**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 107-06-2 |1,2-Dichloroethane | 100 | 203-458-1 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: T F
Risk Phrases: 11 22 36/37/38 45
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Highly flammable. Harmful if swallowed. Irritating to eyes,
respiratory system and skin. May cause cancer.
Potential Health Effects
Eye:
Causes eye irritation. Vapors may cause eye irritation. May cause
chemical conjunctivitis and corneal damage.
Skin:
Causes skin irritation. May be absorbed through the skin. May cause
irritation and dermatitis. May cause cyanosis of the extremities.
Ingestion:
May cause central nervous system depression, kidney damage, and
liver damage. May cause gastrointestinal irritation with nausea,
vomiting and diarrhea. May cause effects similar to those for
inhalation exposure. May be harmful if swallowed.
Inhalation:
Inhalation of high concentrations may cause central nervous system
effects characterized by nausea, headache, dizziness, unconsciousness
and coma. Causes respiratory tract irritation. May cause liver and
kidney damage. Aspiration may lead to pulmonary edema. Vapors may
cause dizziness or suffocation. Can produce delayed pulmonary edema.
Exposure to high concentrations may produce narcosis, nausea and loss
of consciousness. May cause burning sensation in the chest.
Chronic:
Possible cancer hazard based on tests with laboratory animals.
Prolonged or repeated skin contact may cause dermatitis. Prolonged or
repeated eye contact may cause conjunctivitis. May cause liver and
kidney damage. Effects may be delayed.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of soap and water for at
least 15 minutes while removing contaminated clothing and shoes. Wash
clothing before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and
drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure to fresh air immediately. If not breathing,
give artificial respiration. If breathing is difficult, give oxygen.
Get medical aid. Do NOT use mouth-to-mouth resuscitation.
Notes to Physician:
Treat symptomatically and supportively.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Vapors may form an explosive mixture with air.
During a fire, irritating and highly toxic gases may be generated by
thermal decomposition or combustion. Use water spray to keep
fire-exposed containers cool. Flammable liquid and vapor. Approach
fire from upwind to avoid hazardous vapors and toxic decomposition
products. Vapors are heavier than air and may travel to a source of
ignition and flash back. Vapors can spread along the ground and
collect in low or confined areas.
Extinguishing Media:
For small fires, use dry chemical, carbon dioxide, water spray or
alcohol-resistant foam. For large fires, use water spray, fog, or
alcohol-resistant foam. Water may be ineffective. Do NOT use
straight streams of water.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Avoid runoff into storm sewers and
ditches which lead to waterways. Clean up spills immediately,
observing precautions in the Protective Equipment section. Remove all
sources of ignition. Use a spark-proof tool. Provide ventilation. A
vapor suppressing foam may be used to reduce vapors.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Ground and bond containers when transferring
material. Use spark-proof tools and explosion proof equipment. Avoid
contact with eyes, skin, and clothing. Empty containers retain
product residue, (liquid and/or vapor), and can be dangerous. Keep
container tightly closed. Do not pressurize, cut, weld, braze,
solder, drill, grind, or expose empty containers to heat, sparks or
open flames. Use only with adequate ventilation. Keep away from heat,
sparks and flame. Avoid breathing vapor or mist.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of
ignition. Store in a tightly closed container. Keep from contact
with oxidizing materials. Store in a cool, dry, well-ventilated area
away from incompatible substances. Flammables-area. Storage under a
nitrogen blanket has been recommended.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate general or
local explosion-proof ventilation to keep airborne levels to
acceptable levels.
Personal Protective Equipment
Eyes:
Wear chemical goggles.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR ??1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant a respirator's use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Appearance: colourless
Odor: chloroform-like
pH: Not available.
Vapor Pressure: 100 mm Hg @29 deg C
Viscosity: Not available.
Boiling Point: 81-85 deg C
Freezing/Melting Point: -35 deg C
Autoignition Temperature: 775 deg F ( 412.78 deg C)
Flash Point: 56 deg F ( 13.33 deg C)
Explosion Limits, lower: 6.2%
Explosion Limits, upper: 15.9%
Decomposition Temperature: Not available.
Solubility in water: Insoluble.
Specific Gravity/Density: 1.25 (Water=1)
Molecular Formula: C2H4Cl2
Molecular Weight: 98.96
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable at room temperature in closed containers under normal storage
and handling conditions.
