**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
|----------------|--------------------------------------|----------|-----------|
| 7784-31-8 |Aluminum sulfate octadecahydrate | >98 | unlisted |
|----------------|--------------------------------------|----------|-----------|
+----------------+--------------------------------------+----------+-----------+
Text for R-phrases: see Section 16
Hazard Symbols: None Listed.
Risk Phrases: None Listed.
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
The toxicological properties of this material have not been fully
investigated.
Potential Health Effects
Eye:
Dust may cause mechanical irritation.
Skin:
May cause skin irritation.
Ingestion:
Ingestion of large amounts may cause gastrointestinal irritation.
The toxicological properties of this substance have not been fully
investigated.
Inhalation:
May cause respiratory tract irritation.
Chronic:
No information found.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Flush skin with plenty of water for at least 15 minutes while
removing contaminated clothing and shoes. Get medical aid if
irritation develops or persists. Wash clothing before reuse.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Get medical aid immediately.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid if cough or other symptoms appear.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container. Clean up spills immediately, observing precautions in the
Protective Equipment section. Avoid generating dusty conditions.
Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Use with adequate ventilation.
Minimize dust generation and accumulation. Avoid contact with eyes,
skin, and clothing. Keep container tightly closed. Avoid ingestion
and inhalation.
Storage:
Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use process enclosure, local exhaust ventilation, or other
engineering controls to control airborne levels below recommended
exposure limits. Facilities storing or utilizing this material should
be equipped with an eyewash facility and a safety shower.
Exposure Limits
CAS# 7784-31-8:
United Kingdom, WEL - TWA: (listed as aluminum, soluble salts): 2
mg/m3 TWA
United Kingdom, WEL - STEL: (listed as aluminum, soluble salts):
mg/m3 STEL
Belgium - TWA: (listed as aluminum, soluble salts): 2 mg/m3 VLE (
Al)
France - VME: (listed as aluminum, soluble salts): 2 mg/m3 VME
Germany: (listed as aluminum, soluble salts): 2 mg/m3 VME
Malaysia: (listed as aluminum, soluble salts): 2 mg/m3 TWA (as Al
Spain: (listed as aluminum, soluble salts): 2 mg/m3 VLA-ED (as Al
CAS# 10043-01-3:
United Kingdom, WEL - TWA: (listed as aluminum, soluble salts): 2
mg/m3 TWA
United Kingdom, WEL - STEL: (listed as aluminum, soluble salts):
mg/m3 STEL
Belgium - TWA: (listed as aluminum, soluble salts): 2 mg/m3 VLE (
Al)
France - VME: (listed as aluminum, soluble salts): 2 mg/m3 VME
Germany: (listed as aluminum, soluble salts): 2 mg/m3 VME
Malaysia: (listed as aluminum, soluble salts): 2 mg/m3 TWA (as Al
Spain: (listed as aluminum, soluble salts): 2 mg/m3 VLA-ED (as Al
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Solid
Color: white crystalline chunks
Odor: Not available.
pH: 3-4 (2% soln)
Vapor Pressure: Negligible.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 86 deg C (dec)
Autoignition Temperature: Not available.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: >86 deg C
Solubility in water: Soluble.
Specific Gravity/Density:
Molecular Formula: Al2O12S3.18H2O
Molecular Weight: 666.42
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Dust generation.
Incompatibilities with Other Materials:
Incompatible with strong oxidizing agents; moisture. Decomposes in
water which may generate quantities of heat or pressure.
Hazardous Decomposition Products:
Oxides of sulfur, aluminum oxide.
Hazardous Polymerization: Has not been reported
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 7784-31-8: WS5697000
CAS# 10043-01-3: BD1700000
LD50/LC50:
CAS# 7784-31-8: Oral, mouse: LD50 = 980 mg/kg; Oral, rat: LD50 = 370
mg/kg.
CAS# 10043-01-3: Draize test, rabbit, eye: 10 mg/24H Severe; Oral,
mouse: LD50 = 6207 mg/kg.
Carcinogenicity:
Aluminum sulfate octadecahydrate -
Not listed by ACGIH, IARC, or NTP.
Aluminum sulfate, anhydrous -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing Group:
IMO
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing Group:
RID/ADR
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing group:
USA RQ: CAS# 10043-01-3: 5000 lb final RQ; 2270 kg final RQ
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 7784-31-8: No information available.
