**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 106-51-4 |Quinone | 100 | 203-405-2 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: T N
Risk Phrases: 23/25 36/37/38 50
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Toxic by inhalation and if swallowed. Irritating to eyes,
respiratory system and skin. Very toxic to aquatic organisms.
Potential Health Effects
Eye:
Causes severe eye burns. Contact may cause discoloration, redness,
swelling, and formation of eye lesions. May cause corneal edema,
ulceration, and scarring. Prolonged exposure to vapor can lead to
gradual deposition of pigment in the cornea and conjunctiva which
may result in severe visual disturbances. Causes small opacities of
the cornea and structural corneal changes that result in loss of
visual activity.
Skin:
Causes skin irritation. Depigmentation and skin lesions may occur.
May cause discoloration, erythema (redness), swelling, and the
formation of papules and vesicles (blisters). Prolonged contact may
lead to necrosis.
Ingestion:
Harmful if swallowed. May cause irritation of the digestive tract.
Ingestion may cause convulsions, seizures and possible coma.
Inhalation:
Causes respiratory tract irritation. May cause adverse central
nervous system effects including headache, convulsions, and possible
death. May produce asphyxia due to pulmonary damage and effects on
the hemoglobin. May produce clonic convulsions, respiratory
difficulties, decreased blood pressure and death due to medullary
centers.
Chronic:
Prolonged or repeated exposure may cause permanent eye damage.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately. Do NOT allow victim to rub eyes or keep eyes closed.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical
aid immediately.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
Antidote:
None reported.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Dusts at sufficient concentrations can form
explosive mixtures with air.
Extinguishing Media:
In case of fire, use water, dry chemical, chemical foam, or
alcohol-resistant foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Sweep up, then place into a suitable container for disposal. Avoid
generating dusty conditions. Remove all sources of ignition. Provide
ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use only in a well-ventilated area. Minimize dust
generation and accumulation. May form flammable dust-air mixtures.
Do not get in eyes, on skin, or on clothing. Keep container tightly
closed. Do not ingest or inhale.
Storage:
Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use adequate general or local exhaust ventilation to keep airborne
concentrations below the permissible exposure limits.
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Always use
a NIOSH or European Standard EN 149 approved
respirator when necessary.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Solid
Color: yellow or green
Odor: chlorine-like
pH: Not available.
Vapor Pressure: Negligible
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 113 - 115 C
Autoignition Temperature: 815 deg F ( 435.00 deg C)
Flash Point: 100-200F
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: Not available.
Solubility in water: Slightly soluble in water.
Specific Gravity/Density: 1.3180
Molecular Formula: C6H4O2
Molecular Weight: 108.0268
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
High temperatures, incompatible materials.
Incompatibilities with Other Materials:
Oxidizing agents. Attacks some forms of coatings, plastics and
rubber.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide.
Hazardous Polymerization: Will not occur.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 106-51-4: DK2625000
LD50/LC50:
CAS# 106-51-4: Oral, mouse: LD50 = 25 mg/kg; Oral, rat: LD50 = 130
mg/kg.
Carcinogenicity:
Quinone -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Ecotoxicity:
Fish: Rainbow trout: LC50 = 0.125 mg/L; 96 Hr.; UnspecifiedFish:
Fathead Minnow: LC50 = 0.045 mg/L; 96 Hr.; UnspecifiedBacteria:
Phytobacterium phosphoreum: EC50 =2.09 mg/L; 5-30 minutes; Microtox
test
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Products which are considered hazardous for supply are classified as Special
Waste and the disposal of such chemicals is covered by regulations which may
vary according to location. Contact a specialist disposal company or the local
waste regulator for advice. Empty containers must be decontaminated before
returning for recycling.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: BENZOQUINONE
Hazard Class: 6.1
UN Number: 2587
Packing Group: II
IMO
Shipping Name: BENZOQUINONE
Hazard Class: 6.1
UN Number: 2587
Packing Group: II
RID/ADR
Shipping Name: BENZOQUINONE
Hazard Class: 6.1
UN Number: 2587
Packing group: II
USA RQ:CAS# 106-51-4: 10 lb final RQ; 4.54 kg final RQ
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T N
Risk Phrases:
R 23/25 Toxic by inhalation and if swallowed.
R 36/37/38 Irritating to eyes, respiratory system
and skin.
R 50 Very toxic to aquatic organisms.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 28 After contact with skin, wash immediately
with...
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
S 61 Avoid release to the environment. Refer to
special instructions/safety data sheets.
WGK (Water Danger/Protection)
CAS# 106-51-4: 2
United Kingdom Occupational Exposure Limits
CAS# 106-51-4: OES-United Kingdom, TWA 0.1 ppm TWA; 0.45 mg/m3 TWA
CAS# 106-51-4: OES-United Kingdom, STEL 0.3 ppm STEL; 1.3 mg/m3 STEL
United Kingdom Maximum Exposure Limits
Canada
CAS# 106-51-4 is listed on Canada's DSL List.
CAS# 106-51-4 is listed on Canada's Ingredient Disclosure List.
