**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 111-96-6 |2-Methoxyethyl ether | 99 | 203-924-4 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: T
Risk Phrases: 10 19 60 61
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Flammable. May form explosive peroxides. May impair fertility. May
cause harm to the unborn child.Hygroscopic (absorbs moisture from the
air).
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea. May cause central nervous system depression.
Inhalation:
May cause respiratory tract irritation. Exposure produces central
nervous system depression.
Chronic:
May cause reproductive and fetal effects.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
In case of contact, immediately flush eyes with plenty of water for
at least 15 minutes. Get medical aid.
Skin:
In case of contact, flush skin with plenty of water. Remove
contaminated clothing and shoes. Get medical aid if irritation
develops and persists. Wash clothing before reuse.
Ingestion:
If swallowed, do not induce vomiting unless directed to do so by
medical personnel. Never give anything by mouth to an unconscious
person. Get medical aid.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial
respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Use water
spray to keep fire-exposed containers cool. Containers may explode in
the heat of a fire. Flammable liquid and vapor. Vapors are heavier
than air and may travel to a source of ignition and flash back.
Vapors can spread along the ground and collect in low or confined
areas. May accumulate static electricity.
Extinguishing Media:
Use water spray, dry chemical, or carbon dioxide.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Clean up spills immediately,
observing precautions in the Protective Equipment section. Remove all
sources of ignition. Use a spark-proof tool. Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Ground and bond containers when transferring material. Avoid contact
with eyes, skin, and clothing. Empty containers retain product
residue, (liquid and/or vapor), and can be dangerous. If peroxide
formation is suspected, do not open or move container. Do not
pressurize, cut, weld, braze, solder, drill, grind, or expose empty
containers to heat, sparks or open flames. Use only with adequate
ventilation. Keep away from heat and flame. Avoid breathing vapor or
mist.
Storage:
Keep away from heat, sparks, and flame. Store in a tightly closed
container. Keep from contact with oxidizing materials. Store in a
cool, dry, well-ventilated area away from incompatible substances.
Storage under a nitrogen blanket has been recommended. Containers
should be dated when opened and tested periodically for the presence
of peroxides. Should crystals form in a peroxidizable liquid,
peroxidation may have occurred and the product should be considered
extremely dangerous. In this instance, the container should only be
opened remotely by professionals. All peroxidizable substances
should be stored away from heat and light and be protected from
ignition sources.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use process enclosure, local exhaust ventilation, or other
engineering controls to control airborne levels.
Exposure Limits
CAS# 111-96-6:
Germany: 5 ppm TWA; 28 mg/m3 TWA
Germany: Skin absorber
Netherlands: 5 ppm MAC; 27 mg/m3 MAC
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: clear, colorless
Odor: ethereal odor
pH: Not available.
Vapor Pressure: 3.0 mm Hg @ 25 deg C
Viscosity: 1.14 mPa s 20 C
Boiling Point: 162 deg C @ 760 mm Hg
Freezing/Melting Point: -64 deg C
Autoignition Temperature: 170 deg C ( 338.00 deg F)
Flash Point: 55 deg C ( 131.00 deg F)
Explosion Limits, lower: 1.5
Explosion Limits, upper: 17.4
Decomposition Temperature: Not available.
Solubility in water: Soluble.
Specific Gravity/Density: .9370
Molecular Formula: C6H14O3
Molecular Weight: 134.18
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Under normal storage conditions, peroxidizable compounds can form
and accumulate peroxides which may explode when subjected to heat or
shock. This material is most hazardous when peroxide levels are
concentrated by distillation or evaporation.
Conditions to Avoid:
High temperatures, light, ignition sources, exposure to air, exposure
to moist air or water.
Incompatibilities with Other Materials:
Strong oxidizing agents, sulfuric acid, isocyanates, perchloric acid,
metal halides.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 111-96-6: KN3339000
LD50/LC50:
CAS# 111-96-6: Oral, mouse: LD50 = 6 gm/kg; Oral, rat: LD50 = 5400
mg/kg.
Carcinogenicity:
2-Methoxyethyl ether -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Other
No information available.
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: Ethers, N.O.S.
Hazard Class: 3
UN Number: 3271
Packing Group: III
IMO
Shipping Name: ETHERS, N.O.S.
Hazard Class: 3.3
UN Number: 3271
Packing Group: III
RID/ADR
Shipping Name: Ethers, N.O.S.
Hazard Class: 3
UN Number: 3271
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T
Risk Phrases:
R 61 May cause harm to the unborn child.
R 10 Flammable.
R 19 May form explosive peroxides.
R 60 May impair fertility.