Conditions to Avoid:
Light, ignition sources, excess heat, electrical sparks.
Incompatibilities with Other Materials:
Aluminum, bases, alkali metals, ketones, organic peroxides, nitric
acid, strong oxidizing agents, strong reducing agents, liquid
ammonia, amines.
Hazardous Decomposition Products:
Hydrogen chloride, phosgene, carbon monoxide, irritating and toxic
fumes and gases, carbon dioxide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 107-06-2: KI0525000
LD50/LC50:
CAS# 107-06-2: Draize test, rabbit, eye: 63 mg Severe; Draize test,
rabbit, eye: 500 mg/24H Mild; Draize test, rabbit, skin: 500 mg/24H
Mild; Inhalation, rat: LC50 = 1000 ppm/7H; Oral, mouse: LD50 = 413
mg/kg; Oral, rabbit: LD50 = 860 mg/kg; Oral, rat: LD50 = 670 mg/kg;
Skin, rabbit: LD50 = 2800 mg/kg.
Carcinogenicity:
1,2-Dichloroethane -
ACGIH: A4 - Not Classifiable as a Human Carcinogen
California: carcinogen; initial date 10/1/87
NIOSH: occupational carcinogen
NTP: Suspect carcinogen
OSHA: Possible Select carcinogen
IARC: Group 2B carcinogen
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Ecotoxicity:
Water flea Daphnia: 218mg/L; 48HFish: Bluegill/Sunfish: 430mg/L; 96H;
StaticFish: Fathead Minnow: 136mg/L; 96H; Static
Other
For more information, see "HANDBOOK OF ENVIRONMENTAL FATE AND
EXPOSURE DATA."
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: Ethylene Dichloride
Hazard Class: 3
UN Number: 1184
Packing Group: II
IMO
Shipping Name: Ethylene Dichloride
Hazard Class: 3
UN Number: 1184
Packing Group: II
RID/ADR
Shipping Name: Ethylene Dichloride
Dangerous Goods Code: 3
UN Number: 1184
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T F
Risk Phrases:
R 11 Highly flammable.
R 22 Harmful if swallowed.
R 36/37/38 Irritating to eyes, respiratory system
and skin.
R 45 May cause cancer.
Safety Phrases:
S 53 Avoid exposure - obtain special instructions
before use.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 107-06-2: 3
United Kingdom Occupational Exposure Limits
Canada
CAS# 107-06-2 is listed on Canada's DSL List.
CAS# 107-06-2 is listed on Canada's Ingredient Disclosure List.
Exposure Limits
CAS# 107-06-2: OEL-ARAB Republic of Egypt:TWA 5 ppm (2 mg/m3)
OEL-AUSTRALIA:TWA 10 ppm (40 mg/m3)
OEL-AUSTRIA:TWA 20 ppm (80 mg/m3)
OEL-BELGIUM:TWA 10 ppm (40 mg/m3)
OEL-DENMARK:TWA 1 ppm (4 mg/m3);Skin
OEL-FINLAND:TWA 10 ppm (40 mg/m3);STEL 20 ppm (80 mg/m3);CAR
OEL-FRANCE:TWA 10 ppm (40 mg/m3)
OEL-GERMANY;Carcinogen
OEL-HUNGARY:STEL 4 mg/m3;Carcinogen
OEL-JAPAN:TWA 10 ppm (40 mg/m3)
OEL-THE NETHERLANDS:TWA 50 ppm (200 mg/m3)
OEL-THE PHILIPPINES:TWA 50 ppm (200 mg/m3)
OEL-RUSSIA:TWA 10 ppm
OEL-SWEDEN:TWA 1 ppm (4 mg/m3);STEL 5 ppm (20 mg/m3);Skin;CAR
OEL-SWITZERLAND:TWA 10 ppm (40 mg/m3);STEL 20 ppm (80 mg/m3)
OEL-TURKEY:TWA 50 ppm (200 mg/m3)
OEL-UNITED KINGDOM:TWA 10 ppm (40 mg/m3);STEL 15 ppm (60 mg/m3)
OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV
OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGI TLV
US FEDERAL
TSCA
CAS# 107-06-2 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 1/18/1999 Revision #6 Date: 4/17/2002
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
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