Exposure Limits
CAS# 106-51-4: OEL-ARAB Republic of Egypt:TWA 0.1 ppm (0.4 mg/m3)
OEL-AUSTRALIA:TWA 0.1 ppm (0.4 mg/m3)
OEL-AUSTRIA:TWA 0.1 ppm (0.4 mg/m3)
OEL-BELGIUM:TWA 0.1 ppm (0.44 mg/m3)
OEL-DENMARK:TWA 0.1 ppm (0.4 mg/m3)
OEL-FINLAND:TWA 0.1 ppm (0.4 mg/m3);STEL 0.3 ppm;Skin
OEL-FRANCE:TWA 0.1 ppm (0.4 mg/m3);STEL 0.3 ppm (1.5 mg/m3)
OEL-GERMANY:TWA 0.1 ppm (0.4 mg/m3)
OEL-THE NETHERLANDS:TWA 0.1 ppm (0.4 mg/m3)
OEL-THE PHILIPPINES:TWA 5 ppm (15 mg/m3)
OEL-RUSSIA:STEL 0.05 mg/m3
OEL-SWEDEN:TWA 0.1 ppm (0.4 mg/m3);STEL 0.3 ppm (1.3 mg/m3)
OEL-SWITZERLAND:TWA 0.1 ppm (0.4 mg/m3);STEL 0.2 ppm (0.8 mg/m3)
OEL-TURKEY:TWA 0.1 ppm (0.4 mg/m3)
OEL-UNITED KINGDOM:TWA 0.1 ppm (0.4 mg/m3);STEL 0.3 ppm
OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV
OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGI TLV
US FEDERAL
TSCA
CAS# 106-51-4 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 5/07/1999 Revision #4 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
2-(4-Chlorophenyl)-4,4-Bis(methylthio)-
| 0-00-1 |
|
L-(-)-Galactose, 99%
| 15572-79-9 |
|
2-Iodobutane, 99%
| 513-48-4 |
|
3,5-Dimethyl-1,2-Cyclopentanedione, 97%
| 21834-98-0 |
|
3-Nitrobenzenesulfonamide, 98%
| 121-52-8 |
|
1-(2-Amino-5-Chlorobenzoyl)-1-Methyl-Hydrazine, 98%
| 0-00-1 |
|
Tetramethylrhodamine-5(6)Isothiocyanate
| 80724-20-5 |
|
Biphenylene, 99+% (GC)
| 259-79-0 |
|
Tetramethyltin, 99%
| 594-27-4 |
|
Ethyl dl-mandelate, 97%
| 4358-88-7 |
|
Propionic acid
| 79-09-4 |
|
(Trifluoromethyl)trimethylsilane, 96%
| 81290-20-2 |
|
3-Methyl-2-Butanone, 98%
| 563-80-4 |
|
(+)-N-Tosyl-L-Glutamic Acid, 98%
| 0-01-1 |
|
1-Propanol 99+%
| 71-23-8 |
|
1,4-Difluorobenzene, 99+%
| 540-36-3 |
|
3-Bromoanisole, 99+%
| 2398-37-0 |
|
1,2,4,5-Tetrafluorobenzene, 98%
| 327-54-8 |
|
Propylene Carbonate
| 108-32-7 |
|
(+)-1,6-Bis(2-Chlorophenyl)-1,6-Diphenyl- 2,4-Hexadiyne-1,6-Diol,
| 86436-19-3 |
|
Lithium amide, 95%
| 7782-89-0 |
|
Propylene glycol
| 57-55-6 |
|
Aluminum-nickel, Raney-type alloy, powder, Al-Ni 50/50
| 12635-29-9 |
|
Hexahydro-1h-azepine-1-acetonitrile, tech., ca.90%
| 54714-50-0 |
|
Ethyl 2-chloroacetoacetate (pract), 95% (gc)
| 609-15-4 |
|
Bis(Diphenylphosphino)Methane, 98%
| 2071-20-7 |
|
4-Acetylbenzenesulfonic Acid, Sodium Salt, 98%
| 61827-67-6 |
|
N-Benzylbenzamide, 99%
| 1485-70-7 |
|
p-Toluidine hydrochloride, 99%
| 540-23-8 |
|
Propylene oxide
| 75-56-9 |
|
Cyclohexanol-D12, 98+ Atom % D
| 66522-78-9 |
|
L(-)-carnitine hydrochloride, 99%
| 6645-46-1 |
|
6-Hydroxy-2,4,5-Triaminopyrimidine Sulfate
| 1603-02-7 |
|
2-Hydroxy-1-naphthaldehyde, tech., contains ca 15% water
| 708-06-5 |
|
5-Phenyl-2-(2-propynylamino)-2-oxazolin-4- one, 97+%
| 32962-46-2 |
|
4(3H)-Pyrimidone, 98+%
| 51953-17-4 |
|
Pyridine-N-oxide, 98%
| 694-59-7 |
|
2-Bromoterephthalic Acid, 99%
| 586-35-6 |
|
Serotonin Creatinine Sulfate Monohydrate, 99%
| 61-47-2 |
|
2-Methyl-6-nitroaniline, 99%
| 570-24-1 |
|
3-Fluoro-4-methylbenzoic acid, 97%
| 350-28-7 |
|
Pyridine
| 110-86-1 |
|
4,5-Dihydroxy-3-(p-Sulfophenylazo)-2,7- Naphthalenedisulfonic Acid
| 23647-14-5 |
|
Pyrogallol
| 87-66-1 |
|
N-Methylnicotinamide, 98%
| 114-33-0 |
|
Cesium Acetate, 99%
| 3396-11-0 |
|
1-Phenylcyclopentanecarboxylic Acid, 98%
| 77-55-4 |
|
Quinoline
| 91-22-5 |
|
p-Quinone
| 106-51-4 |
|
1,2,3-Benzenetricarboxylic acid hydrate 96%
| 36362-97-7 |
|
|