**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 66424-91-7 |5-Methyl-2-Nitrobenzyl Chloride | ca 100 | 266-359-2 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: C
Risk Phrases: 34
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Causes burns.Corrosive.Lachrymator (substance which increases the
flow of tears).
Potential Health Effects
Eye:
Contact with eyes may cause severe irritation, and possible eye
burns. Lachrymator (substance which increases the flow of tears).
May cause chemical conjunctivitis and corneal damage.
Skin:
May cause severe irritation and possible burns. May cause skin rash
(in milder cases), and cold and clammy skin with cyanosis or pale
color.
Ingestion:
May cause severe and permanent damage to the digestive tract. Causes
gastrointestinal tract burns. May cause perforation of the digestive
tract. May cause systemic effects.
Inhalation:
May cause severe irritation of the respiratory tract with sore
throat, coughing, shortness of breath and delayed lung edema. Causes
chemical burns to the respiratory tract. Aspiration may lead to
pulmonary edema. May cause systemic effects.
Chronic:
Effects may be delayed.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Get medical aid immediately. Do NOT allow victim to rub eyes or keep
eyes closed. Extensive irrigation with water is required (at least 30
minutes).
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes. Wash clothing before reuse. Destroy contaminated shoes.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If breathing is difficult, give oxygen. Do NOT use
mouth-to-mouth resuscitation. If breathing has ceased apply
artificial respiration using oxygen and a suitable mechanical device
such as a bag and a mask.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Use water
spray to keep fire-exposed containers cool. Vapors may be heavier
than air. They can spread along the ground and collect in low or
confined areas. Containers may explode when heated.
Extinguishing Media:
Cool containers with flooding quantities of water until well after
fire is out. Use water spray, dry chemical, carbon dioxide, or
appropriate foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Avoid runoff into storm sewers and
ditches which lead to waterways. Clean up spills immediately,
observing precautions in the Protective Equipment section. Remove all
sources of ignition. Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Keep container tightly closed. Do
not get on skin or in eyes. Do not ingest or inhale. Use with
adequate ventilation. Discard contaminated shoes.
Storage:
Keep container closed when not in use. Store in a cool, dry,
well-ventilated area away from incompatible substances. Corrosives
area.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 66424-91-7:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to minimize
contact with skin.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Powder
Color: tan
Odor: chlorine-like
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 41.00 - 43.00 deg C
Autoignition Temperature: Not available.
Flash Point: > 112 deg C (> 233.60 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C8H8ClNO2
Molecular Weight: 185.61
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable at room temperature in closed containers under normal storage
and handling conditions.
Conditions to Avoid:
Incompatible materials, dust generation, excess heat.
Incompatibilities with Other Materials:
Amines, bases, oxidizing agents, moisture, alcohols, steel.
Hazardous Decomposition Products:
Hydrogen chloride, carbon monoxide, irritating and toxic fumes and
gases, carbon dioxide, nitrogen oxides (NOx) and ammonia (NH3).
Hazardous Polymerization: Has not been reported
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 66424-91-7 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
5-Methyl-2-Nitrobenzyl Chloride -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: CORROSIVE SOLID, N.O.S.*
Hazard Class: 8
UN Number: 1759
Packing Group: II
IMO
Shipping Name: CORROSIVE SOLID, N.O.S.
Hazard Class: 8
UN Number: 1759
Packing Group: II
RID/ADR
Shipping Name: CORROSIVE LIQUID, N.O.S.
Hazard Class: 8
UN Number: 1760
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 34 Causes burns.
