**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 7488-55-3 |TIN(II) SULFATE | 99 | 231-302-2 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XI
Risk Phrases: 36/37
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Irritating to eyes and respiratory system.Moisture sensitive.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation. Prolonged and/or repeated contact may
cause irritation and/or dermatitis.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea. Ingested inorganic tin exhibits only moderate toxicity due
to poor absorption and rapid tissue turnover. Ingestion of large
amounts may cause gastrointestinal irritation, nausea, cramps,
vomiting and diarrhea. May interfere with various enzyme systems.
Inorganic tin salts may cause systemic effects on the central nervous
system, heart and liver.
Inhalation:
May cause respiratory tract irritation. Irritation may lead to
chemical pneumonitis and pulmonary edema. Inhalation of fumes may
cause metal fume fever, which is characterized by flu-like symptoms
with metallic taste, fever, chills, cough, weakness, chest pain,
muscle pain and increased white blood cell count. May cause chemical
bronchitis with coughing and difficulty in breathing. When inhaled as
a dust or fume, may cause benign pneumoconiosis.
Chronic:
Prolonged or repeated skin contact may cause dermatitis. Adverse
reproductive effects have been reported in animals. Chronic exposure
to tin oxide dusts and fumes may result in stannosis (benign
pneumoconiosis).
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Immediately flush skin with plenty of water for at
least 15 minutes while removing contaminated clothing and shoes.
Wash clothing before reuse.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Get medical aid.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion.
Extinguishing Media:
For small fires, use water spray, dry chemical, carbon dioxide or
chemical foam. Do NOT get water inside containers.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Clean up spills immediately, observing precautions in the Protective
Equipment section. Sweep up, then place into a suitable container for
disposal. Avoid generating dusty conditions. Provide ventilation. Do
not get water inside containers.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use with adequate ventilation. Minimize dust
generation and accumulation. Avoid contact with skin and eyes. Keep
container tightly closed. Avoid ingestion and inhalation. Do not
allow contact with water. Keep from contact with moist air and
steam.
Storage:
Store in a cool, dry, well-ventilated area away from incompatible
substances. Keep away from water. Store protected from moisture.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 7488-55-3:
United Kingdom, WEL - TWA: (listed as tin inorganic compounds): 2
mg/m3 TWA (except SnH4, as Sn)
United Kingdom, WEL - STEL: (listed as tin inorganic compounds):
mg/m3 STEL (except SnH4, as Sn)
United States OSHA: 2 mg/m3 TWA (as Sn) (listed under Tin inorga
compounds).
Belgium - TWA: (listed as tin inorganic compounds): 2 mg/m3 VLE (
Sn)
Malaysia: (listed as tin inorganic compounds): 2 mg/m3 TWA (as Sn
except tin hydride)
Netherlands: (listed as tin inorganic compounds): 2 mg/m3 MAC (as
Spain: (listed as tin inorganic compounds): 2 mg/m3 VLA-ED (as Sn
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Solid
Color: white to yellow
Odor: none reported
pH: acidic (in solution)
Vapor Pressure: Negligible.
Viscosity: Not available.
Boiling Point: Not applicable.
Freezing/Melting Point: 712 deg F
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: 712 deg F
Solubility in water: soluble in water
Specific Gravity/Density: 3.95 @ 20C
Molecular Formula: O4SSn
Molecular Weight: 214.7476
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures. May decompose on
exposure to moist air or water.
Conditions to Avoid:
High temperatures, incompatible materials, moisture.
Incompatibilities with Other Materials:
Moisture, strong oxidizing agents.
Hazardous Decomposition Products:
Oxides of sulfur, irritating and toxic fumes and gases, tin/tin
oxides.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 7488-55-3: WT1255000
LD50/LC50:
CAS# 7488-55-3: Oral, mouse: LD50 = 2152 mg/kg; Oral, rat: LD50 =
2207 mg/kg.
Carcinogenicity:
TIN(II) SULFATE -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI
Risk Phrases:
R 36/37 Irritating to eyes and respiratory system.
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 7488-55-3: No information available.
Canada
CAS# 7488-55-3 is listed on Canada's DSL List.
