**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 52-68-6 |O,O-Dimethyl-1-Hydroxy-2,2,2-Trichloro| 98 | 200-149-3 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN
Risk Phrases: 21/22 43
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful in contact with skin and if swallowed. May cause
sensitization by skin contact.
Potential Health Effects
Eye:
May cause mild eye irritation.
Skin:
May cause skin irritation. May cause skin sensitization, an allergic
reaction, which becomes evident upon re-exposure to this material.
May be harmful if absorbed through the skin.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea. May cause central nervous system effects and/or
neurological effects. May be harmful if swallowed.
Inhalation:
May cause respiratory tract irritation. May cause effects similar to
those described for ingestion.
Chronic:
Chronic ingestion may cause central nervous system failure.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and
drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid. Do NOT use mouth-to-mouth
resuscitation.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Use water
spray to keep fire-exposed containers cool. Use extinguishing media
appropriate to the surrounding fire. Substance is noncombustible.
Vapors may be heavier than air. They can spread along the ground and
collect in low or confined areas. Containers may explode when heated.
Extinguishing Media:
Substance is noncombustible; use agent most appropriate to
extinguish surrounding fire. Do NOT get water inside containers. Do
NOT use straight streams of water. For small fires, use dry chemical,
carbon dioxide, or water spray. For large fires, use water spray, fog
or regular foam. Cool containers with flooding quantities of water
until well after fire is out.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Clean up spills immediately, observing precautions in the Protective
Equipment section. Sweep up, then place into a suitable container for
disposal. Avoid generating dusty conditions. Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Use with adequate ventilation. Avoid
contact with eyes, skin, and clothing. Keep container tightly closed.
Keep away from heat, sparks and flame. Avoid ingestion and
inhalation.
Storage:
Keep away from heat, sparks, and flame. Store in a tightly closed
container. Store in a cool, dry, well-ventilated area away from
incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 52-68-6:
Russia: 0.5 mg/m3 TWA
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Crystals
Color: white
Odor: mild ether-like odor
pH: Not available.
Vapor Pressure: Negligible.
Viscosity: Not available.
Boiling Point: 100 deg C @ 1mmHg
Freezing/Melting Point: 77.00 - 81.00 C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: Slightly soluble.
Specific Gravity/Density: 1.7300
Molecular Formula: C4H8Cl3O4P
Molecular Weight: 257.3864
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, dust generation, excess heat, strong
oxidants.
Incompatibilities with Other Materials:
Oxidizing agents.
Hazardous Decomposition Products:
Hydrogen chloride, carbon monoxide, oxides of phosphorus, irritating
and toxic fumes and gases, carbon dioxide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 52-68-6: TA0700000
LD50/LC50:
CAS# 52-68-6: Draize test, rabbit, eye: 120 mg/6D (Intermittent)
Mild; Inhalation, rat: LC50 = 1300 mg/m3; Oral, mouse: LD50 = 300
mg/kg; Oral, rabbit: LD50 = 160 mg/kg; Oral, rat: LD50 = 450 mg/kg;
Oral, rat: LD50 = 882.7 mg/kg; Skin, rat: LD50 = 2 gm/kg.
Carcinogenicity:
O,O-Dimethyl-1-Hydroxy-2,2,2-Trichloroethylphosphonate -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Other
No information available.
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: ORGANOPHOSPHORUS PESTICIDE, SOLID, TOXIC*
Hazard Class: 6.1
UN Number: 2783
Packing Group: III
IMO
Shipping Name: ORGANOPHOSPHORUS PESTICIDE, SOLID, TOXIC
Hazard Class: 6.1
UN Number: 2783
Packing Group: III
RID/ADR
Shipping Name: ORGANOPHOSPHORUS PESTICIDE, SOLID, TOXIC
Hazard Class: 6.1
UN Number: 2783
Packing group: III
USA RQ: CAS# 52-68-6: 100 lb final RQ; 45.4 kg final RQ
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 21/22 Harmful in contact with skin and if
swallowed.
R 43 May cause sensitization by skin contact.
Safety Phrases:
S 24 Avoid contact with skin.
S 28A After contact with skin, wash immediately with
plenty of water.
S 37 Wear suitable gloves.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 52-68-6: 3
Canada
CAS# 52-68-6 is listed on Canada's DSL List.
