**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 3315-16-0 |Silver cyanate | >98 | 222-006-4 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN
Risk Phrases: 22 36/38
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful if swallowed. Irritating to eyes and skin.Light sensitive.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea. Ingestion of soluble silver salts may cause argyria,
characterized by permanent blue-gray pigmentation of the skin, mucous
membranes, and eyes. Ingestion of silver compounds may cause
abdominal pain, rigidity, convulsions and shock.
Inhalation:
Causes respiratory tract irritation. Inhalation of silver metal dust
and fume or of soluble silver compounds may eventually cause argyria,
an unsightly blue-gray discoloration of the skin and mucous
membranes, including gum tissue and conjunctiva of the eyes.
Chronic:
Chronic inhalation or ingestion of silver salts may cause argyria
characterized by a permanent blue-gray discoloration of the eyes,
skin, mucous membranes, and internal organs. This malady results
from the accumulation of silver in the body.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion.
Extinguishing Media:
Use agent most appropriate to extinguish fire. Use water spray, dry
chemical, carbon dioxide, or appropriate foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container. Clean up spills immediately, observing precautions in the
Protective Equipment section. Avoid generating dusty conditions.
Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Minimize dust generation and accumulation. Avoid
contact with eyes, skin, and clothing. Keep container tightly closed.
Use with adequate ventilation. Avoid breathing dust.
Storage:
Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances. Store
protected from light.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate general or
local exhaust ventilation to keep airborne concentrations below the
permissible exposure limits.
Exposure Limits
CAS# 3315-16-0:
United Kingdom, WEL - TWA: (listed as silver soluble compounds):
mg/m3 TWA (as Ag)
United Kingdom, WEL - STEL: (listed as silver soluble compounds):
0.03 mg/m3 STEL (as Ag)
United States OSHA: 0.01 mg/m3 TWA (listed under Silver soluble
compounds).
Belgium - TWA: (listed as silver soluble compounds): 0.01 mg/m3 V
(as Ag)
France - VME: (listed as silver soluble compounds): 0.01 mg/m3 VM
(as Ag)
Germany: (listed as silver soluble compounds): 0.01 mg/m3 VME (as
Japan: (listed as silver compounds): 0.01 mg/m3 OEL (as Ag)
Malaysia: (listed as silver soluble compounds): 0.01 mg/m3 TWA (a
Ag)
Netherlands: (listed as silver soluble compounds): 0.01 mg/m3 MAC
Ag)
Spain: (listed as silver soluble compounds): 0.01 mg/m3 VLA-ED (a
Ag)
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Powder
Color: beige to gray
Odor: None reported.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: Soluble.
Specific Gravity/Density: 4.0 g/cm3
Molecular Formula: AgOCN
Molecular Weight: 149.89
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures. May discolor on
exposure to light.
Conditions to Avoid:
Light, dust generation, excess heat.
Incompatibilities with Other Materials:
Strong acids.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, carbon dioxide, oxides of silver.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 3315-16-0 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Silver cyanate -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: CORROSIVE SOLID, N.O.S.*
Hazard Class: 8
UN Number: 1759
Packing Group: III
IMO
Shipping Name: CORROSIVE SOLID, N.O.S.
Hazard Class: 8
UN Number: 1759
Packing Group: III
RID/ADR
Shipping Name: CORROSIVE SOLID, N.O.S.
Hazard Class: 8
UN Number: 1759
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 22 Harmful if swallowed.
R 36/38 Irritating to eyes and skin.
Safety Phrases:
S 7/8 Keep container tightly closed and dry.
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 28A After contact with skin, wash immediately with
plenty of water.
WGK (Water Danger/Protection)
CAS# 3315-16-0: 3
Canada
CAS# 3315-16-0 is listed on Canada's DSL List.