CAS# 10043-01-3: 1
Canada
CAS# 10043-01-3 is listed on Canada's DSL List.
CAS# 7784-31-8 is not listed on Canada's Ingredient Disclosure List.
CAS# 10043-01-3 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 7784-31-8 is not on the TSCA Inventory because it is a hydrate.
It is considered to be listed if the CAS number for the anhydrous form
is on the inventory (40CFR720.3(u)(2)).
CAS# 10043-01-3 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
Text for R-phrases from Section 2
MSDS Creation Date: 9/02/1997 Revision #5 Date: 3/10/2004
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Methyl methacrylate, 99+% (GC)
| 80-62-6 |
|
Bicine, Biograde
| 150-25-4 |
|
Methyl P-Hydroxybenzoate, 99% (Titr.)
| 99-76-3 |
|
Methyl Red, reagent ACS
| 493-52-7 |
|
Methyl Salicylate, 99+%
| 119-36-8 |
|
Triethylphenylammonium iodide, 99% (titr.)
| 1010-19-1 |
|
CAPS, BioGRADE
| 1135-40-6 |
|
1,6-Dibromohexane, 98%
| 629-03-8 |
|
tert-Butyl methyl ether, 99%
| 1634-04-4 |
|
MES monohydrate
| 4432-31-9 |
|
Aluminum sulfate
| 10043-01-3 |
|
Aluminum sulfate octadecahydrate
| 7784-31-8 |
|
Dimethoxymethane, 99.5+%
| 109-87-5 |
|
Methylamine, 40 wt. % solution in water
| 74-89-5 |
|
TAPS, Biograde
| 29915-38-6 |
|
TRICINE, BioGRADE
| 5704-04-1 |
|
Acetone, Electronic Use Grade, Residue Free
| 67-64-1 |
|
Butyl acetate Electronic use grade, residue free
| 123-86-4 |
|
1,2-Dichloroethane, electronic use grade, residue free
| 107-06-2 |
|
Dichloromethane, Stabilized, Electronic Use Grade, Residue Free
| 75-09-2 |
|
Ethyl Acetate, Electronic use Grade, Residue Free
| 141-78-6 |
|
N-Hexane, Electronic Use Grade, Residue Free
| 110-54-3 |
|
Methyl alcohol, electronic use grade, residue free
| 67-56-1 |
|
2-Butanone, Electronic Use Grade, Residue Free
| 78-93-3 |
|
4-Methyl-2-Pentanone, Electronic Use Grade, Residue Free
| 108-10-1 |
|
Isopropanol, Electronic use Grade, Residue Free
| 67-63-0 |
|
Xylenes mixed, electronic use grade, residue free
| 1330-20-7 |
|
5-Fluorocytosine, 98%
| 2022-85-7 |
|
A23187 (Free Acid)
| 52665-69-7 |
|
A23187(Mixed Calcium-Magnesium Salt)
| 52665-69-7 |
|
Aluminum (Metallic, Powder)
| 7429-90-5 |
|
A23187, 4-Bromo
| 76455-82-8 |
|
Hydroxyurea, 98%
| 127-07-1 |
|
AEBSF Hydrochloride
| 30827-99-7 |
|
Calmidazolium chloride
| 57265-65-3 |
|
Calpain Inhibitor I
| 110044-82-1 |
|
Calpain Inhibitor II
| 136632-32-1 |
|
Calpeptin
| 117591-20-5 |
|
Calphostin C
| 121263-19-2 |
|
Capsazepine
| 138977-28-3 |
|
Creatine Phosphate Disodium Salt Tetrahydrate, 99%
| 922-32-7 |
|
D-LUCIFERIN
| 2591-17-5 |
|
D-LUCIFERIN SODIUM SALT MONOHYDRATE
| 103404-75-7 |
|
4-Nitrophenyl-Beta-D-Glucuronide
| 10344-94-2 |
|
4-NITROPHENYL-ALPHA-D-MANNOPYRANOSIDE HYDRATE, 99%
| 10357-27-4 |
|
Dichloromethane, CP, Stabilized With ca 0.2% Ethanol
| 75-09-2 |
|
Tris(2-butoxyethyl)phosphate 98%
| 78-51-3 |
|
D-Ribose-5-Phosphate Disodium Salt Hydrate, 95%
| 18265-46-8 |
|
Diiodomethane, 99+%
| 75-11-6 |
|
2-Phenylethyl-Beta-D-Thiogalactoside
| 63407-54-5 |
|
|