CAS# 7488-55-3 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 7488-55-3 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 5/04/1999 Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Sodium peroxide, p.a.
| 1313-60-6 |
|
(+)-(1S,2R)-2-Amino-1-Cyclopentanecarboxylic Acid
| 64191-14-6 |
|
1,2,3,4-Tetrahydroisoquinoline-3-carboxylic acid hydrochloride, 98%
| 35186-99-3 |
|
2-Amino-3-Chloro-5-Nitrobenzonitrile, 98%
| 20352-84-5 |
|
Sodium phosphate, dibasic heptahydrate, reagent ACS, crystals
| 7558-79-4 |
|
Adipic Acid Monomethyl Ester, 98%
| 627-91-8 |
|
4-Methyl-3-nitrophenol, 98%
| 2042-14-0 |
|
6-Fluoroindole, 98%
| 399-51-9 |
|
Potassium sodium tartrate tetrahydrate, p.a.
| 6381-59-5 |
|
Methylboronic acid, 97%
| 13061-96-6 |
|
Sodium Pyrophosphate Decahydrate, P.A.
| 13472-36-1 |
|
Dotriacontane, 99% (GC)
| 544-85-4 |
|
Salicylic Acid, Sodium Salt, P.A.
| 54-21-7 |
|
Sodium sulfate, powder, anhydrous, 99%, p.a.
| 7757-82-6 |
|
4-Chlorobenzyl Chloride, 99+% (GC)
| 104-83-6 |
|
Sodium Sulfite, Anhydrous, P.A.
| 7757-83-7 |
|
Sodium Thiocyanate, Reagent ACS (Crystals)
| 540-72-7 |
|
3-Tolylboronic acid, 97%
| 17933-03-8 |
|
4-Tolylboronic acid, 97%
| 5720-05-8 |
|
4-Chlorophenylboronic Acid, 97%
| 1679-18-1 |
|
3-Fluorophenylboronic Acid, 97%
| 768-35-4 |
|
Sodium Thiosulfate, Anhydrous
| 7772-98-7 |
|
4-Carboxyphenylboronic Acid, 97%
| 14047-29-1 |
|
3-Carboxyphenylboronic acid, 98%
| 25487-66-5 |
|
2-Carboxyphenylboronic acid, 97%
| 149105-19-1 |
|
2-Methoxyphenylboronic Acid, 97%
| 5720-06-9 |
|
Hexahydro-4-Methylphthalic Anhydride, 98% Mixture of Cis and Trans
| 19438-60-9 |
|
Sodium Thiosulfate Pentahydrate, P.A.
| 10102-17-7 |
|
Sodium Tripolyphosphate, Tech., 85%
| 7758-29-4 |
|
Sodium tungstate, dihydrate, reagent acs
| 10213-10-2 |
|
Biuret, 99% (TLC)
| 108-19-0 |
|
Tin(IV) Chloride, 99.999%
| 7646-78-8 |
|
Tin (II) Chloride, Anhydrous, 98%
| 7772-99-8 |
|
Tin (II) Oxide, 98+%
| 21651-19-4 |
|
Tin (II) Sulfate, 99%
| 7488-55-3 |
|
3-Nitrophenylboronic acid, 97%
| 13331-27-6 |
|
(2S,3R)-2-Amino-3-Hydroxy-4-Methylpentanoic Acid, 99+% e.e.
| 10148-71-7 |
|
4-(Methylthio)phenylboronic acid, 97%
| 98546-51-1 |
|
Starch, mais
| 9005-25-8 |
|
Styrene, P.A., Stabilized With 10-15 ppm p-Tert-Butylcatechol
| 100-42-5 |
|
3-Thiopheneboronic acid, 97%
| 6165-69-1 |
|
1,3-Dichloro-1,1,3,3-tetraisopropyldisiloxane, 96% (GC)
| 69304-37-6 |
|
2-Thiopheneboronic acid
| 6165-68-0 |
|
1-Naphthaleneboronic Acid, 97%
| 13922-41-3 |
|
n-Hexylboronic Acid
| 16343-08-1 |
|
Sucrose
| 57-50-1 |
|
Sulfamic Acid, 98+%
| 5329-14-6 |
|
Sulfanilamide, 98%
| 63-74-1 |
|
Ethyl 2-amino-1-cyclopentene-1-carboxylate 99%
| |
|
Sulfanilic Acid, 99+%
| 121-57-3 |
|
|