**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 5194-50-3 |cis-2, trans-4-Hexadiene | 95% | 225-979-3 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XI F
Risk Phrases: 11 36/37
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Highly flammable. Irritating to eyes and respiratory system.
Potential Health Effects
The toxicological properties of this material have not been
investigated. Use appropriate procedures to prevent opportunities
for direct contact with the skin or eyes and to prevent inhalation.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Immediately flush
eyes with plenty of water for at least 15 minutes, occasionally
lifting the upper and lower eyelids. Get medical aid immediately.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Remove
contaminated clothing and shoes.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Get medical aid immediately. Do NOT induce vomiting. If conscious and
alert, rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Flammable liquid and vapor.
Extinguishing Media:
In case of fire, use water, dry chemical, chemical foam, or
alcohol-resistant foam. Use agent most appropriate to extinguish
fire.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Clean up spills immediately,
observing precautions in the Protective Equipment section. Sweep up,
then place into a suitable container for disposal.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Empty containers retain product residue, (liquid and/or vapor), and
can be dangerous. Keep away from heat, sparks and flame.
Storage:
Keep away from heat, sparks, and flame. Flammables-area.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use adequate general or local exhaust ventilation to keep airborne
concentrations below the permissible exposure limits. Use process
enclosure, local exhaust ventilation, or other engineering controls
to control airborne levels.
Exposure Limits
CAS# 5194-50-3:
Personal Protective Equipment
Eyes:
Not available.
Skin:
Wear appropriate protective gloves and clothing to
prevent skin exposure. Wear appropriate protective
gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to minimize
contact with skin.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use. Wear a NIOSH/MSHA
or European Standard EN 149 approved full-facepiece
airline respirator in the positive pressure mode with
emergency escape provisions.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Not available.
Color: Clearlight yellow liquid
Odor: None reported.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 80.0 - 82.0 deg C @ 760.00mm Hg
Freezing/Melting Point: 0 deg C
Autoignition Temperature: Not available.
Flash Point: -7 deg C ( 19.40 deg F)
Explosion Limits, lower: .06 vol %
Explosion Limits, upper: .02 vol %
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density: .7200g/cm3
Molecular Formula: CH3CH=CHCH=CHCH3
Molecular Weight: 82.13
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, strong oxidants.
Incompatibilities with Other Materials:
Oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, irritating and toxic fumes and gases, carbon
dioxide, hydrogen bromide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 5194-50-3 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
cis-2, trans-4-Hexadiene -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: HEXADIENE
Hazard Class: 3
UN Number: 2458
Packing Group: II
IMO
Shipping Name: HEXADIENE
Hazard Class: 3
UN Number: 2458
Packing Group: II
RID/ADR
Shipping Name: HEXADIENES
Hazard Class: 3
UN Number: 2458
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI F
Risk Phrases:
R 11 Highly flammable.
R 36/37 Irritating to eyes and respiratory system.
Safety Phrases:
S 16 Keep away from sources of ignition - No
smoking.
WGK (Water Danger/Protection)
CAS# 5194-50-3: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 5194-50-3 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 5194-50-3 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/02/1997 Revision #2 Date: 4/04/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
2,3-Butanedione monoxime, 96% (uv-vis)
| 57-71-6 |
|
Dimethylglyoxime, reagent ACS
| 95-45-4 |
|
Methyl 3,5-Dibenzyloxybenzoate, 98%
| 58605-10-0 |
|
Diethylamine, 99+%
| 109-89-7 |
|
Bis(2-hydroxyethyl)ether, 99%
| 111-46-6 |
|
2-Methoxyethyl ether, 99%
| 111-96-6 |
|
2-(2-Butoxyethoxy)-ethanol 99+%
| 112-34-5 |
|
2-(2-Ethoxyethoxy)-Ethanol, 98+%
| 111-90-0 |
|
Diethylenetriamine, 98+%
| 111-40-0 |
|
Diisopropylamine, 99+%
| 108-18-9 |
|
Tris(3,3,4,4,5,5,6,6,7,7,8,8-tridecafluorooctyl)phenyltin
| 175354-30-0 |
|
N,N-Dimethylacetamide, 99+% spectrophotometric grade
| 127-19-5 |
|
Dimethyl phthalate, p.a.
| 131-11-3 |
|
2-Hydroxyethyl acrylate, stabilized, 97%
| 818-61-1 |
|
4-Fluorophenylboronic Acid
| 1765-93-1 |
|
1-(3-Dimethylaminopropyl)-3-Ethylcarbodiimide Methiodide, 98%
| 22572-40-3 |
|
2-Chlorophenothiazine, 99%
| 92-39-7 |
|
Ethyl Butyrylacetate, 98%
| 3249-68-1 |
|
3-Methoxypropylisothiocyanate
| 17702-11-3 |
|
2,6-Dibenzylidenecyclohexanone
| 897-78-9 |
|
(1R,2R)-2-Amino-1-(4-Nitrophenyl)Propane-1,3-Diol, 96%
| 716-61-0 |
|
Docosanoic Acid, Tech. 85%
| 112-85-6 |
|
Silica gel, for column chromatography, 0.035-0.070 mm, pore diameter
| 7631-86-9 |
|
Phenylazoformic acid 2-phenylhydrazide, suitable for colorimetric
| 538-62-5 |
|
sym-Diphenylcarbazide, 99+%
| 140-22-7 |
|
Diphenylamine-4-sulfonic acid sodium salt, reagent acs
| 6152-67-6 |
|
Cis-2, trans-4-hexadiene
| 5194-50-3 |
|
Diphenylthiocarbazone, reagent ACS, 85+% (UV-VIS)
| 60-10-6 |
|
2,6-Diisopropylphenol, 99%
| 2078-54-8 |
|
3-Heptanone, 98%
| 106-35-4 |
|
2,2'-Dipyridyl, 99+%
| 366-18-7 |
|
Dodecane, Spectro Grade, 98% (GC)
| 112-40-3 |
|
Diethyl Acetamidomalonate, 99+%
| 1068-90-2 |
|
Brij 35
| 7732-18-5 |
|
1-(Pyrrolidino)-1-cyclohexene
| 1125-99-1 |
|
(4S)-(+)-4-Benzyl-3-Propionyl-2-Oxazolidinone, 97%
| 101711-78-8 |
|
N-[(1S)-2-Hydroxy-1-Phenethyl)]Ethoxycarboxamide
| 0-01-1 |
|
Dodecyl Sulfate, Sodium Salt, 99%
| 151-21-3 |
|
Eosin B (Cert)
| 548-24-3 |
|
Ethanolamine, scintillation grade (CO2 absorber)
| 141-43-5 |
|
(R)-(+)-2-(tert-Butoxycarbonylamino)-3-phenyl-1-propanol, 98%
| 106454-69-7 |
|
(R)-1-(2-Hydroxy-1-Phenylethyl)-1,5-Dihydropyrrol-2-One
| 158271-95-5 |
|
Chelerythrine chloride
| 3895-92-9 |
|
Cyclopiazonic Acid
| 18172-33-3 |
|
D609 Potassium Salt
| 83373-60-8 |
|
Daidzein, 98%
| 486-66-8 |
|
Fumonisin B1, 98%
| 116355-83-0 |
|
Sodium Tert. Butoxide
| 865-48-5 |
|
1-(4-Hydroxyphenyl)piperazine dihydrobromide
| 38869-37-3 |
|
1,2-Benzenedithiol, 96%
| 17534-15-5 |
|
|