**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 71-23-8 |n-Propyl alcohol | >99 | 200-746-9 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XI F
Risk Phrases: 11 41 67
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Highly flammable. Risk of serious damage to eyes. Vapours may cause
drowsiness and dizziness.Hygroscopic (absorbs moisture from the
air).
Potential Health Effects
Eye:
May cause moderate eye irritation. May result in corneal injury.
Skin:
May cause moderate skin irritation. Prolonged and/or repeated
contact may cause defatting of the skin and dermatitis.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea. May cause central nervous system depression, characterized
by excitement, followed by headache, dizziness, drowsiness, and
nausea. Advanced stages may cause collapse, unconsciousness, coma
and possible death due to respiratory failure.
Inhalation:
Inhalation of vapor may cause respiratory tract irritation. May
cause effects similar to those described for ingestion.
Chronic:
Prolonged or repeated skin contact may cause defatting and
dermatitis. Chronic exposure may cause liver damage.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
Containers can build up pressure if exposed to heat and/or fire. As
in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Combustion generates toxic fumes. During a fire,
irritating and highly toxic gases may be generated by thermal
decomposition or combustion. Flammable Liquid. Can release vapors
that form explosive mixtures at temperatures above the flashpoint.
Vapors may be heavier than air. They can spread along the ground
and collect in low or confined areas.
Extinguishing Media:
Use water spray to cool fire-exposed containers. Use dry chemical,
carbon dioxide, or alcohol-resistant foam. Do NOT use straight
streams of water.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Avoid runoff into storm sewers and
ditches which lead to waterways. Clean up spills immediately,
observing precautions in the Protective Equipment section. Use water
spray to disperse the gas/vapor. Remove all sources of ignition.
Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use with adequate ventilation. Use spark-proof
tools and explosion proof equipment. Empty containers retain product
residue, (liquid and/or vapor), and can be dangerous. Do not get on
skin or in eyes. Do not ingest or inhale. Do not pressurize, cut,
weld, braze, solder, drill, grind, or expose empty containers to
heat, sparks or open flames.
Storage:
Keep away from heat, sparks, and flame. Do not store near
combustible materials. Store in a cool, dry place. Store in a
tightly closed container. Keep from contact with oxidizing
materials. Flammables-area.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate general or
local exhaust ventilation to keep airborne concentrations below the
permissible exposure limits.
Exposure Limits
CAS# 71-23-8:
United Kingdom, WEL - TWA: 200 ppm TWA; 500 mg/m3 TWA
United Kingdom, WEL - STEL: 250 ppm STEL; 625 mg/m3 STEL
United States OSHA: 200 ppm TWA; 500 mg/m3 TWA
Belgium - TWA: 200 ppm VLE; 499 mg/m3 VLE
Belgium - STEL: 250 ppm VLE; 623 mg/m3 VLE
France - VME: 200 ppm VME; 500 mg/m3 VME
Malaysia: 200 ppm TWA; 492 mg/m3 TWA
Russia: 10 mg/m3 TWA
Spain: 200 ppm VLA-ED; 500 mg/m3 VLA-ED
Spain: 250 ppm VLA-EC; 625 mg/m3 VLA-EC
Personal Protective Equipment
Eyes:
Wear chemical splash goggles.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to minimize
contact with skin.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: clear, colorless
Odor: alcohol-like
pH: Not available.
Vapor Pressure: 14.3 mm Hg @ 20
Viscosity: 2.2 mPas 20 deg C
Boiling Point: 97 deg C @ 760mm Hg
Freezing/Melting Point: -127 deg C
Autoignition Temperature: 405 deg C ( 761.00 deg F)
Flash Point: 15 deg C ( 59.00 deg F)
Explosion Limits, lower: 2.2 vol %
Explosion Limits, upper: 13.7 vol %
Decomposition Temperature:
Solubility in water: Miscible.
Specific Gravity/Density: .8040g/cm3
Molecular Formula: C3H8O
Molecular Weight: 60.10
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, ignition sources.
Incompatibilities with Other Materials:
Acid chlorides, acid anhydrides, oxidizing agents, potassium
tert-butoxide.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide.
Hazardous Polymerization: Will not occur.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 71-23-8: UH8225000
LD50/LC50:
CAS# 71-23-8: Draize test, rabbit, eye: 20 mg/24H Moderate;
Inhalation, mouse: LC50 = 48 gm/m3; Inhalation, mouse: LC50 = 48000
mg/m3; Oral, mouse: LD50 = 6800 mg/kg; Oral, rabbit: LD50 = 2825
mg/kg; Oral, rat: LD50 = 1870 mg/kg; Oral, rat: LD50 = 2200 mg/kg;
Skin, rabbit: LD50 = 5040 mg/kg.
Carcinogenicity:
n-Propyl alcohol -
ACGIH: A3 - Confirmed animal carcinogen with unknown relevance to
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Other
No information available.
