**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 29576-14-5 |Crotyl bromide, remainder 3-bromo-1-bu| 85gc.ca | unlisted |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XI F
Risk Phrases: 11 36/37/38
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Highly flammable. Irritating to eyes, respiratory system and
skin.Light sensitive.The toxicological properties of this material
have not been fully investigated.
Potential Health Effects
Eye:
May cause eye irritation. Lachrymator (substance which increases
the flow of tears).
Skin:
May cause skin irritation.
Ingestion:
May cause irritation of the digestive tract. The toxicological
properties of this substance have not been fully investigated.
Inhalation:
May cause respiratory tract irritation. The toxicological properties
of this substance have not been fully investigated. Vapors may cause
dizziness or suffocation.
Chronic:
No information found.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical
aid immediately.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
Antidote:
None reported.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Vapors may form an explosive mixture with air.
During a fire, irritating and highly toxic gases may be generated by
thermal decomposition or combustion. Will burn if involved in a fire.
Use water spray to keep fire-exposed containers cool. Containers may
explode in the heat of a fire. Flammable liquid and vapor.
Extinguishing Media:
For small fires, use dry chemical, carbon dioxide, water spray or
alcohol-resistant foam. For large fires, use water spray, fog, or
alcohol-resistant foam. Use water spray to cool fire-exposed
containers. Water may be ineffective. Do NOT use straight streams of
water.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Clean up spills immediately,
observing precautions in the Protective Equipment section. Sweep up
or absorb material, then place into a suitable clean, dry, closed
container for disposal. Remove all sources of ignition. Use a
spark-proof tool. Provide ventilation. A vapor suppressing foam may
be used to reduce vapors.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use with adequate ventilation. Ground and bond
containers when transferring material. Use spark-proof tools and
explosion proof equipment. Avoid contact with eyes, skin, and
clothing. Empty containers retain product residue, (liquid and/or
vapor), and can be dangerous. Keep container tightly closed. Keep
away from heat, sparks and flame. Avoid ingestion and inhalation. Do
not pressurize, cut, weld, braze, solder, drill, grind, or expose
empty containers to heat, sparks or open flames.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of
ignition. Keep container closed when not in use. Store in a tightly
closed container. Store in a cool, dry, well-ventilated area away
from incompatible substances. Flammables-area.
Refrigerator/flammables.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 29576-14-5:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: light yellow
Odor: None reported.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 97 - 99 deg C
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: 11 deg C ( 51.80 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: slightly soluble in water
Specific Gravity/Density: 1.3120g/cm3
Molecular Formula: C4H7Br
Molecular Weight: 135.00
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, ignition sources, excess heat, strong
oxidants.
Incompatibilities with Other Materials:
Oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, irritating and toxic fumes and gases, carbon
dioxide, hydrogen bromide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 29576-14-5 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Crotyl bromide, remainder 3-bromo-1-butene -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Other
No information available.
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: FLAMMABLE LIQUID, N.O.S.*
Hazard Class: 3
UN Number: 1993
Packing Group: II
IMO
Shipping Name: FLAMMABLE LIQUID, N.O.S.
Hazard Class: 3.2
UN Number: 1993
Packing Group: II
RID/ADR
Shipping Name: FLAMMABLE LIQUID, N.O.S.
Hazard Class: 3
UN Number: 1993
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI F
Risk Phrases:
R 11 Highly flammable.
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 9 Keep container in a well-ventilated place.
S 16 Keep away from sources of ignition - No
smoking.
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 28A After contact with skin, wash immediately with
plenty of water.
S 33 Take precautionary measures against static
discharges.
S 37 Wear suitable gloves.
S 37/39 Wear suitable gloves and eye/face
protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
S 50A Do not mix with acids.
WGK (Water Danger/Protection)
CAS# 29576-14-5: No information available.
Canada
CAS# 29576-14-5 is listed on Canada's NDSL List.