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
WGK (Water Danger/Protection)
CAS# 66424-91-7: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 66424-91-7 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 66424-91-7 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 7/20/1999 Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Ethyl delta-bromo-beta,beta-dimethyl levulinate, 96%
| 197234-17-6 |
|
1-Cyclohexyl-3-(2-Morpholinoethyl)Carbodiimide
| 2491-17-0 |
|
3-Chloroanisole, 99%
| 2845-89-8 |
|
2-Acetamidoacrylic acid, 99+ %
| 5429-56-1 |
|
Bianthrone
| 434-85-5 |
|
1-(4-Chlorophenyl)-1-cyclopentanecarbonyl chloride, 97%
| 71501-44-5 |
|
Acetic acid-d, 98 atom % d
| 758-12-3 |
|
n-Phenyl-1-naphthylamine, 98%
| 90-30-2 |
|
5-Methyl-2-Nitrobenzyl Chloride
| 66424-91-7 |
|
2-Hydroxy-4-Methoxybenzophenone, 98%
| 131-57-7 |
|
Myristyltrimethylammonium bromide, 99% (ti tr.)
| 1119-97-7 |
|
Cyclododecanone, 99+%
| 830-13-7 |
|
4,4'-Biphenol, 97%
| 92-88-6 |
|
Diphenylacetylene (Tolan), 99%
| 501-65-5 |
|
Dicyclohexyl Phenyl Phosphine
| 6476-37-5 |
|
(+/-)-2-azabicyclo2.2.1hept-5-en-3-one 98% (hplc)
| 49805-30-3 |
|
Iron (III) Sulfate Tetrahydrate, Reagent (Powder), 97% (Titr.)
| 15244-10-7 |
|
Phenyl Isocyanate (Pract), 98% (gc)
| 103-71-9 |
|
3,5-Dichlorosalicylaldehyde
| 90-60-8 |
|
1,5-Dicyanopentane, 98%
| 646-20-8 |
|
2-Pyridinecarboxaldehyde, 99%
| 1121-60-4 |
|
Lithium Iodide, Anhydrous, 99%
| 10377-51-2 |
|
Alginic Acid, Sodium Salt
| 9005-38-3 |
|
(2R,3R)-1-Carboxy-4,5-dichloro-2,3-dihydroxycyclohexa-4,6-diene
| 205587-32-2 |
|
4-Chloro-3-Nitrobenzoic Acid, 99.5%
| 96-99-1 |
|
Barium Titanate(iv), 99%
| 12047-27-7 |
|
2,3-Dichloro-5,6 Dicyano-1,4-Benzoquinone, 98%
| 84-58-2 |
|
Triethanolamine hydrochloride
| 637-39-8 |
|
2,6-Diisopropylaniline, 95%
| 24544-04-5 |
|
3-Quinuclidinol, 99%
| 1619-34-7 |
|
n,n-Dimethylformamide diethyl acetal, 98%
| 1188-33-6 |
|
(R)-4-Benzyl-2-oxazolidinone, 99%, (>99% e.e.)
| 102029-44-7 |
|
2-Ethylimidazole, 98%
| 1072-62-4 |
|
All-Trans-Retinoic Acid 97%
| 302-79-4 |
|
Bis(2-Ethylhexyl) Terephthalate, 98.5% (GC)
| 6422-86-2 |
|
D(+)-10-camphorsulfonic acid 99%
| 3144-16-9 |
|
1,6-Hexanedithiol, 97%
| 1191-43-1 |
|
Ferric benzoylacetonate
| 14323-17-2 |
|
3-Chlorophenyl isothiocyanate
| 2392-68-9 |
|
1-Bromodecane, 98%
| 112-29-8 |
|
Didodecyldimethylammonium bromide, 99%
| 3282-73-3 |
|
1,4-Cyclohexadiene, 97%
| 628-41-1 |
|
Dl-3-(alpha-acetonyl-4'-chlorobenzyl)- 4-hydroxycoumarin, 98%
| 81-82-3 |
|
3-Nitrophenol, 99%
| 554-84-7 |
|
O,O-Dimethyl-1-Hydroxy-2,2,2-Trichloroethylphosphonate, 98%
| 52-68-6 |
|
Allyl Chloride
| 107-05-1 |
|
1,2,3,4-Tetrahydroacridine-9-Carboxylic Acid Dihydrate
| 38186-54-8 |
|
1-Bromododecane, 98%
| 143-15-7 |
|
Ethyl 2,4-dioxovalerate, 98%
| 615-79-2 |
|
Arsenazo I, Indicator Grade
| 520-10-5 |
|
|