**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 109-89-7 |Diethylamine | > 99 | 203-716-3 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: F C
Risk Phrases: 11 20/21/22 35
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Highly flammable. Harmful by inhalation, in contact with skin and if
swallowed. Causes severe burns.
Potential Health Effects
Eye:
Causes eye burns. Vapors may cause eye irritation.
Skin:
Causes skin burns. May be absorbed through the skin in harmful
amounts. Prolonged or repeated contact may dry/defat the skin and
cause irritation.
Ingestion:
Causes gastrointestinal tract burns. May be harmful if swallowed.
Inhalation:
Inhalation may produce coughing, nausea, and pulmonary edema.
Chronic:
Chronic exposure may cause effects similar to those of acute
exposure.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
In case of contact, immediately flush eyes with plenty of water for
at least 15 minutes. Get medical aid immediately.
Skin:
In case of contact, immediately flush skin with plenty of water for
at least 15 minutes while removing contaminated clothing and shoes.
Get medical aid immediately. Wash clothing before reuse.
Ingestion:
If swallowed, do NOT induce vomiting. Get medical aid immediately.
If victim is fully conscious, give a cupful of water. Never give
anything by mouth to an unconscious person.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial
respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
Use water spray to keep fire-exposed containers cool. Wear
appropriate protective clothing to prevent contact with skin and
eyes. Wear a self-contained breathing apparatus (SCBA) to prevent
contact with thermal decomposition products. Extremely flammable
liquid and vapor. Vapor may cause flash fire. Vapors are heavier than
air and may travel to a source of ignition and flash back. Vapors can
spread along the ground and collect in low or confined areas.
Extinguishing Media:
For small fires, use dry chemical, carbon dioxide, water spray or
alcohol-resistant foam. Water may be ineffective.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Use water spray to dilute spill to
a non-flammable mixture. Use water spray to disperse the gas/vapor.
Remove all sources of ignition. Provide ventilation. Approach spill
from upwind.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Ground and bond containers when transferring material. Use
spark-proof tools and explosion proof equipment. Do not get in eyes,
on skin, or on clothing. Empty containers retain product residue,
(liquid and/or vapor), and can be dangerous. Avoid ingestion and
inhalation. Do not pressurize, cut, weld, braze, solder, drill,
grind, or expose empty containers to heat, sparks or open flames. Use
only with adequate ventilation. Keep away from heat, sparks and
flame.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of
ignition. Store in a tightly closed container. Keep from contact
with oxidizing materials. Store in a cool, dry, well-ventilated area
away from incompatible substances. Keep away from organic halogens.
Keep away from acids.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate general or
local exhaust ventilation to keep airborne concentrations below the
permissible exposure limits.
Exposure Limits
CAS# 109-89-7:
United Kingdom, WEL - TWA: 10 ppm TWA; 30 mg/m3 TWA
United Kingdom, WEL - STEL: 25 ppm STEL; 76 mg/m3 STEL
United States OSHA: 25 ppm TWA; 75 mg/m3 TWA
Belgium - TWA: 5 ppm VLE; 15 mg/m3 VLE
Belgium - STEL: 15 ppm VLE; 46 mg/m3 VLE
France - VLE: 10 ppm VLE; 30 mg/m3 VLE
Germany: 5 ppm TWA; 15 mg/m3 TWA
Germany: Skin absorber
Japan: 10 ppm OEL; 30 mg/m3 OEL
Malaysia: 5 ppm TWA; 15 mg/m3 TWA
Netherlands: 5 ppm MAC; 15 mg/m3 MAC
Russia: 30 mg/m3 TWA
Spain: 10 ppm VLA-ED; 30 mg/m3 VLA-ED
Spain: 25 ppm VLA-EC; 75 mg/m3 VLA-EC
Personal Protective Equipment
Eyes:
Wear chemical splash goggles and face shield.
Skin:
Wear appropriate gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: colorless
Odor: fishy ammonical
pH: very alkaline
Vapor Pressure: 195 mm Hg @ 20 deg C
Viscosity: Not available.
Boiling Point: 55-58 deg C
Freezing/Melting Point: -50 deg C
Autoignition Temperature: 312 deg C ( 593.60 deg F)
Flash Point: -28 deg C ( -18.40 deg F)
Explosion Limits, lower: 1.8
Explosion Limits, upper: 10.1
Decomposition Temperature: Not available.
Solubility in water: Miscible in water
Specific Gravity/Density: 0.71
Molecular Formula: C4H11N
Molecular Weight: 73.13
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Ignition sources, excess heat.
Incompatibilities with Other Materials:
Strong oxidizing agents, acids, epichlorohydrin, cellulose nitrate,
some metals.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, carbon dioxide, amines.
Hazardous Polymerization: Will not occur.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 109-89-7: HZ8750000
LD50/LC50:
CAS# 109-89-7: Inhalation, rat: LC50 = 4000 ppm/4H; Oral, mouse:
LD50 = 500 mg/kg; Oral, rat: LD50 = 540 mg/kg; Skin, rabbit: LD50 =
820 uL/kg.