Safety Phrases:
S 53 Avoid exposure - obtain special instructions
before use.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 111-96-6: 1
Canada
CAS# 111-96-6 is listed on Canada's DSL List.
CAS# 111-96-6 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 111-96-6 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 5/01/1998 Revision #5 Date: 10/05/2004
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
2,3-Butanedione monoxime, 96% (uv-vis)
| 57-71-6 |
|
Dimethylglyoxime, reagent ACS
| 95-45-4 |
|
Methyl 3,5-Dibenzyloxybenzoate, 98%
| 58605-10-0 |
|
Diethylamine, 99+%
| 109-89-7 |
|
Bis(2-hydroxyethyl)ether, 99%
| 111-46-6 |
|
2-Methoxyethyl ether, 99%
| 111-96-6 |
|
2-(2-Butoxyethoxy)-ethanol 99+%
| 112-34-5 |
|
2-(2-Ethoxyethoxy)-Ethanol, 98+%
| 111-90-0 |
|
Diethylenetriamine, 98+%
| 111-40-0 |
|
Diisopropylamine, 99+%
| 108-18-9 |
|
Tris(3,3,4,4,5,5,6,6,7,7,8,8-tridecafluorooctyl)phenyltin
| 175354-30-0 |
|
N,N-Dimethylacetamide, 99+% spectrophotometric grade
| 127-19-5 |
|
Dimethyl phthalate, p.a.
| 131-11-3 |
|
2-Hydroxyethyl acrylate, stabilized, 97%
| 818-61-1 |
|
4-Fluorophenylboronic Acid
| 1765-93-1 |
|
1-(3-Dimethylaminopropyl)-3-Ethylcarbodiimide Methiodide, 98%
| 22572-40-3 |
|
2-Chlorophenothiazine, 99%
| 92-39-7 |
|
Ethyl Butyrylacetate, 98%
| 3249-68-1 |
|
3-Methoxypropylisothiocyanate
| 17702-11-3 |
|
2,6-Dibenzylidenecyclohexanone
| 897-78-9 |
|
(1R,2R)-2-Amino-1-(4-Nitrophenyl)Propane-1,3-Diol, 96%
| 716-61-0 |
|
Docosanoic Acid, Tech. 85%
| 112-85-6 |
|
Silica gel, for column chromatography, 0.035-0.070 mm, pore diameter
| 7631-86-9 |
|
Phenylazoformic acid 2-phenylhydrazide, suitable for colorimetric
| 538-62-5 |
|
sym-Diphenylcarbazide, 99+%
| 140-22-7 |
|
Diphenylamine-4-sulfonic acid sodium salt, reagent acs
| 6152-67-6 |
|
Cis-2, trans-4-hexadiene
| 5194-50-3 |
|
Diphenylthiocarbazone, reagent ACS, 85+% (UV-VIS)
| 60-10-6 |
|
2,6-Diisopropylphenol, 99%
| 2078-54-8 |
|
3-Heptanone, 98%
| 106-35-4 |
|
2,2'-Dipyridyl, 99+%
| 366-18-7 |
|
Dodecane, Spectro Grade, 98% (GC)
| 112-40-3 |
|
Diethyl Acetamidomalonate, 99+%
| 1068-90-2 |
|
Brij 35
| 7732-18-5 |
|
1-(Pyrrolidino)-1-cyclohexene
| 1125-99-1 |
|
(4S)-(+)-4-Benzyl-3-Propionyl-2-Oxazolidinone, 97%
| 101711-78-8 |
|
N-[(1S)-2-Hydroxy-1-Phenethyl)]Ethoxycarboxamide
| 0-01-1 |
|
Dodecyl Sulfate, Sodium Salt, 99%
| 151-21-3 |
|
Eosin B (Cert)
| 548-24-3 |
|
Ethanolamine, scintillation grade (CO2 absorber)
| 141-43-5 |
|
(R)-(+)-2-(tert-Butoxycarbonylamino)-3-phenyl-1-propanol, 98%
| 106454-69-7 |
|
(R)-1-(2-Hydroxy-1-Phenylethyl)-1,5-Dihydropyrrol-2-One
| 158271-95-5 |
|
Chelerythrine chloride
| 3895-92-9 |
|
Cyclopiazonic Acid
| 18172-33-3 |
|
D609 Potassium Salt
| 83373-60-8 |
|
Daidzein, 98%
| 486-66-8 |
|
Fumonisin B1, 98%
| 116355-83-0 |
|
Sodium Tert. Butoxide
| 865-48-5 |
|
1-(4-Hydroxyphenyl)piperazine dihydrobromide
| 38869-37-3 |
|
1,2-Benzenedithiol, 96%
| 17534-15-5 |
|
|