**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 13061-96-6 |Methylboronic acid | 97 | unlisted |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XI
Risk Phrases: 36/37/38
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Irritating to eyes, respiratory system and skin.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation. May be harmful if absorbed through the skin.
Ingestion:
May cause irritation of the digestive tract. May be harmful if
swallowed.
Inhalation:
Causes respiratory tract irritation. May be harmful if inhaled.
Chronic:
Chronic poisoning by boron compounds, borism, may be little more
than dry skin and mucous membranes, followed by appearance of a red
tongue, patchy alopecia (hair loss), cracked lips, and
conjunctivitis. Prolonged absorption of boron compounds may cause
anorexia, vomiting, mild diarrhea, skin rash, alopecia, convulsions,
weakness, confusion, menstrual disorders, and anemia.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes.
Ingestion:
Get medical aid. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container. Avoid generating dusty conditions. Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Use with adequate ventilation. Minimize dust generation and
accumulation. Avoid contact with eyes, skin, and clothing. Avoid
breathing dust.
Storage:
Store in a cool, dry place. Store in a tightly closed container.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 13061-96-6:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Solid
Color: white - off-white
Odor: odorless
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 91 - 94 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: Soluble.
Specific Gravity/Density:
Molecular Formula: CH5BO2
Molecular Weight: 59.86
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Dust generation.
Incompatibilities with Other Materials:
Strong oxidizing agents, strong acids, strong bases.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide, boron oxides.
Hazardous Polymerization: Will not occur.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 13061-96-6 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Methylboronic acid -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing Group:
IMO
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing Group:
RID/ADR
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing group:
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI
Risk Phrases:
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 37/39 Wear suitable gloves and eye/face
protection.
WGK (Water Danger/Protection)
CAS# 13061-96-6: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 13061-96-6 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 13061-96-6 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/24/1999 Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Sodium peroxide, p.a.
| 1313-60-6 |
|
(+)-(1S,2R)-2-Amino-1-Cyclopentanecarboxylic Acid
| 64191-14-6 |
|
1,2,3,4-Tetrahydroisoquinoline-3-carboxylic acid hydrochloride, 98%
| 35186-99-3 |
|
2-Amino-3-Chloro-5-Nitrobenzonitrile, 98%
| 20352-84-5 |
|
Sodium phosphate, dibasic heptahydrate, reagent ACS, crystals
| 7558-79-4 |
|
Adipic Acid Monomethyl Ester, 98%
| 627-91-8 |
|
4-Methyl-3-nitrophenol, 98%
| 2042-14-0 |
|
6-Fluoroindole, 98%
| 399-51-9 |
|
Potassium sodium tartrate tetrahydrate, p.a.
| 6381-59-5 |
|
Methylboronic acid, 97%
| 13061-96-6 |
|
Sodium Pyrophosphate Decahydrate, P.A.
| 13472-36-1 |
|
Dotriacontane, 99% (GC)
| 544-85-4 |
|
Salicylic Acid, Sodium Salt, P.A.
| 54-21-7 |
|
Sodium sulfate, powder, anhydrous, 99%, p.a.
| 7757-82-6 |
|
4-Chlorobenzyl Chloride, 99+% (GC)
| 104-83-6 |
|
Sodium Sulfite, Anhydrous, P.A.
| 7757-83-7 |
|
Sodium Thiocyanate, Reagent ACS (Crystals)
| 540-72-7 |
|
3-Tolylboronic acid, 97%
| 17933-03-8 |
|
4-Tolylboronic acid, 97%
| 5720-05-8 |
|
4-Chlorophenylboronic Acid, 97%
| 1679-18-1 |
|
3-Fluorophenylboronic Acid, 97%
| 768-35-4 |
|
Sodium Thiosulfate, Anhydrous
| 7772-98-7 |
|
4-Carboxyphenylboronic Acid, 97%
| 14047-29-1 |
|
3-Carboxyphenylboronic acid, 98%
| 25487-66-5 |
|
2-Carboxyphenylboronic acid, 97%
| 149105-19-1 |
|
2-Methoxyphenylboronic Acid, 97%
| 5720-06-9 |
|
Hexahydro-4-Methylphthalic Anhydride, 98% Mixture of Cis and Trans
| 19438-60-9 |
|
Sodium Thiosulfate Pentahydrate, P.A.
| 10102-17-7 |
|
Sodium Tripolyphosphate, Tech., 85%
| 7758-29-4 |
|
Sodium tungstate, dihydrate, reagent acs
| 10213-10-2 |
|
Biuret, 99% (TLC)
| 108-19-0 |
|
Tin(IV) Chloride, 99.999%
| 7646-78-8 |
|
Tin (II) Chloride, Anhydrous, 98%
| 7772-99-8 |
|
Tin (II) Oxide, 98+%
| 21651-19-4 |
|
Tin (II) Sulfate, 99%
| 7488-55-3 |
|
3-Nitrophenylboronic acid, 97%
| 13331-27-6 |
|
(2S,3R)-2-Amino-3-Hydroxy-4-Methylpentanoic Acid, 99+% e.e.
| 10148-71-7 |
|
4-(Methylthio)phenylboronic acid, 97%
| 98546-51-1 |
|
Starch, mais
| 9005-25-8 |
|
Styrene, P.A., Stabilized With 10-15 ppm p-Tert-Butylcatechol
| 100-42-5 |
|
3-Thiopheneboronic acid, 97%
| 6165-69-1 |
|
1,3-Dichloro-1,1,3,3-tetraisopropyldisiloxane, 96% (GC)
| 69304-37-6 |
|
2-Thiopheneboronic acid
| 6165-68-0 |
|
1-Naphthaleneboronic Acid, 97%
| 13922-41-3 |
|
n-Hexylboronic Acid
| 16343-08-1 |
|
Sucrose
| 57-50-1 |
|
Sulfamic Acid, 98+%
| 5329-14-6 |
|
Sulfanilamide, 98%
| 63-74-1 |
|
Ethyl 2-amino-1-cyclopentene-1-carboxylate 99%
| |
|
Sulfanilic Acid, 99+%
| 121-57-3 |
|
|