**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
|----------------|--------------------------------------|----------|-----------|
| 7440-52-0 |Erbium | 0.1 | 231-160-1 |
|----------------|--------------------------------------|----------|-----------|
| 7697-37-2 |Nitric acid | 2.0 | 231-714-2 |
|----------------|--------------------------------------|----------|-----------|
| 7732-18-5 |Water | 97.9 | 231-791-2 |
+----------------+--------------------------------------+----------+-----------+
Text for R-phrases: see Section 16
Hazard Symbols: XI
Risk Phrases: 37/38 41
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Irritating to respiratory system and skin. Risk of serious damage to
eyes.
Potential Health Effects
Eye:
Contact with eyes may cause severe irritation, and possible eye
burns. May cause chemical conjunctivitis and corneal damage.
Skin:
Causes skin irritation.
Ingestion:
May cause irritation of the digestive tract. May cause systemic
effects.
Inhalation:
Causes respiratory tract irritation. May cause systemic effects.
Chronic:
Effects may be delayed.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Get medical aid. Do NOT allow victim to rub eyes or keep eyes
closed. Extensive irrigation with water is required (at least 30
minutes).
Skin:
Get medical aid. Immediately flush skin with plenty of water for at
least 15 minutes while removing contaminated clothing and shoes.
Wash clothing before reuse. Destroy contaminated shoes.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid. Do NOT use mouth-to-mouth
resuscitation. If breathing has ceased apply artificial respiration
using oxygen and a suitable mechanical device such as a bag and a
mask.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Use water
spray to keep fire-exposed containers cool. Vapors may be heavier
than air. They can spread along the ground and collect in low or
confined areas. Containers may explode when heated.
Extinguishing Media:
Use agent most appropriate to extinguish fire. Do NOT get water
inside containers. Cool containers with flooding quantities of water
until well after fire is out. Use water spray, dry chemical, carbon
dioxide, or appropriate foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Avoid runoff into storm sewers and
ditches which lead to waterways. Clean up spills immediately,
observing precautions in the Protective Equipment section. Provide
ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Use with adequate ventilation. Avoid
contact with eyes, skin, and clothing. Do not breathe dust, vapor,
mist, or gas. Keep container tightly closed. Avoid ingestion and
inhalation. Discard contaminated shoes.
Storage:
Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 7440-52-0:
CAS# 7697-37-2:
United Kingdom, WEL - TWA: 2 ppm TWA; 5.2 mg/m3 TWA
United Kingdom, WEL - STEL: 4 ppm STEL; 10 mg/m3 STEL
United States OSHA: 2 ppm TWA; 5 mg/m3 TWA
Belgium - TWA: 2 ppm VLE; 5.3 mg/m3 VLE
Belgium - STEL: 4 ppm VLE; 10 mg/m3 VLE
France - VME: 2 ppm VME; 5 mg/m3 VME
France - VLE: 4 ppm VLE; 10 mg/m3 VLE
Germany: 2 ppm TWA; 5.2 mg/m3 TWA
Japan: 2 ppm OEL; 5.2 mg/m3 OEL
Malaysia: 2 ppm TWA; 5.2 mg/m3 TWA
Netherlands: 0.5 ppm STEL; 1.3 mg/m3 STEL
Russia: 2 mg/m3 TWA
Spain: 2 ppm VLA-ED; 5.2 mg/m3 VLA-ED
Spain: 4 ppm VLA-EC; 10 mg/m3 VLA-EC
CAS# 7732-18-5:
Personal Protective Equipment
Eyes:
Wear chemical splash goggles.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: colorless
Odor: None reported.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: miscible
Specific Gravity/Density:
Molecular Formula: Solution
Molecular Weight: 0
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, excess heat.
Incompatibilities with Other Materials:
Oxidizing agents.
Hazardous Decomposition Products:
Nitrogen oxides, irritating and toxic fumes and gases, nitrogen.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 7440-52-0 unlisted.
CAS# 7697-37-2: QU5775000 QU5900000
CAS# 7732-18-5: ZC0110000
LD50/LC50:
Not available.
CAS# 7697-37-2: Inhalation, rat: LC50 = 260 mg/m3/30M; Inhalation,
rat: LC50 = 130 mg/m3/4H; Inhalation, rat: LC50 = 67 ppm(NO2)/4H.
CAS# 7732-18-5: Oral, rat: LD50 = >90 mL/kg.
Carcinogenicity:
Erbium -
Not listed by ACGIH, IARC, or NTP.
Nitric acid -
Not listed by ACGIH, IARC, or NTP.
Water -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: NITRIC ACID
Hazard Class: 8
UN Number: 2031
Packing Group: II
IMO
Shipping Name: NITRIC ACID
Hazard Class: 8
UN Number: 2031
Packing Group: II
RID/ADR
Shipping Name: NITRIC ACID
Hazard Class: 8
UN Number: 2031
Packing group: II
USA RQ: CAS# 7697-37-2: 1000 lb final RQ; 454 kg final RQ
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI
Risk Phrases:
R 37/38 Irritating to respiratory system and skin.
R 41 Risk of serious damage to eyes.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 37/39 Wear suitable gloves and eye/face
protection.