Carcinogenicity:
Diethylamine -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: DIETHYLAMINE
Hazard Class: 3 (8)
UN Number: 1154
Packing Group: II
IMO
Shipping Name: DIETHYLAMINE
Hazard Class: 3.1 (8)
UN Number: 1154
Packing Group: II
RID/ADR
Shipping Name: DIETHYLAMINE
Hazard Class: 3
UN Number: 1154
Packing group: II
USA RQ: CAS# 109-89-7: 100 lb final RQ; 45.4 kg final RQ
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: F C
Risk Phrases:
R 11 Highly flammable.
R 20/21/22 Harmful by inhalation, in contact with
skin and if swallowed.
R 35 Causes severe burns.
Safety Phrases:
S 3 Keep in a cool place.
S 16 Keep away from sources of ignition - No
smoking.
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 29 Do not empty into drains.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 109-89-7: 1
Canada
CAS# 109-89-7 is listed on Canada's DSL List.
CAS# 109-89-7 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 109-89-7 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 11/13/1997 Revision #3 Date: 9/20/2002
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
2,3-Butanedione monoxime, 96% (uv-vis)
| 57-71-6 |
|
Dimethylglyoxime, reagent ACS
| 95-45-4 |
|
Methyl 3,5-Dibenzyloxybenzoate, 98%
| 58605-10-0 |
|
Diethylamine, 99+%
| 109-89-7 |
|
Bis(2-hydroxyethyl)ether, 99%
| 111-46-6 |
|
2-Methoxyethyl ether, 99%
| 111-96-6 |
|
2-(2-Butoxyethoxy)-ethanol 99+%
| 112-34-5 |
|
2-(2-Ethoxyethoxy)-Ethanol, 98+%
| 111-90-0 |
|
Diethylenetriamine, 98+%
| 111-40-0 |
|
Diisopropylamine, 99+%
| 108-18-9 |
|
Tris(3,3,4,4,5,5,6,6,7,7,8,8-tridecafluorooctyl)phenyltin
| 175354-30-0 |
|
N,N-Dimethylacetamide, 99+% spectrophotometric grade
| 127-19-5 |
|
Dimethyl phthalate, p.a.
| 131-11-3 |
|
2-Hydroxyethyl acrylate, stabilized, 97%
| 818-61-1 |
|
4-Fluorophenylboronic Acid
| 1765-93-1 |
|
1-(3-Dimethylaminopropyl)-3-Ethylcarbodiimide Methiodide, 98%
| 22572-40-3 |
|
2-Chlorophenothiazine, 99%
| 92-39-7 |
|
Ethyl Butyrylacetate, 98%
| 3249-68-1 |
|
3-Methoxypropylisothiocyanate
| 17702-11-3 |
|
2,6-Dibenzylidenecyclohexanone
| 897-78-9 |
|
(1R,2R)-2-Amino-1-(4-Nitrophenyl)Propane-1,3-Diol, 96%
| 716-61-0 |
|
Docosanoic Acid, Tech. 85%
| 112-85-6 |
|
Silica gel, for column chromatography, 0.035-0.070 mm, pore diameter
| 7631-86-9 |
|
Phenylazoformic acid 2-phenylhydrazide, suitable for colorimetric
| 538-62-5 |
|
sym-Diphenylcarbazide, 99+%
| 140-22-7 |
|
Diphenylamine-4-sulfonic acid sodium salt, reagent acs
| 6152-67-6 |
|
Cis-2, trans-4-hexadiene
| 5194-50-3 |
|
Diphenylthiocarbazone, reagent ACS, 85+% (UV-VIS)
| 60-10-6 |
|
2,6-Diisopropylphenol, 99%
| 2078-54-8 |
|
3-Heptanone, 98%
| 106-35-4 |
|
2,2'-Dipyridyl, 99+%
| 366-18-7 |
|
Dodecane, Spectro Grade, 98% (GC)
| 112-40-3 |
|
Diethyl Acetamidomalonate, 99+%
| 1068-90-2 |
|
Brij 35
| 7732-18-5 |
|
1-(Pyrrolidino)-1-cyclohexene
| 1125-99-1 |
|
(4S)-(+)-4-Benzyl-3-Propionyl-2-Oxazolidinone, 97%
| 101711-78-8 |
|
N-[(1S)-2-Hydroxy-1-Phenethyl)]Ethoxycarboxamide
| 0-01-1 |
|
Dodecyl Sulfate, Sodium Salt, 99%
| 151-21-3 |
|
Eosin B (Cert)
| 548-24-3 |
|
Ethanolamine, scintillation grade (CO2 absorber)
| 141-43-5 |
|
(R)-(+)-2-(tert-Butoxycarbonylamino)-3-phenyl-1-propanol, 98%
| 106454-69-7 |
|
(R)-1-(2-Hydroxy-1-Phenylethyl)-1,5-Dihydropyrrol-2-One
| 158271-95-5 |
|
Chelerythrine chloride
| 3895-92-9 |
|
Cyclopiazonic Acid
| 18172-33-3 |
|
D609 Potassium Salt
| 83373-60-8 |
|
Daidzein, 98%
| 486-66-8 |
|
Fumonisin B1, 98%
| 116355-83-0 |
|
Sodium Tert. Butoxide
| 865-48-5 |
|
1-(4-Hydroxyphenyl)piperazine dihydrobromide
| 38869-37-3 |
|
1,2-Benzenedithiol, 96%
| 17534-15-5 |
|
|