**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 563-80-4 |3-Methyl-2-Butanone | 98 | 209-264-3 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: F
Risk Phrases: 11
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Highly flammable.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
May cause skin irritation.
Ingestion:
Causes gastrointestinal irritation with nausea, vomiting and
diarrhea.
Inhalation:
May cause respiratory tract irritation. Vapors may cause dizziness
or suffocation.
Chronic:
Not available.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical
aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Vapors may form an explosive mixture with air.
Vapors can travel to a source of ignition and flash back. Will burn
if involved in a fire. Use water spray to keep fire-exposed
containers cool. Containers may explode in the heat of a fire.
Flammable liquid and vapor. Vapors may be heavier than air. They can
spread along the ground and collect in low or confined areas.
Extinguishing Media:
For small fires, use dry chemical, carbon dioxide, water spray or
alcohol-resistant foam. For large fires, use water spray, fog, or
alcohol-resistant foam. Use water spray to cool fire-exposed
containers. Water may be ineffective. Do NOT use straight streams of
water.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Clean up spills immediately,
observing precautions in the Protective Equipment section. Remove all
sources of ignition. Use a spark-proof tool. Provide ventilation. A
vapor suppressing foam may be used to reduce vapors.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Use only in a well-ventilated area.
Ground and bond containers when transferring material. Use
spark-proof tools and explosion proof equipment. Avoid contact with
eyes, skin, and clothing. Empty containers retain product residue,
(liquid and/or vapor), and can be dangerous. Keep away from heat,
sparks and flame. Avoid ingestion and inhalation. Do not pressurize,
cut, weld, braze, solder, drill, grind, or expose empty containers to
heat, sparks or open flames.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of
ignition. Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances.
Flammables-area.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use adequate general or local exhaust ventilation to keep airborne
concentrations below the permissible exposure limits.
Exposure Limits
CAS# 563-80-4:
Belgium - TWA: 200 ppm VLE; 715 mg/m3 VLE
France - VME: 200 ppm VME; 705 mg/m3 VME
Germany: 705 mg/m3 TWA
Malaysia: 200 ppm TWA; 705 mg/m3 TWA
Netherlands: 200 ppm MAC; 705 mg/m3 MAC
Spain: 200 ppm VLA-ED; 715 mg/m3 VLA-ED
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: colorless
Odor: acetone-like
pH: Not available.
Vapor Pressure: 55 hPa @ 20 C
Viscosity: Not available.
Boiling Point: 94.0 - 95.0 deg C @ 760.00mm
Freezing/Melting Point: 0 deg C
Autoignition Temperature: 427 deg C ( 800.60 deg F)
Flash Point: 6 deg C ( 42.80 deg F)
Explosion Limits, lower: 1.80 vol %
Explosion Limits, upper: 9.00 vol %
Decomposition Temperature:
Solubility in water: 6 g/l (20 c)
Specific Gravity/Density: .8050g/cm3
Molecular Formula: C5H10O
Molecular Weight: 86.13
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, ignition sources, excess heat, strong
oxidants.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, irritating and toxic fumes and gases, carbon
dioxide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 563-80-4: EL9100000
LD50/LC50:
CAS# 563-80-4: Draize test, rabbit, eye: 100 mg/24H Mild; Draize
test, rabbit, eye: 500 mg/24H Mild; Draize test, rabbit, skin: 500
mg/24H Moderate; Inhalation, mouse: LC50 = 30000 mg/m3; Oral, mouse:
LD50 = 2572 mg/kg; Oral, mouse: LD50 = 3000 mg/kg; Oral, rat: LD50 =
3078 mg/kg; Oral, rat: LD50 = 3000 mg/kg; Skin, rabbit: LD50 = 6350
mg/kg.
Carcinogenicity:
3-Methyl-2-Butanone -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: 3-METHYLBUTAN-2-ONE
Hazard Class: 3
UN Number: 2397
Packing Group: II
IMO
Shipping Name: 3-METHYLBUTAN-2-ONE
Hazard Class: 3.2
UN Number: 2397
Packing Group: II
RID/ADR
Shipping Name: 3-METHYLBUTAN-2-ONE
Hazard Class: 3
UN Number: 2397
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: F
Risk Phrases:
R 11 Highly flammable.
Safety Phrases:
S 9 Keep container in a well-ventilated place.
S 16 Keep away from sources of ignition - No
smoking.
S 33 Take precautionary measures against static
discharges.
