**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 106-35-4 |3-Heptanone | 98 | 203-388-1 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN
Risk Phrases: 10 36 20
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Flammable. Irritating to eyes. Harmful by inhalation.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation. May be harmful if absorbed through the
skin.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea. May be harmful if swallowed.
Inhalation:
May cause respiratory tract irritation. Vapors may cause dizziness
or suffocation. Harmful if inhaled.
Chronic:
Prolonged or repeated skin contact may cause dermatitis.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Remove
contaminated clothing and shoes.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Vapors may form an explosive mixture with air.
Vapors can travel to a source of ignition and flash back. Will burn
if involved in a fire. Use water spray to keep fire-exposed
containers cool. Containers may explode in the heat of a fire.
Flammable liquid and vapor. Vapors may be heavier than air. They can
spread along the ground and collect in low or confined areas.
Extinguishing Media:
For small fires, use dry chemical, carbon dioxide, water spray or
alcohol-resistant foam. For large fires, use water spray, fog, or
alcohol-resistant foam. Water may be ineffective. Do NOT use
straight streams of water.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Avoid runoff into storm sewers and
ditches which lead to waterways. Clean up spills immediately,
observing precautions in the Protective Equipment section. Remove all
sources of ignition. Use a spark-proof tool. Provide ventilation. A
vapor suppressing foam may be used to reduce vapors.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Use only in a well-ventilated area.
Ground and bond containers when transferring material. Use
spark-proof tools and explosion proof equipment. Avoid contact with
eyes, skin, and clothing. Empty containers retain product residue,
(liquid and/or vapor), and can be dangerous. Keep away from heat,
sparks and flame. Avoid ingestion and inhalation. Do not pressurize,
cut, weld, braze, solder, drill, grind, or expose empty containers to
heat, sparks or open flames.
Storage:
Keep away from sources of ignition. Store in a tightly closed
container. Store in a cool, dry, well-ventilated area away from
incompatible substances. Flammables-area.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate general or
local exhaust ventilation to keep airborne concentrations below the
permissible exposure limits.
Exposure Limits
CAS# 106-35-4:
United Kingdom, WEL - TWA: 35 ppm TWA; 166 mg/m3 TWA
United Kingdom, WEL - STEL: 100 ppm STEL; 475 mg/m3 STEL
United States OSHA: 50 ppm TWA; 230 mg/m3 TWA
Belgium - TWA: 50 ppm VLE; 95 mg/m3 VLE
France - VME: 50 ppm VME; 230 mg/m3 VME
Germany: 10 ppm TWA; 47 mg/m3 TWA
Malaysia: 50 ppm TWA; 234 mg/m3 TWA
Netherlands: 35 ppm MAC; 163 mg/m3 MAC
Spain: 20 ppm VLA-ED; 95 mg/m3 VLA-ED
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Clear liquid
Color: slightly yellow
Odor: fatty odor
pH: Not available.
Vapor Pressure: 5.5 hPa @ 20 C
Viscosity: Not available.
Boiling Point: 146- 149 deg C @ 760.00mmHg
Freezing/Melting Point: -39 deg C
Autoignition Temperature: 390 deg C ( 734.00 deg F)
Flash Point: 41 deg C ( 105.80 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: Insoluble.
Specific Gravity/Density: .8180g/cm3
Molecular Formula: C7H14O
Molecular Weight: 114.19
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, ignition sources, excess heat, strong
oxidants.
Incompatibilities with Other Materials:
Oxidizing agents, reducing agents, bases.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 106-35-4: MJ5250000
LD50/LC50:
CAS# 106-35-4: Draize test, rabbit, eye: 100 mg Mild; Draize test,
rabbit, eye: 500 mg/24H Mild; Draize test, rabbit, skin: 500 mg/24H
Moderate; Oral, rat: LD50 = 2760 mg/kg; Skin, rabbit: LD50 = >20
mL/kg.
Carcinogenicity:
3-Heptanone -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: KETONES, LIQUID, N.O.S.
Hazard Class: 3
UN Number: 1224
Packing Group: III
IMO
Shipping Name: KETONES, LIQUID, N.O.S.
Hazard Class: 3
UN Number: 1224
Packing Group: III
RID/ADR
Shipping Name: KETONES, LIQUID, N.O.S.
Hazard Class: 3
UN Number: 1224
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 10 Flammable.
R 20 Harmful by inhalation.
R 36 Irritating to eyes.
Safety Phrases:
S 9 Keep container in a well-ventilated place.
S 16 Keep away from sources of ignition - No
smoking.
S 24 Avoid contact with skin.
S 33 Take precautionary measures against static
discharges.