CAS# 52-68-6 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 52-68-6 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 11/17/1998 Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
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Ethyl delta-bromo-beta,beta-dimethyl levulinate, 96%
| 197234-17-6 |
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1-Cyclohexyl-3-(2-Morpholinoethyl)Carbodiimide
| 2491-17-0 |
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3-Chloroanisole, 99%
| 2845-89-8 |
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2-Acetamidoacrylic acid, 99+ %
| 5429-56-1 |
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Bianthrone
| 434-85-5 |
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1-(4-Chlorophenyl)-1-cyclopentanecarbonyl chloride, 97%
| 71501-44-5 |
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Acetic acid-d, 98 atom % d
| 758-12-3 |
|
n-Phenyl-1-naphthylamine, 98%
| 90-30-2 |
|
5-Methyl-2-Nitrobenzyl Chloride
| 66424-91-7 |
|
2-Hydroxy-4-Methoxybenzophenone, 98%
| 131-57-7 |
|
Myristyltrimethylammonium bromide, 99% (ti tr.)
| 1119-97-7 |
|
Cyclododecanone, 99+%
| 830-13-7 |
|
4,4'-Biphenol, 97%
| 92-88-6 |
|
Diphenylacetylene (Tolan), 99%
| 501-65-5 |
|
Dicyclohexyl Phenyl Phosphine
| 6476-37-5 |
|
(+/-)-2-azabicyclo2.2.1hept-5-en-3-one 98% (hplc)
| 49805-30-3 |
|
Iron (III) Sulfate Tetrahydrate, Reagent (Powder), 97% (Titr.)
| 15244-10-7 |
|
Phenyl Isocyanate (Pract), 98% (gc)
| 103-71-9 |
|
3,5-Dichlorosalicylaldehyde
| 90-60-8 |
|
1,5-Dicyanopentane, 98%
| 646-20-8 |
|
2-Pyridinecarboxaldehyde, 99%
| 1121-60-4 |
|
Lithium Iodide, Anhydrous, 99%
| 10377-51-2 |
|
Alginic Acid, Sodium Salt
| 9005-38-3 |
|
(2R,3R)-1-Carboxy-4,5-dichloro-2,3-dihydroxycyclohexa-4,6-diene
| 205587-32-2 |
|
4-Chloro-3-Nitrobenzoic Acid, 99.5%
| 96-99-1 |
|
Barium Titanate(iv), 99%
| 12047-27-7 |
|
2,3-Dichloro-5,6 Dicyano-1,4-Benzoquinone, 98%
| 84-58-2 |
|
Triethanolamine hydrochloride
| 637-39-8 |
|
2,6-Diisopropylaniline, 95%
| 24544-04-5 |
|
3-Quinuclidinol, 99%
| 1619-34-7 |
|
n,n-Dimethylformamide diethyl acetal, 98%
| 1188-33-6 |
|
(R)-4-Benzyl-2-oxazolidinone, 99%, (>99% e.e.)
| 102029-44-7 |
|
2-Ethylimidazole, 98%
| 1072-62-4 |
|
All-Trans-Retinoic Acid 97%
| 302-79-4 |
|
Bis(2-Ethylhexyl) Terephthalate, 98.5% (GC)
| 6422-86-2 |
|
D(+)-10-camphorsulfonic acid 99%
| 3144-16-9 |
|
1,6-Hexanedithiol, 97%
| 1191-43-1 |
|
Ferric benzoylacetonate
| 14323-17-2 |
|
3-Chlorophenyl isothiocyanate
| 2392-68-9 |
|
1-Bromodecane, 98%
| 112-29-8 |
|
Didodecyldimethylammonium bromide, 99%
| 3282-73-3 |
|
1,4-Cyclohexadiene, 97%
| 628-41-1 |
|
Dl-3-(alpha-acetonyl-4'-chlorobenzyl)- 4-hydroxycoumarin, 98%
| 81-82-3 |
|
3-Nitrophenol, 99%
| 554-84-7 |
|
O,O-Dimethyl-1-Hydroxy-2,2,2-Trichloroethylphosphonate, 98%
| 52-68-6 |
|
Allyl Chloride
| 107-05-1 |
|
1,2,3,4-Tetrahydroacridine-9-Carboxylic Acid Dihydrate
| 38186-54-8 |
|
1-Bromododecane, 98%
| 143-15-7 |
|
Ethyl 2,4-dioxovalerate, 98%
| 615-79-2 |
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Arsenazo I, Indicator Grade
| 520-10-5 |
|
|