CAS# 3315-16-0 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 3315-16-0 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/02/1997 Revision #6 Date: 10/24/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
2-Amino-1,3-Propanediol, 98%
| 534-03-2 |
|
1,7-Octadiene, 98.5%
| 3710-30-3 |
|
(2-Bromoethyl)benzene, 98%
| 103-63-9 |
|
4-Piperidinopiperidine, tech., 95%
| 4897-50-1 |
|
4'-Bromopropiophenone, 97%
| 10342-83-3 |
|
Thiophenol
| 108-98-5 |
|
1,2,4-Trivinylcyclohexane, 98% mixture of isomers
| 2855-27-8 |
|
l-Bornyl acetate
| 5655-61-8 |
|
Cyclopentadecanone, 96%
| 502-72-7 |
|
1,14-Tetradecanediol, 95% (GC)
| 19812-64-7 |
|
3-Heptylthiophene, 97%
| 65016-61-7 |
|
2,4-Dimethyl-6-Hydroxypyrimidine, 99+%
| 6622-92-0 |
|
3-(2-Chloroethyl)-2,4(1H,3H)-Quinazoline- Dione, 99%
| 5081-87-8 |
|
3,5-Dimethyl-4-heptanone, 97+%
| 19549-84-9 |
|
N-Methyl-p-anisidine, 98%
| 5961-59-1 |
|
m-Toluenethiol, 97% (GC)
| 108-40-7 |
|
Dehydroabietylamine, tech.
| 1446-61-3 |
|
Zirconium atomic absorption standard solution, 1 mg/ml Zr in 5% HF
| 7440-67-7 |
|
DL-Bromosuccinic Acid, 96%
| 923-06-8 |
|
3-Chloropropiophenone, 98%
| 936-59-4 |
|
Hexadecyltrimethylammonium chloride, 99%
| 112-02-7 |
|
2,5-Dichlorothiophene, 98%
| 3172-52-9 |
|
Stigmastanol, Tech.
| 19466-47-8 |
|
3-Acetamido-4-methoxybenzenesulfinic acid, hydrate, 97%
| |
|
2,4-Dinitrobenzenesulfonic Acid Sodium Salt, 98% (UV-Vis)
| 885-62-1 |
|
2-Methylindole, 98%
| 95-20-5 |
|
(R)-(+)-2-Chloropropionic acid, 98%
| 598-78-7 |
|
m-Phosphoric Acid, Glacial
| 37267-86-0 |
|
2-Ethylhexyl acrylate, 99+% stabilized with 10-20 ppm MEHQ
| 103-11-7 |
|
2-Chloropropane, P.A.
| 75-29-6 |
|
m-Xylene
| 108-38-3 |
|
4-Chloro-3,5-Dinitrobenzotrifluoride 98+%
| 393-75-9 |
|
Crotyl bromide, 85 %(gc-cap.), remainder 3-bromo-1-butene
| 29576-14-5 |
|
n-Dodecyl sulfide, 93%
| 2469-45-6 |
|
6-Nitropiperonyl Alcohol, 98%
| 15341-08-9 |
|
Methyl 2-methoxybenzoate, 99%
| 606-45-1 |
|
Magnesium, turnings and ribbons
| 7439-95-4 |
|
Magnesium acetate tetrahydrate
| 16674-78-5 |
|
Formaldoxime Trimer Hydrochloride
| 62479-72-5 |
|
4-Ethoxy-1,3-Phenylenediamine Dihydro-Chloride, 98%
| 67801-06-3 |
|
Erbium atomic absorption standard solution, 1 mg/ml Er in 2% HNO3
| 7440-52-0 |
|
Dithiothreitol, 99%
| 3483-12-3 |
|
2,5-Dichloroaniline, 99%
| 95-82-9 |
|
Dimesitylcyclopropenone, 99% (uv-vis)
| 61440-88-8 |
|
Alpha-Cyclodextrin Hydrate, 98+% (HPLC)
| 10016-20-3 |
|
Magnesium Bromide Hexahydrate
| 13446-53-2 |
|
Magnesium carbonate anhydrous
| 546-93-0 |
|
Silver cyanate
| 3315-16-0 |
|
2,3,4,6-Tetra-o-acetyl-alpha-d-glucopyranosyl azide, 95%
| 20369-61-7 |
|
Magnesium Chloride Hexahydrate
| 7791-18-6 |
|
|