WGK (Water Danger/Protection)
CAS# 7440-52-0: No information available.
CAS# 7697-37-2: 1
CAS# 7732-18-5: No information available.
Canada
CAS# 7440-52-0 is listed on Canada's NDSL List.
CAS# 7697-37-2 is listed on Canada's DSL List.
CAS# 7732-18-5 is listed on Canada's DSL List.
CAS# 7440-52-0 is not listed on Canada's Ingredient Disclosure List.
CAS# 7697-37-2 is listed on Canada's Ingredient Disclosure List.
CAS# 7732-18-5 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 7440-52-0 is listed on the TSCA inventory.
CAS# 7697-37-2 is listed on the TSCA inventory.
CAS# 7732-18-5 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
Text for R-phrases from Section 2
MSDS Creation Date: 9/02/1997 Revision #6 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
2-Amino-1,3-Propanediol, 98%
| 534-03-2 |
|
1,7-Octadiene, 98.5%
| 3710-30-3 |
|
(2-Bromoethyl)benzene, 98%
| 103-63-9 |
|
4-Piperidinopiperidine, tech., 95%
| 4897-50-1 |
|
4'-Bromopropiophenone, 97%
| 10342-83-3 |
|
Thiophenol
| 108-98-5 |
|
1,2,4-Trivinylcyclohexane, 98% mixture of isomers
| 2855-27-8 |
|
l-Bornyl acetate
| 5655-61-8 |
|
Cyclopentadecanone, 96%
| 502-72-7 |
|
1,14-Tetradecanediol, 95% (GC)
| 19812-64-7 |
|
3-Heptylthiophene, 97%
| 65016-61-7 |
|
2,4-Dimethyl-6-Hydroxypyrimidine, 99+%
| 6622-92-0 |
|
3-(2-Chloroethyl)-2,4(1H,3H)-Quinazoline- Dione, 99%
| 5081-87-8 |
|
3,5-Dimethyl-4-heptanone, 97+%
| 19549-84-9 |
|
N-Methyl-p-anisidine, 98%
| 5961-59-1 |
|
m-Toluenethiol, 97% (GC)
| 108-40-7 |
|
Dehydroabietylamine, tech.
| 1446-61-3 |
|
Zirconium atomic absorption standard solution, 1 mg/ml Zr in 5% HF
| 7440-67-7 |
|
DL-Bromosuccinic Acid, 96%
| 923-06-8 |
|
3-Chloropropiophenone, 98%
| 936-59-4 |
|
Hexadecyltrimethylammonium chloride, 99%
| 112-02-7 |
|
2,5-Dichlorothiophene, 98%
| 3172-52-9 |
|
Stigmastanol, Tech.
| 19466-47-8 |
|
3-Acetamido-4-methoxybenzenesulfinic acid, hydrate, 97%
| |
|
2,4-Dinitrobenzenesulfonic Acid Sodium Salt, 98% (UV-Vis)
| 885-62-1 |
|
2-Methylindole, 98%
| 95-20-5 |
|
(R)-(+)-2-Chloropropionic acid, 98%
| 598-78-7 |
|
m-Phosphoric Acid, Glacial
| 37267-86-0 |
|
2-Ethylhexyl acrylate, 99+% stabilized with 10-20 ppm MEHQ
| 103-11-7 |
|
2-Chloropropane, P.A.
| 75-29-6 |
|
m-Xylene
| 108-38-3 |
|
4-Chloro-3,5-Dinitrobenzotrifluoride 98+%
| 393-75-9 |
|
Crotyl bromide, 85 %(gc-cap.), remainder 3-bromo-1-butene
| 29576-14-5 |
|
n-Dodecyl sulfide, 93%
| 2469-45-6 |
|
6-Nitropiperonyl Alcohol, 98%
| 15341-08-9 |
|
Methyl 2-methoxybenzoate, 99%
| 606-45-1 |
|
Magnesium, turnings and ribbons
| 7439-95-4 |
|
Magnesium acetate tetrahydrate
| 16674-78-5 |
|
Formaldoxime Trimer Hydrochloride
| 62479-72-5 |
|
4-Ethoxy-1,3-Phenylenediamine Dihydro-Chloride, 98%
| 67801-06-3 |
|
Erbium atomic absorption standard solution, 1 mg/ml Er in 2% HNO3
| 7440-52-0 |
|
Dithiothreitol, 99%
| 3483-12-3 |
|
2,5-Dichloroaniline, 99%
| 95-82-9 |
|
Dimesitylcyclopropenone, 99% (uv-vis)
| 61440-88-8 |
|
Alpha-Cyclodextrin Hydrate, 98+% (HPLC)
| 10016-20-3 |
|
Magnesium Bromide Hexahydrate
| 13446-53-2 |
|
Magnesium carbonate anhydrous
| 546-93-0 |
|
Silver cyanate
| 3315-16-0 |
|
2,3,4,6-Tetra-o-acetyl-alpha-d-glucopyranosyl azide, 95%
| 20369-61-7 |
|
Magnesium Chloride Hexahydrate
| 7791-18-6 |
|
|