WGK (Water Danger/Protection)
CAS# 106-35-4: 1
Canada
CAS# 106-35-4 is listed on Canada's DSL List.
CAS# 106-35-4 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 106-35-4 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 5/22/1998 Revision #3 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
2,3-Butanedione monoxime, 96% (uv-vis)
| 57-71-6 |
|
Dimethylglyoxime, reagent ACS
| 95-45-4 |
|
Methyl 3,5-Dibenzyloxybenzoate, 98%
| 58605-10-0 |
|
Diethylamine, 99+%
| 109-89-7 |
|
Bis(2-hydroxyethyl)ether, 99%
| 111-46-6 |
|
2-Methoxyethyl ether, 99%
| 111-96-6 |
|
2-(2-Butoxyethoxy)-ethanol 99+%
| 112-34-5 |
|
2-(2-Ethoxyethoxy)-Ethanol, 98+%
| 111-90-0 |
|
Diethylenetriamine, 98+%
| 111-40-0 |
|
Diisopropylamine, 99+%
| 108-18-9 |
|
Tris(3,3,4,4,5,5,6,6,7,7,8,8-tridecafluorooctyl)phenyltin
| 175354-30-0 |
|
N,N-Dimethylacetamide, 99+% spectrophotometric grade
| 127-19-5 |
|
Dimethyl phthalate, p.a.
| 131-11-3 |
|
2-Hydroxyethyl acrylate, stabilized, 97%
| 818-61-1 |
|
4-Fluorophenylboronic Acid
| 1765-93-1 |
|
1-(3-Dimethylaminopropyl)-3-Ethylcarbodiimide Methiodide, 98%
| 22572-40-3 |
|
2-Chlorophenothiazine, 99%
| 92-39-7 |
|
Ethyl Butyrylacetate, 98%
| 3249-68-1 |
|
3-Methoxypropylisothiocyanate
| 17702-11-3 |
|
2,6-Dibenzylidenecyclohexanone
| 897-78-9 |
|
(1R,2R)-2-Amino-1-(4-Nitrophenyl)Propane-1,3-Diol, 96%
| 716-61-0 |
|
Docosanoic Acid, Tech. 85%
| 112-85-6 |
|
Silica gel, for column chromatography, 0.035-0.070 mm, pore diameter
| 7631-86-9 |
|
Phenylazoformic acid 2-phenylhydrazide, suitable for colorimetric
| 538-62-5 |
|
sym-Diphenylcarbazide, 99+%
| 140-22-7 |
|
Diphenylamine-4-sulfonic acid sodium salt, reagent acs
| 6152-67-6 |
|
Cis-2, trans-4-hexadiene
| 5194-50-3 |
|
Diphenylthiocarbazone, reagent ACS, 85+% (UV-VIS)
| 60-10-6 |
|
2,6-Diisopropylphenol, 99%
| 2078-54-8 |
|
3-Heptanone, 98%
| 106-35-4 |
|
2,2'-Dipyridyl, 99+%
| 366-18-7 |
|
Dodecane, Spectro Grade, 98% (GC)
| 112-40-3 |
|
Diethyl Acetamidomalonate, 99+%
| 1068-90-2 |
|
Brij 35
| 7732-18-5 |
|
1-(Pyrrolidino)-1-cyclohexene
| 1125-99-1 |
|
(4S)-(+)-4-Benzyl-3-Propionyl-2-Oxazolidinone, 97%
| 101711-78-8 |
|
N-[(1S)-2-Hydroxy-1-Phenethyl)]Ethoxycarboxamide
| 0-01-1 |
|
Dodecyl Sulfate, Sodium Salt, 99%
| 151-21-3 |
|
Eosin B (Cert)
| 548-24-3 |
|
Ethanolamine, scintillation grade (CO2 absorber)
| 141-43-5 |
|
(R)-(+)-2-(tert-Butoxycarbonylamino)-3-phenyl-1-propanol, 98%
| 106454-69-7 |
|
(R)-1-(2-Hydroxy-1-Phenylethyl)-1,5-Dihydropyrrol-2-One
| 158271-95-5 |
|
Chelerythrine chloride
| 3895-92-9 |
|
Cyclopiazonic Acid
| 18172-33-3 |
|
D609 Potassium Salt
| 83373-60-8 |
|
Daidzein, 98%
| 486-66-8 |
|
Fumonisin B1, 98%
| 116355-83-0 |
|
Sodium Tert. Butoxide
| 865-48-5 |
|
1-(4-Hydroxyphenyl)piperazine dihydrobromide
| 38869-37-3 |
|
1,2-Benzenedithiol, 96%
| 17534-15-5 |
|
|