WGK (Water Danger/Protection)
CAS# 563-80-4: 1
Canada
CAS# 563-80-4 is listed on Canada's DSL List.
CAS# 563-80-4 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 563-80-4 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 8/04/1998 Revision #3 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
2-(4-Chlorophenyl)-4,4-Bis(methylthio)-
| 0-00-1 |
|
L-(-)-Galactose, 99%
| 15572-79-9 |
|
2-Iodobutane, 99%
| 513-48-4 |
|
3,5-Dimethyl-1,2-Cyclopentanedione, 97%
| 21834-98-0 |
|
3-Nitrobenzenesulfonamide, 98%
| 121-52-8 |
|
1-(2-Amino-5-Chlorobenzoyl)-1-Methyl-Hydrazine, 98%
| 0-00-1 |
|
Tetramethylrhodamine-5(6)Isothiocyanate
| 80724-20-5 |
|
Biphenylene, 99+% (GC)
| 259-79-0 |
|
Tetramethyltin, 99%
| 594-27-4 |
|
Ethyl dl-mandelate, 97%
| 4358-88-7 |
|
Propionic acid
| 79-09-4 |
|
(Trifluoromethyl)trimethylsilane, 96%
| 81290-20-2 |
|
3-Methyl-2-Butanone, 98%
| 563-80-4 |
|
(+)-N-Tosyl-L-Glutamic Acid, 98%
| 0-01-1 |
|
1-Propanol 99+%
| 71-23-8 |
|
1,4-Difluorobenzene, 99+%
| 540-36-3 |
|
3-Bromoanisole, 99+%
| 2398-37-0 |
|
1,2,4,5-Tetrafluorobenzene, 98%
| 327-54-8 |
|
Propylene Carbonate
| 108-32-7 |
|
(+)-1,6-Bis(2-Chlorophenyl)-1,6-Diphenyl- 2,4-Hexadiyne-1,6-Diol,
| 86436-19-3 |
|
Lithium amide, 95%
| 7782-89-0 |
|
Propylene glycol
| 57-55-6 |
|
Aluminum-nickel, Raney-type alloy, powder, Al-Ni 50/50
| 12635-29-9 |
|
Hexahydro-1h-azepine-1-acetonitrile, tech., ca.90%
| 54714-50-0 |
|
Ethyl 2-chloroacetoacetate (pract), 95% (gc)
| 609-15-4 |
|
Bis(Diphenylphosphino)Methane, 98%
| 2071-20-7 |
|
4-Acetylbenzenesulfonic Acid, Sodium Salt, 98%
| 61827-67-6 |
|
N-Benzylbenzamide, 99%
| 1485-70-7 |
|
p-Toluidine hydrochloride, 99%
| 540-23-8 |
|
Propylene oxide
| 75-56-9 |
|
Cyclohexanol-D12, 98+ Atom % D
| 66522-78-9 |
|
L(-)-carnitine hydrochloride, 99%
| 6645-46-1 |
|
6-Hydroxy-2,4,5-Triaminopyrimidine Sulfate
| 1603-02-7 |
|
2-Hydroxy-1-naphthaldehyde, tech., contains ca 15% water
| 708-06-5 |
|
5-Phenyl-2-(2-propynylamino)-2-oxazolin-4- one, 97+%
| 32962-46-2 |
|
4(3H)-Pyrimidone, 98+%
| 51953-17-4 |
|
Pyridine-N-oxide, 98%
| 694-59-7 |
|
2-Bromoterephthalic Acid, 99%
| 586-35-6 |
|
Serotonin Creatinine Sulfate Monohydrate, 99%
| 61-47-2 |
|
2-Methyl-6-nitroaniline, 99%
| 570-24-1 |
|
3-Fluoro-4-methylbenzoic acid, 97%
| 350-28-7 |
|
Pyridine
| 110-86-1 |
|
4,5-Dihydroxy-3-(p-Sulfophenylazo)-2,7- Naphthalenedisulfonic Acid
| 23647-14-5 |
|
Pyrogallol
| 87-66-1 |
|
N-Methylnicotinamide, 98%
| 114-33-0 |
|
Cesium Acetate, 99%
| 3396-11-0 |
|
1-Phenylcyclopentanecarboxylic Acid, 98%
| 77-55-4 |
|
Quinoline
| 91-22-5 |
|
p-Quinone
| 106-51-4 |
|
1,2,3-Benzenetricarboxylic acid hydrate 96%
| 36362-97-7 |
|
|