**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 66522-78-9 |Cyclohexanol-D12 | 98+ | 266-389-6 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN
Risk Phrases: 20/22 37/38
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful by inhalation and if swallowed. Irritating to respiratory
system and skin.Hygroscopic (absorbs moisture from the air).
Potential Health Effects
Eye:
Causes eye irritation. May cause chemical conjunctivitis and
corneal damage.
Skin:
Causes skin irritation. May cause cyanosis of the extremities.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea. May be harmful if swallowed.
Inhalation:
Causes respiratory tract irritation. Can produce delayed pulmonary
edema. Inhalation at high concentrations may cause CNS depression and
asphixiation.
Chronic:
Prolonged or repeated skin contact may cause dermatitis. Effects may
be delayed.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and
drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Use water
spray to keep fire-exposed containers cool. Combustible liquid.
Vapors may be heavier than air. They can spread along the ground and
collect in low or confined areas. Containers may explode when heated.
Extinguishing Media:
In case of fire, use water, dry chemical, chemical foam, or
alcohol-resistant foam. Use water spray to cool fire-exposed
containers. Use agent most appropriate to extinguish fire.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Clean up spills immediately,
observing precautions in the Protective Equipment section. Remove all
sources of ignition. Use a spark-proof tool. Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use only in a well-ventilated area. Avoid contact
with eyes, skin, and clothing. Empty containers retain product
residue, (liquid and/or vapor), and can be dangerous. Keep container
tightly closed. Keep away from heat, sparks and flame. Avoid
ingestion and inhalation. Do not pressurize, cut, weld, braze,
solder, drill, grind, or expose empty containers to heat, sparks or
open flames.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of
ignition. Keep container closed when not in use. Store in a tightly
closed container. Store in a cool, dry, well-ventilated area away
from incompatible substances. Store protected from moisture.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate general or
local explosion-proof ventilation to keep airborne levels to
acceptable levels.
Exposure Limits
CAS# 66522-78-9:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: clear, colorless
Odor: None reported.
pH: Not available.
Vapor Pressure: 1 mm Hg @ 21 deg C
Viscosity: Not available.
Boiling Point: 157.4 -158.4 deg C @ 760 mmHg
Freezing/Melting Point: Not available.
Autoignition Temperature: 299 deg C ( 570.20 deg F)
Flash Point: 67 deg C ( 152.60 deg F)
Explosion Limits, lower: 1.25 vol %
Explosion Limits, upper: 12.25 vol %
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density: 1.079
Molecular Formula: C6D12O
Molecular Weight: 112.26
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, ignition sources, excess heat, strong
oxidants, exposure to moist air or water.
Incompatibilities with Other Materials:
Moisture, oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, irritating and toxic fumes and gases, carbon
dioxide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 66522-78-9 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Cyclohexanol-D12 -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 20/22 Harmful by inhalation and if swallowed.
R 37/38 Irritating to respiratory system and skin.
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 66522-78-9: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 66522-78-9 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 66522-78-9 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/02/1997 Revision #7 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
2-(4-Chlorophenyl)-4,4-Bis(methylthio)-
| 0-00-1 |
|
L-(-)-Galactose, 99%
| 15572-79-9 |
|
2-Iodobutane, 99%
| 513-48-4 |
|
3,5-Dimethyl-1,2-Cyclopentanedione, 97%
| 21834-98-0 |
|
3-Nitrobenzenesulfonamide, 98%
| 121-52-8 |
|
1-(2-Amino-5-Chlorobenzoyl)-1-Methyl-Hydrazine, 98%
| 0-00-1 |
|
Tetramethylrhodamine-5(6)Isothiocyanate
| 80724-20-5 |
|
Biphenylene, 99+% (GC)
| 259-79-0 |
|
Tetramethyltin, 99%
| 594-27-4 |
|
Ethyl dl-mandelate, 97%
| 4358-88-7 |
|
Propionic acid
| 79-09-4 |
|
(Trifluoromethyl)trimethylsilane, 96%
| 81290-20-2 |
|
3-Methyl-2-Butanone, 98%
| 563-80-4 |
|
(+)-N-Tosyl-L-Glutamic Acid, 98%
| 0-01-1 |
|
1-Propanol 99+%
| 71-23-8 |
|
1,4-Difluorobenzene, 99+%
| 540-36-3 |
|
3-Bromoanisole, 99+%
| 2398-37-0 |
|
1,2,4,5-Tetrafluorobenzene, 98%
| 327-54-8 |
|
Propylene Carbonate
| 108-32-7 |
|
(+)-1,6-Bis(2-Chlorophenyl)-1,6-Diphenyl- 2,4-Hexadiyne-1,6-Diol,
| 86436-19-3 |
|
Lithium amide, 95%
| 7782-89-0 |
|
Propylene glycol
| 57-55-6 |
|
Aluminum-nickel, Raney-type alloy, powder, Al-Ni 50/50
| 12635-29-9 |
|
Hexahydro-1h-azepine-1-acetonitrile, tech., ca.90%
| 54714-50-0 |
|
Ethyl 2-chloroacetoacetate (pract), 95% (gc)
| 609-15-4 |
|
Bis(Diphenylphosphino)Methane, 98%
| 2071-20-7 |
|
4-Acetylbenzenesulfonic Acid, Sodium Salt, 98%
| 61827-67-6 |
|
N-Benzylbenzamide, 99%
| 1485-70-7 |
|
p-Toluidine hydrochloride, 99%
| 540-23-8 |
|
Propylene oxide
| 75-56-9 |
|
Cyclohexanol-D12, 98+ Atom % D
| 66522-78-9 |
|
L(-)-carnitine hydrochloride, 99%
| 6645-46-1 |
|
6-Hydroxy-2,4,5-Triaminopyrimidine Sulfate
| 1603-02-7 |
|
2-Hydroxy-1-naphthaldehyde, tech., contains ca 15% water
| 708-06-5 |
|
5-Phenyl-2-(2-propynylamino)-2-oxazolin-4- one, 97+%
| 32962-46-2 |
|
4(3H)-Pyrimidone, 98+%
| 51953-17-4 |
|
Pyridine-N-oxide, 98%
| 694-59-7 |
|
2-Bromoterephthalic Acid, 99%
| 586-35-6 |
|
Serotonin Creatinine Sulfate Monohydrate, 99%
| 61-47-2 |
|
2-Methyl-6-nitroaniline, 99%
| 570-24-1 |
|
3-Fluoro-4-methylbenzoic acid, 97%
| 350-28-7 |
|
Pyridine
| 110-86-1 |
|
4,5-Dihydroxy-3-(p-Sulfophenylazo)-2,7- Naphthalenedisulfonic Acid
| 23647-14-5 |
|
Pyrogallol
| 87-66-1 |
|
N-Methylnicotinamide, 98%
| 114-33-0 |
|
Cesium Acetate, 99%
| 3396-11-0 |
|
1-Phenylcyclopentanecarboxylic Acid, 98%
| 77-55-4 |
|
Quinoline
| 91-22-5 |
|
p-Quinone
| 106-51-4 |
|
1,2,3-Benzenetricarboxylic acid hydrate 96%
| 36362-97-7 |
|
|