CAS# 29576-14-5 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 29576-14-5 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 11/05/1998 Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
2-Amino-1,3-Propanediol, 98%
| 534-03-2 |
|
1,7-Octadiene, 98.5%
| 3710-30-3 |
|
(2-Bromoethyl)benzene, 98%
| 103-63-9 |
|
4-Piperidinopiperidine, tech., 95%
| 4897-50-1 |
|
4'-Bromopropiophenone, 97%
| 10342-83-3 |
|
Thiophenol
| 108-98-5 |
|
1,2,4-Trivinylcyclohexane, 98% mixture of isomers
| 2855-27-8 |
|
l-Bornyl acetate
| 5655-61-8 |
|
Cyclopentadecanone, 96%
| 502-72-7 |
|
1,14-Tetradecanediol, 95% (GC)
| 19812-64-7 |
|
3-Heptylthiophene, 97%
| 65016-61-7 |
|
2,4-Dimethyl-6-Hydroxypyrimidine, 99+%
| 6622-92-0 |
|
3-(2-Chloroethyl)-2,4(1H,3H)-Quinazoline- Dione, 99%
| 5081-87-8 |
|
3,5-Dimethyl-4-heptanone, 97+%
| 19549-84-9 |
|
N-Methyl-p-anisidine, 98%
| 5961-59-1 |
|
m-Toluenethiol, 97% (GC)
| 108-40-7 |
|
Dehydroabietylamine, tech.
| 1446-61-3 |
|
Zirconium atomic absorption standard solution, 1 mg/ml Zr in 5% HF
| 7440-67-7 |
|
DL-Bromosuccinic Acid, 96%
| 923-06-8 |
|
3-Chloropropiophenone, 98%
| 936-59-4 |
|
Hexadecyltrimethylammonium chloride, 99%
| 112-02-7 |
|
2,5-Dichlorothiophene, 98%
| 3172-52-9 |
|
Stigmastanol, Tech.
| 19466-47-8 |
|
3-Acetamido-4-methoxybenzenesulfinic acid, hydrate, 97%
| |
|
2,4-Dinitrobenzenesulfonic Acid Sodium Salt, 98% (UV-Vis)
| 885-62-1 |
|
2-Methylindole, 98%
| 95-20-5 |
|
(R)-(+)-2-Chloropropionic acid, 98%
| 598-78-7 |
|
m-Phosphoric Acid, Glacial
| 37267-86-0 |
|
2-Ethylhexyl acrylate, 99+% stabilized with 10-20 ppm MEHQ
| 103-11-7 |
|
2-Chloropropane, P.A.
| 75-29-6 |
|
m-Xylene
| 108-38-3 |
|
4-Chloro-3,5-Dinitrobenzotrifluoride 98+%
| 393-75-9 |
|
Crotyl bromide, 85 %(gc-cap.), remainder 3-bromo-1-butene
| 29576-14-5 |
|
n-Dodecyl sulfide, 93%
| 2469-45-6 |
|
6-Nitropiperonyl Alcohol, 98%
| 15341-08-9 |
|
Methyl 2-methoxybenzoate, 99%
| 606-45-1 |
|
Magnesium, turnings and ribbons
| 7439-95-4 |
|
Magnesium acetate tetrahydrate
| 16674-78-5 |
|
Formaldoxime Trimer Hydrochloride
| 62479-72-5 |
|
4-Ethoxy-1,3-Phenylenediamine Dihydro-Chloride, 98%
| 67801-06-3 |
|
Erbium atomic absorption standard solution, 1 mg/ml Er in 2% HNO3
| 7440-52-0 |
|
Dithiothreitol, 99%
| 3483-12-3 |
|
2,5-Dichloroaniline, 99%
| 95-82-9 |
|
Dimesitylcyclopropenone, 99% (uv-vis)
| 61440-88-8 |
|
Alpha-Cyclodextrin Hydrate, 98+% (HPLC)
| 10016-20-3 |
|
Magnesium Bromide Hexahydrate
| 13446-53-2 |
|
Magnesium carbonate anhydrous
| 546-93-0 |
|
Silver cyanate
| 3315-16-0 |
|
2,3,4,6-Tetra-o-acetyl-alpha-d-glucopyranosyl azide, 95%
| 20369-61-7 |
|
Magnesium Chloride Hexahydrate
| 7791-18-6 |
|
|