygen
by volume.
Conditions to Avoid:
Incompatible materials, ignition sources, strong oxidants, loss of
inhibitor, heat.
Incompatibilities with Other Materials:
Oxidizing agents
Hazardous Decomposition Products:
Irritating and toxic fumes and gases, acrid smoke and fumes.
Hazardous Polymerization: May occur.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 103-11-7: AT0855000
CAS# 150-76-5: SL7700000
CAS# 7732-18-5: ZC0110000
LD50/LC50:
CAS# 103-11-7: Draize test, rabbit, eye: 5 mg Severe; Draize test,
rabbit, eye: 500 mg/24H Mild; Draize test, rabbit, skin: 20 mg/24H
Moderate; Oral, mouse: LD50 = 4400 mg/kg; Oral, mouse: LD50 = 4400
mg/kg; Oral, rat: LD50 = 6500 uL/kg; Oral, rat: LD50 = 6700 mg/kg;
Skin, rabbit: LD50 = 8480 uL/kg.
CAS# 150-76-5: Draize test, rabbit, skin: 6 gm/12D (Intermittent)
Mild; Draize test, rabbit, skin: 10%; Oral, rat: LD50 = 1600 mg/kg.
CAS# 7732-18-5: Oral, rat: LD50 = >90 mL/kg.
Carcinogenicity:
2-Ethylhexyl acrylate -
Not listed by ACGIH, IARC, or NTP.
4-Methoxyphenol -
Not listed by ACGIH, IARC, or NTP.
Water -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Other
No information available.
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI
Risk Phrases:
R 37/38 Irritating to respiratory system and skin.
R 43 May cause sensitization by skin contact.
Safety Phrases:
S 24 Avoid contact with skin.
S 37 Wear suitable gloves.
WGK (Water Danger/Protection)
CAS# 103-11-7: 1
CAS# 150-76-5: 1
CAS# 7732-18-5: No information available.
Canada
CAS# 103-11-7 is listed on Canada's DSL List.
CAS# 150-76-5 is listed on Canada's DSL List.
CAS# 7732-18-5 is listed on Canada's DSL List.
CAS# 103-11-7 is listed on Canada's Ingredient Disclosure List.
CAS# 150-76-5 is listed on Canada's Ingredient Disclosure List.
CAS# 7732-18-5 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 103-11-7 is listed on the TSCA inventory.
CAS# 150-76-5 is listed on the TSCA inventory.
CAS# 7732-18-5 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
Text for R-phrases from Section 2
MSDS Creation Date: 3/18/1999 Revision #4 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|