**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 12635-29-9 |Aluminum-Nickel alloy | 100 | unlisted |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN F
Risk Phrases: 15 40 43
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Contact with water liberates extremely flammable gases. Limited
evidence of a carcinogenic effect. May cause sensitization by skin
contact.Water-reactive.Cancer suspect agent.
Potential Health Effects
Eye:
May cause eye irritation. Aluminum particles may cause corneal
necrosis.
Skin:
May cause skin irritation. May cause skin sensitization, an allergic
reaction, which becomes evident upon re-exposure to this material.
May be harmful if absorbed through the skin. Causes "nickel itch"
which is a dermatitis resulting from sensitization to nickel, which
is characterized by skin eruptions, followed by discrete ulcers that
may discharge and become crusted, or by eczema.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea. The toxicological properties of this substance have not
been fully investigated. May be harmful if swallowed.
Inhalation:
May cause respiratory tract irritation. Inhalation of fumes may
cause metal fume fever, which is characterized by flu-like symptoms
with metallic taste, fever, chills, cough, weakness, chest pain,
muscle pain and increased white blood cell count. May cause anosmia
(loss of smell). Exposure may cause coughing, shortness of breath,
lethargy, and an increased respiration rate. Breathing Nickel (Dust
and Fume) can cause a sore or hole in the "bone" (septum) dividing
the inner nose.
Chronic:
Possible cancer hazard based on tests with laboratory animals.
Chronic inhalation of fine dusts may cause lung damage. Chronic
inhalation may cause pulmonary fibrosis. Repeated inhalation may
cause perforation of the nasal septum.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes.
Ingestion:
Get medical aid. Do NOT induce vomiting. If conscious and alert,
rinse mouth and drink 2-4 cupfuls of milk or water. Wash mouth out
with water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Water Reactive. Material will react with water and
may release a flammable and/or toxic gas. This material in
sufficient quantity and reduced particle size is capable of creating
a dust explosion.
Extinguishing Media:
Do NOT use water directly on fire. Do NOT use carbon dioxide. Use
dry chemical to fight fire.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container. Clean up spills immediately, observing precautions in the
Protective Equipment section. Avoid generating dusty conditions.
Provide ventilation. Remove ignition sources since flammable hydrogen
gas may be generated by reaction with water.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use with adequate ventilation. Avoid contact with
eyes, skin, and clothing. Avoid ingestion and inhalation. Do not
allow contact with water. Keep from contact with moist air and steam.
Storage:
Store in a cool, dry place. Store in a tightly closed container.
Keep away from water.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate general or
local exhaust ventilation to keep airborne concentrations below the
permissible exposure limits.
Exposure Limits
CAS# 12635-29-9:
United States OSHA: 1 mg/m3 TWA (as Ni) (listed under Nickel sol
compounds).
Belgium - TWA: (listed as nickel soluble compounds): 0.1 mg/m3 VL
(as Ni)
Malaysia: (listed as nickel soluble compounds): 0.1 mg/m3 TWA
(inhalable fraction, as Ni)
Netherlands: (listed as nickel soluble compounds): 0.1 mg/m3 MAC
Ni)
Spain: (listed as nickel soluble compounds): 0.1 mg/m3 VLA-ED (as
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective gloves to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Powder
Color: grey
Odor: Odorless
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 1350 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: reacts slowly forming H2
Specific Gravity/Density: 3.4600g/cm3
Molecular Formula: AlNi
Molecular Weight: 85.68
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Water contact produces hydrogen gas.
Conditions to Avoid:
Dust generation, contact with water.
Incompatibilities with Other Materials:
Strong oxidizing agents, strong acids.
Hazardous Decomposition Products:
Aluminum oxide, nickel oxide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 12635-29-9 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Aluminum-Nickel alloy -
California: carcinogen, initial date 5/7/04 (listed as Nickel compound
NTP: Known carcinogen (listed as Nickel compounds).
IARC: Group 1 carcinogen (listed as Nickel compounds).
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: WATER-REACTIVE SOLID, N.O.S.*
Hazard Class: 4.3
UN Number: 2813
Packing Group: III
IMO
Shipping Name: WATER-REACTIVE SOLID, N.O.S.
Hazard Class: 4.3
UN Number: 2813
Packing Group: III
RID/ADR
Shipping Name: WATER-REACTIVE SOLID, N.O.S.
Hazard Class: 4.3
UN Number: 2813
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN F
Risk Phrases:
R 15 Contact with water liberates extremely
flammable gases.
R 40 Limited evidence of a carcinogenic effect.
R 43 May cause sensitization by skin contact.
