**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 104-83-6 |4-Chlorobenzyl Chloride | 98 | 203-242-7 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN N
Risk Phrases: 36/38 43 51/53
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Irritating to eyes and skin. May cause sensitization by skin
contact. Toxic to aquatic organisms, may cause long-term adverse
effects in the aquatic environment.Moisture sensitive.Dangerous for
the environment.Lachrymator (substance which increases the flow of
tears).
Potential Health Effects
Eye:
Causes eye irritation. Lachrymator (substance which increases the
flow of tears).
Skin:
Causes skin irritation. May cause skin sensitization, an allergic
reaction, which becomes evident upon re-exposure to this material.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea.
Inhalation:
May cause respiratory tract irritation.
Chronic:
Repeated or prolonged exposure may cause allergic reactions in
sensitive individuals.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid. Do
NOT allow victim to rub eyes or keep eyes closed.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Discard
contaminated clothing in a manner which limits further exposure.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and
drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid. Do NOT use mouth-to-mouth
resuscitation.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Use water
spray to keep fire-exposed containers cool. Vapors may be heavier
than air. They can spread along the ground and collect in low or
confined areas. May polymerize explosively when involved in a fire.
Contact with metals may evolve flammable hydrogen gas. Containers may
explode when heated.
Extinguishing Media:
Do NOT use water directly on fire. Do NOT get water inside
containers. For small fires, use dry chemical, carbon dioxide, or
water spray. For large fires, use dry chemical, carbon dioxide,
alcohol-resistant foam, or water spray. Cool containers with flooding
quantities of water until well after fire is out.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Avoid runoff into storm sewers and
ditches which lead to waterways. Clean up spills immediately,
observing precautions in the Protective Equipment section. Remove all
sources of ignition. Provide ventilation. Do not get water inside
containers.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Use only in a well-ventilated area.
Avoid breathing dust, vapor, mist, or gas. Empty containers retain
product residue, (liquid and/or vapor), and can be dangerous. Do not
allow contact with water. Wash clothing before reuse. Do not
pressurize, cut, weld, braze, solder, drill, grind, or expose empty
containers to heat, sparks or open flames. Keep from contact with
moist air and steam.
Storage:
Store in a cool, dry, well-ventilated area away from incompatible
substances. Do not store in metal containers. Keep containers
tightly closed. Store protected from moisture.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate general or
local exhaust ventilation to keep airborne concentrations below the
permissible exposure limits.
Exposure Limits
CAS# 104-83-6:
Russia: 0.5 mg/m3 TWA
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves and clothing to
prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Wear a NIOSH/MSHA or European Standard EN 149
approved full-facepiece airline respirator in the
positive pressure mode with emergency escape
provisions.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: clear, colorless
Odor: None reported.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 221 deg C @ 760.00mm Hg
Freezing/Melting Point: 27 - 29 deg C
Autoignition Temperature: > 650 deg C (> 1,202.00 deg F)
Flash Point: 107 deg C ( 224.60 deg F)
Explosion Limits, lower: 2.00 vol %
Explosion Limits, upper: 8.60 vol %
Decomposition Temperature: >500 deg C
Solubility in water: soluble in alcohol, ether and acetone
Specific Gravity/Density:
Molecular Formula: C7H6Cl2
Molecular Weight: 161.03
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, moisture, metals, excess heat.
Incompatibilities with Other Materials:
Oxidizing agents, amines, bases, alcohols, moisture, steel.
Hazardous Decomposition Products:
Hydrogen chloride, carbon monoxide, irritating and toxic fumes and
gases, carbon dioxide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 104-83-6: XT0720000
LD50/LC50:
Not available.
Carcinogenicity:
4-Chlorobenzyl Chloride -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Other
No information available.
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: CHLOROBENZYLCHLORIDES
Hazard Class: 6.1
UN Number: 2235
Packing Group: III
IMO
Shipping Name: para-CHLOROBENZYL CHLORIDE, LIQUID or SOLID
Hazard Class: 6.1
UN Number: 2235
Packing Group: III
RID/ADR
Shipping Name: CHLOROBENZYL CHLORIDES
Hazard Class: 6.1
UN Number: 2235
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN N
Risk Phrases:
R 36/38 Irritating to eyes and skin.
R 43 May cause sensitization by skin contact.
R 51/53 Toxic to aquatic organisms, may cause
long-term adverse effects in the aquatic environment.
Safety Phrases:
S 14C Keep away from water, acids and alkali.
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 61 Avoid release to the environment. Refer to
special instructions/safety data sheets.