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: n-PROPANOL
Hazard Class: 3
UN Number: 1274
Packing Group: II
IMO
Shipping Name: normal-PROPANOL
Hazard Class: 3.2
UN Number: 1274
Packing Group: II
RID/ADR
Shipping Name: n-PROPANOL
Hazard Class: 3
UN Number: 1274
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI F
Risk Phrases:
R 11 Highly flammable.
R 41 Risk of serious damage to eyes.
R 67 Vapours may cause drowsiness and dizziness.
Safety Phrases:
S 7 Keep container tightly closed.
S 16 Keep away from sources of ignition - No
smoking.
S 24 Avoid contact with skin.
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 39 Wear eye/face protection.
WGK (Water Danger/Protection)
CAS# 71-23-8: 1
Canada
CAS# 71-23-8 is listed on Canada's DSL List.
CAS# 71-23-8 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 71-23-8 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 12/12/1997 Revision #7 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
2-(4-Chlorophenyl)-4,4-Bis(methylthio)-
| 0-00-1 |
|
L-(-)-Galactose, 99%
| 15572-79-9 |
|
2-Iodobutane, 99%
| 513-48-4 |
|
3,5-Dimethyl-1,2-Cyclopentanedione, 97%
| 21834-98-0 |
|
3-Nitrobenzenesulfonamide, 98%
| 121-52-8 |
|
1-(2-Amino-5-Chlorobenzoyl)-1-Methyl-Hydrazine, 98%
| 0-00-1 |
|
Tetramethylrhodamine-5(6)Isothiocyanate
| 80724-20-5 |
|
Biphenylene, 99+% (GC)
| 259-79-0 |
|
Tetramethyltin, 99%
| 594-27-4 |
|
Ethyl dl-mandelate, 97%
| 4358-88-7 |
|
Propionic acid
| 79-09-4 |
|
(Trifluoromethyl)trimethylsilane, 96%
| 81290-20-2 |
|
3-Methyl-2-Butanone, 98%
| 563-80-4 |
|
(+)-N-Tosyl-L-Glutamic Acid, 98%
| 0-01-1 |
|
1-Propanol 99+%
| 71-23-8 |
|
1,4-Difluorobenzene, 99+%
| 540-36-3 |
|
3-Bromoanisole, 99+%
| 2398-37-0 |
|
1,2,4,5-Tetrafluorobenzene, 98%
| 327-54-8 |
|
Propylene Carbonate
| 108-32-7 |
|
(+)-1,6-Bis(2-Chlorophenyl)-1,6-Diphenyl- 2,4-Hexadiyne-1,6-Diol,
| 86436-19-3 |
|
Lithium amide, 95%
| 7782-89-0 |
|
Propylene glycol
| 57-55-6 |
|
Aluminum-nickel, Raney-type alloy, powder, Al-Ni 50/50
| 12635-29-9 |
|
Hexahydro-1h-azepine-1-acetonitrile, tech., ca.90%
| 54714-50-0 |
|
Ethyl 2-chloroacetoacetate (pract), 95% (gc)
| 609-15-4 |
|
Bis(Diphenylphosphino)Methane, 98%
| 2071-20-7 |
|
4-Acetylbenzenesulfonic Acid, Sodium Salt, 98%
| 61827-67-6 |
|
N-Benzylbenzamide, 99%
| 1485-70-7 |
|
p-Toluidine hydrochloride, 99%
| 540-23-8 |
|
Propylene oxide
| 75-56-9 |
|
Cyclohexanol-D12, 98+ Atom % D
| 66522-78-9 |
|
L(-)-carnitine hydrochloride, 99%
| 6645-46-1 |
|
6-Hydroxy-2,4,5-Triaminopyrimidine Sulfate
| 1603-02-7 |
|
2-Hydroxy-1-naphthaldehyde, tech., contains ca 15% water
| 708-06-5 |
|
5-Phenyl-2-(2-propynylamino)-2-oxazolin-4- one, 97+%
| 32962-46-2 |
|
4(3H)-Pyrimidone, 98+%
| 51953-17-4 |
|
Pyridine-N-oxide, 98%
| 694-59-7 |
|
2-Bromoterephthalic Acid, 99%
| 586-35-6 |
|
Serotonin Creatinine Sulfate Monohydrate, 99%
| 61-47-2 |
|
2-Methyl-6-nitroaniline, 99%
| 570-24-1 |
|
3-Fluoro-4-methylbenzoic acid, 97%
| 350-28-7 |
|
Pyridine
| 110-86-1 |
|
4,5-Dihydroxy-3-(p-Sulfophenylazo)-2,7- Naphthalenedisulfonic Acid
| 23647-14-5 |
|
Pyrogallol
| 87-66-1 |
|
N-Methylnicotinamide, 98%
| 114-33-0 |
|
Cesium Acetate, 99%
| 3396-11-0 |
|
1-Phenylcyclopentanecarboxylic Acid, 98%
| 77-55-4 |
|
Quinoline
| 91-22-5 |
|
p-Quinone
| 106-51-4 |
|
1,2,3-Benzenetricarboxylic acid hydrate 96%
| 36362-97-7 |
|
|