Safety Phrases:
S 7/8 Keep container tightly closed and dry.
S 22 Do not breathe dust.
S 36 Wear suitable protective clothing.
S 43A In case of fire, use dry chemical (never use
water).
WGK (Water Danger/Protection)
CAS# 12635-29-9: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 12635-29-9 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 12635-29-9 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 8/24/1997 Revision #6 Date: 2/23/2004
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
2-(4-Chlorophenyl)-4,4-Bis(methylthio)-
| 0-00-1 |
|
L-(-)-Galactose, 99%
| 15572-79-9 |
|
2-Iodobutane, 99%
| 513-48-4 |
|
3,5-Dimethyl-1,2-Cyclopentanedione, 97%
| 21834-98-0 |
|
3-Nitrobenzenesulfonamide, 98%
| 121-52-8 |
|
1-(2-Amino-5-Chlorobenzoyl)-1-Methyl-Hydrazine, 98%
| 0-00-1 |
|
Tetramethylrhodamine-5(6)Isothiocyanate
| 80724-20-5 |
|
Biphenylene, 99+% (GC)
| 259-79-0 |
|
Tetramethyltin, 99%
| 594-27-4 |
|
Ethyl dl-mandelate, 97%
| 4358-88-7 |
|
Propionic acid
| 79-09-4 |
|
(Trifluoromethyl)trimethylsilane, 96%
| 81290-20-2 |
|
3-Methyl-2-Butanone, 98%
| 563-80-4 |
|
(+)-N-Tosyl-L-Glutamic Acid, 98%
| 0-01-1 |
|
1-Propanol 99+%
| 71-23-8 |
|
1,4-Difluorobenzene, 99+%
| 540-36-3 |
|
3-Bromoanisole, 99+%
| 2398-37-0 |
|
1,2,4,5-Tetrafluorobenzene, 98%
| 327-54-8 |
|
Propylene Carbonate
| 108-32-7 |
|
(+)-1,6-Bis(2-Chlorophenyl)-1,6-Diphenyl- 2,4-Hexadiyne-1,6-Diol,
| 86436-19-3 |
|
Lithium amide, 95%
| 7782-89-0 |
|
Propylene glycol
| 57-55-6 |
|
Aluminum-nickel, Raney-type alloy, powder, Al-Ni 50/50
| 12635-29-9 |
|
Hexahydro-1h-azepine-1-acetonitrile, tech., ca.90%
| 54714-50-0 |
|
Ethyl 2-chloroacetoacetate (pract), 95% (gc)
| 609-15-4 |
|
Bis(Diphenylphosphino)Methane, 98%
| 2071-20-7 |
|
4-Acetylbenzenesulfonic Acid, Sodium Salt, 98%
| 61827-67-6 |
|
N-Benzylbenzamide, 99%
| 1485-70-7 |
|
p-Toluidine hydrochloride, 99%
| 540-23-8 |
|
Propylene oxide
| 75-56-9 |
|
Cyclohexanol-D12, 98+ Atom % D
| 66522-78-9 |
|
L(-)-carnitine hydrochloride, 99%
| 6645-46-1 |
|
6-Hydroxy-2,4,5-Triaminopyrimidine Sulfate
| 1603-02-7 |
|
2-Hydroxy-1-naphthaldehyde, tech., contains ca 15% water
| 708-06-5 |
|
5-Phenyl-2-(2-propynylamino)-2-oxazolin-4- one, 97+%
| 32962-46-2 |
|
4(3H)-Pyrimidone, 98+%
| 51953-17-4 |
|
Pyridine-N-oxide, 98%
| 694-59-7 |
|
2-Bromoterephthalic Acid, 99%
| 586-35-6 |
|
Serotonin Creatinine Sulfate Monohydrate, 99%
| 61-47-2 |
|
2-Methyl-6-nitroaniline, 99%
| 570-24-1 |
|
3-Fluoro-4-methylbenzoic acid, 97%
| 350-28-7 |
|
Pyridine
| 110-86-1 |
|
4,5-Dihydroxy-3-(p-Sulfophenylazo)-2,7- Naphthalenedisulfonic Acid
| 23647-14-5 |
|
Pyrogallol
| 87-66-1 |
|
N-Methylnicotinamide, 98%
| 114-33-0 |
|
Cesium Acetate, 99%
| 3396-11-0 |
|
1-Phenylcyclopentanecarboxylic Acid, 98%
| 77-55-4 |
|
Quinoline
| 91-22-5 |
|
p-Quinone
| 106-51-4 |
|
1,2,3-Benzenetricarboxylic acid hydrate 96%
| 36362-97-7 |
|
|