**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 107-05-1 |Allyl chloride | >98 | 203-457-6 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN F N
Risk Phrases: 11 20/21/22 36/37/38 40 50 48/20 68
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Highly flammable. Harmful by inhalation, in contact with skin and if
swallowed. Irritating to eyes, respiratory system and skin. Limited
evidence of a carcinogenic effect. Very toxic to aquatic organisms.
Harmful : danger of serious damage to health by prolonged exposure
through inhalation.Possible risk of irreversible effects.
Potential Health Effects
Eye:
Contact with eyes may cause severe irritation, and possible eye
burns.
Skin:
Contact with skin causes irritation and possible burns, especially
if the skin is wet or moist.
Ingestion:
Harmful if swallowed. May cause severe gastrointestinal tract
irritation with nausea, vomiting and possible burns.
Inhalation:
May cause irritation of the respiratory tract with burning pain in
the nose and throat, coughing, wheezing, shortness of breath and
pulmonary edema.
Chronic:
May cause liver and kidney damage. May cause cancer according to
animal studies. May cause lung damage.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Get medical aid immediately. Do NOT allow victim to rub eyes or keep
eyes closed. Extensive irrigation with water is required (at least 30
minutes).
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes. Wash clothing before reuse.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen. Do NOT use mouth-to-mouth
resuscitation.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Use water spray to keep fire-exposed containers
cool. Liquid will float and may reignite on the surface of water.
Fire or excessive heat may result in violent rupture of the container
due to bulk polymerization. Extremely flammable liquid and vapor.
Vapor may cause flash fire. Approach fire from upwind to avoid
hazardous vapors and toxic decomposition products.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or appropriate foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Avoid runoff into storm sewers and
ditches which lead to waterways. Clean up spills immediately,
observing precautions in the Protective Equipment section. Scoop up
with a nonsparking tool, then place into a suitable container for
disposal. Remove all sources of ignition. Provide ventilation.
Approach spill from upwind.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Ground and bond containers when
transferring material. Use spark-proof tools and explosion proof
equipment. Do not get in eyes, on skin, or on clothing. Empty
containers retain product residue, (liquid and/or vapor), and can be
dangerous. Take precautionary measures against static discharges.
Keep container tightly closed. Keep away from heat, sparks and
flame. Do not pressurize, cut, weld, braze, solder, drill, grind, or
expose empty containers to heat, sparks or open flames. Use only
with adequate ventilation. Do not breathe vapor or mist.
Storage:
Keep away from sources of ignition. Keep from freezing. Keep
container closed when not in use. Flammables-area.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use process enclosure, local exhaust ventilation, or other
engineering controls to control airborne levels below recommended
exposure limits. Facilities storing or utilizing this material should
be equipped with an eyewash facility and a safety shower.
Exposure Limits
CAS# 107-05-1:
United States OSHA: 1 ppm TWA; 3 mg/m3 TWA
Belgium - TWA: 1 ppm VLE; 3 mg/m3 VLE
Belgium - STEL: 2 ppm VLE; 6 mg/m3 VLE
France - VME: 1 ppm VME; 3 mg/m3 VME
Germany: 1 ppm TWA; 3 mg/m3 TWA
Germany: Skin absorber
Malaysia: 1 ppm TWA; 3 mg/m3 TWA
Netherlands: 1 ppm MAC; 3 mg/m3 MAC
Russia: 0.3 mg/m3 TWA
Spain: 1 ppm VLA-ED; 3.2 mg/m3 VLA-ED
Spain: 2 ppm VLA-EC; 6.4 mg/m3 VLA-EC
Personal Protective Equipment
Eyes:
Wear chemical splash goggles.
Skin:
Wear appropriate gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: clear, colorless
Odor: disagreeable odor - pungent odor - unpleasant odor -
pH: Not available.
Vapor Pressure: 368 mm Hg @ 25 deg C
Viscosity: Not available.
Boiling Point: 44-45 deg C
Freezing/Melting Point: -134.5 deg C
Autoignition Temperature: 392 deg C ( 737.60 deg F)
Flash Point: -32 deg C ( -25.60 deg F)
Explosion Limits, lower: 2.9%
Explosion Limits, upper: 11.1%
Decomposition Temperature: Not available.
Solubility in water: Slightly soluble.
Specific Gravity/Density: 0.938
Molecular Formula: C3H5Cl
Molecular Weight: 76.53
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
This material is a monomer and may polymerize under certain
conditions if the stabilizer is lost. Allyl chloride produces HCl
upon storage and can similarly undergo hydrolysis in water to form
allyl alcohol (poisonous by inhalation in Hazard Zone B) and HCl.
Conditions to Avoid:
High temperatures, ignition sources, freezing temperatures.
Incompatibilities with Other Materials:
Metals, strong oxidizing agents, strong acids, amines, polymerization
catalysts.
Hazardous Decomposition Products:
Hydrogen chloride, phosgene, carbon monoxide, carbon dioxide.
Hazardous Polymerization: May occur.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 107-05-1: UC7350000
LD50/LC50:
CAS# 107-05-1: Draize test, rabbit, eye: 500 mg Moderate;
Inhalation, mouse: LC50 = 11500 mg/m3/2H; Inhalation, mouse: LC50 =
6600 mg/m3; Inhalation, rat: LC50 = 11 gm/m3/2H; Inhalation, rat:
LC50 = 8200 mg/m3; Oral, mouse: LD50 = 425 mg/kg; Oral, mouse: LD50
= 500 mg/kg; Oral, rabbit: LD50 = 300 mg/kg; Oral, rat: LD50 = 460
mg/kg; Oral, rat: LD50 = 450 mg/kg; Skin, rabbit: LD50 = 2066 mg/kg.
Carcinogenicity:
Allyl chloride -
ACGIH: A3 - Confirmed animal carcinogen with unknown relevance to
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Other
No information available.
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: ALLYL CHLORIDE
Hazard Class: 3 (6.1)
UN Number: 1100
Packing Group: I
IMO
Shipping Name: ALLYL CHLORIDE
Hazard Class: 3.1 (6.1)
UN Number: 1100
Packing Group: I
RID/ADR
Shipping Name: ALLYL CHLORIDE
Hazard Class: 3
UN Number: 1100
Packing group: I
USA RQ: CAS# 107-05-1: 1000 lb final RQ; 454 kg final RQ
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN F N
Risk Phrases:
R 11 Highly flammable.
R 20/21/22 Harmful by inhalation, in contact with
skin and if swallowed.
R 36/37/38 Irritating to eyes, respiratory system
and skin.
R 40 Limited evidence of a carcinogenic effect.
R 48/20 Harmful : danger of serious damage to health
by prolonged exposure through inhalation.
R 50 Very toxic to aquatic organisms.
R 68 Possible risk of irreversible effects.
Safety Phrases:
S 16 Keep away from sources of ignition - No
smoking.
S 25 Avoid contact with eyes.
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 36/37 Wear suitable protective clothing and
gloves.
S 46 If swallowed, seek medical advice immediately
and show this container or label.
S 61 Avoid release to the environment. Refer to
special instructions/safety data sheets.
WGK (Water Danger/Protection)
CAS# 107-05-1: 2
Canada
CAS# 107-05-1 is listed on Canada's DSL List.
CAS# 107-05-1 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 107-05-1 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 8/27/1998 Revision #6 Date: 2/22/2005
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
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|
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|
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| 1191-43-1 |
|
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