WGK (Water Danger/Protection)
CAS# 104-83-6: 2
Canada
CAS# 104-83-6 is listed on Canada's NDSL List.
CAS# 104-83-6 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 104-83-6 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 12/10/1998 Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Sodium peroxide, p.a.
| 1313-60-6 |
|
(+)-(1S,2R)-2-Amino-1-Cyclopentanecarboxylic Acid
| 64191-14-6 |
|
1,2,3,4-Tetrahydroisoquinoline-3-carboxylic acid hydrochloride, 98%
| 35186-99-3 |
|
2-Amino-3-Chloro-5-Nitrobenzonitrile, 98%
| 20352-84-5 |
|
Sodium phosphate, dibasic heptahydrate, reagent ACS, crystals
| 7558-79-4 |
|
Adipic Acid Monomethyl Ester, 98%
| 627-91-8 |
|
4-Methyl-3-nitrophenol, 98%
| 2042-14-0 |
|
6-Fluoroindole, 98%
| 399-51-9 |
|
Potassium sodium tartrate tetrahydrate, p.a.
| 6381-59-5 |
|
Methylboronic acid, 97%
| 13061-96-6 |
|
Sodium Pyrophosphate Decahydrate, P.A.
| 13472-36-1 |
|
Dotriacontane, 99% (GC)
| 544-85-4 |
|
Salicylic Acid, Sodium Salt, P.A.
| 54-21-7 |
|
Sodium sulfate, powder, anhydrous, 99%, p.a.
| 7757-82-6 |
|
4-Chlorobenzyl Chloride, 99+% (GC)
| 104-83-6 |
|
Sodium Sulfite, Anhydrous, P.A.
| 7757-83-7 |
|
Sodium Thiocyanate, Reagent ACS (Crystals)
| 540-72-7 |
|
3-Tolylboronic acid, 97%
| 17933-03-8 |
|
4-Tolylboronic acid, 97%
| 5720-05-8 |
|
4-Chlorophenylboronic Acid, 97%
| 1679-18-1 |
|
3-Fluorophenylboronic Acid, 97%
| 768-35-4 |
|
Sodium Thiosulfate, Anhydrous
| 7772-98-7 |
|
4-Carboxyphenylboronic Acid, 97%
| 14047-29-1 |
|
3-Carboxyphenylboronic acid, 98%
| 25487-66-5 |
|
2-Carboxyphenylboronic acid, 97%
| 149105-19-1 |
|
2-Methoxyphenylboronic Acid, 97%
| 5720-06-9 |
|
Hexahydro-4-Methylphthalic Anhydride, 98% Mixture of Cis and Trans
| 19438-60-9 |
|
Sodium Thiosulfate Pentahydrate, P.A.
| 10102-17-7 |
|
Sodium Tripolyphosphate, Tech., 85%
| 7758-29-4 |
|
Sodium tungstate, dihydrate, reagent acs
| 10213-10-2 |
|
Biuret, 99% (TLC)
| 108-19-0 |
|
Tin(IV) Chloride, 99.999%
| 7646-78-8 |
|
Tin (II) Chloride, Anhydrous, 98%
| 7772-99-8 |
|
Tin (II) Oxide, 98+%
| 21651-19-4 |
|
Tin (II) Sulfate, 99%
| 7488-55-3 |
|
3-Nitrophenylboronic acid, 97%
| 13331-27-6 |
|
(2S,3R)-2-Amino-3-Hydroxy-4-Methylpentanoic Acid, 99+% e.e.
| 10148-71-7 |
|
4-(Methylthio)phenylboronic acid, 97%
| 98546-51-1 |
|
Starch, mais
| 9005-25-8 |
|
Styrene, P.A., Stabilized With 10-15 ppm p-Tert-Butylcatechol
| 100-42-5 |
|
3-Thiopheneboronic acid, 97%
| 6165-69-1 |
|
1,3-Dichloro-1,1,3,3-tetraisopropyldisiloxane, 96% (GC)
| 69304-37-6 |
|
2-Thiopheneboronic acid
| 6165-68-0 |
|
1-Naphthaleneboronic Acid, 97%
| 13922-41-3 |
|
n-Hexylboronic Acid
| 16343-08-1 |
|
Sucrose
| 57-50-1 |
|
Sulfamic Acid, 98+%
| 5329-14-6 |
|
Sulfanilamide, 98%
| 63-74-1 |
|
Ethyl 2-amino-1-cyclopentene-1-carboxylate 99%
| |
|
Sulfanilic Acid, 99+%
| 121-57-3 |
|
|