**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 119-36-8 |METHYL SALICYLATE | >99% | 204-317-7 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN
Risk Phrases: 22 36/38
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful if swallowed. Irritating to eyes and skin.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
Causes moderate skin irritation. May be absorbed through the skin in
harmful amounts.
Ingestion:
May cause nausea and vomiting. May be harmful if swallowed.
Inhalation:
Causes respiratory tract irritation. Irritation may lead to chemical
pneumonitis and pulmonary edema. May cause effects similar to those
described for ingestion. May cause lung damage.
Chronic:
May cause liver and kidney damage. Repeated exposure may cause
metabolic disturbances.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Immediately flush skin with plenty of water for at least 15 minutes
while removing contaminated clothing and shoes. Get medical aid if
irritation develops or persists. Wash clothing before reuse.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Get medical aid immediately. Call a poison
control center.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid. Do NOT use mouth-to-mouth
resuscitation.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Vapors can travel to a source of ignition and flash
back. During a fire, irritating and highly toxic gases may be
generated by thermal decomposition or combustion. Use water spray to
keep fire-exposed containers cool. Vapors may be heavier than air.
They can spread along the ground and collect in low or confined
areas. Containers may explode when heated.
Extinguishing Media:
Water or foam may cause frothing. Use carbon dioxide or dry
chemical. Cool containers with flooding quantities of water until
well after fire is out.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Avoid runoff into storm sewers and ditches which lead to waterways.
Clean up spills immediately, observing precautions in the Protective
Equipment section. Remove all sources of ignition. Absorb spill using
an absorbent, non-combustible material such as earth, sand, or
vermiculite. Do not use combustible materials such as sawdust.
Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use with adequate ventilation. Ground and bond
containers when transferring material. Do not get on skin or in eyes.
Do not ingest or inhale.
Storage:
Keep from contact with oxidizing materials. Store in a cool, dry,
well-ventilated area away from incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate general or
local exhaust ventilation to keep airborne concentrations below the
permissible exposure limits.
Exposure Limits
CAS# 119-36-8:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: colorless to yellow-red
Odor: wintergreen odor
pH: Not available.
Vapor Pressure: .1 mm Hg @ 20C
Viscosity: Not available.
Boiling Point: 433.9 deg F
Freezing/Melting Point: 16.5 deg F
Autoignition Temperature: 850 deg F ( 454.44 deg C)
Flash Point: 205 deg F ( 96.11 deg C)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: Not available.
Solubility in water: Slightly soluble in water.
Specific Gravity/Density: 1.18 (water=1)
Molecular Formula: C8H8O3
Molecular Weight: 152.0542
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable at room temperature in closed containers under normal storage
and handling conditions.
Conditions to Avoid:
Incompatible materials, ignition sources, excess heat.
Incompatibilities with Other Materials:
Strong oxidizing agents, strong bases.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide, salicyclic acid.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 119-36-8: VO4725000
LD50/LC50:
CAS# 119-36-8: Draize test, rabbit, eye: 500 mg/24H Mild; Draize
test, rabbit, skin: 500 mg/24H Moderate; Oral, mouse: LD50 = 1110
mg/kg; Oral, rabbit: LD50 = 1300 mg/kg; Oral, rat: LD50 = 887 mg/kg;
Oral, rat: LD50 = 1220 mg/kg.
Carcinogenicity:
METHYL SALICYLATE -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Other
No information available.
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 22 Harmful if swallowed.
R 36/38 Irritating to eyes and skin.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
WGK (Water Danger/Protection)
CAS# 119-36-8: 1
Canada
CAS# 119-36-8 is listed on Canada's DSL List.
CAS# 119-36-8 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 119-36-8 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/02/1998 Revision #4 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Methyl methacrylate, 99+% (GC)
| 80-62-6 |
|
Bicine, Biograde
| 150-25-4 |
|
Methyl P-Hydroxybenzoate, 99% (Titr.)
| 99-76-3 |
|
Methyl Red, reagent ACS
| 493-52-7 |
|
Methyl Salicylate, 99+%
| 119-36-8 |
|
Triethylphenylammonium iodide, 99% (titr.)
| 1010-19-1 |
|
CAPS, BioGRADE
| 1135-40-6 |
|
1,6-Dibromohexane, 98%
| 629-03-8 |
|
tert-Butyl methyl ether, 99%
| 1634-04-4 |
|
MES monohydrate
| 4432-31-9 |
|
Aluminum sulfate
| 10043-01-3 |
|
Aluminum sulfate octadecahydrate
| 7784-31-8 |
|
Dimethoxymethane, 99.5+%
| 109-87-5 |
|
Methylamine, 40 wt. % solution in water
| 74-89-5 |
|
TAPS, Biograde
| 29915-38-6 |
|
TRICINE, BioGRADE
| 5704-04-1 |
|
Acetone, Electronic Use Grade, Residue Free
| 67-64-1 |
|
Butyl acetate Electronic use grade, residue free
| 123-86-4 |
|
1,2-Dichloroethane, electronic use grade, residue free
| 107-06-2 |
|
Dichloromethane, Stabilized, Electronic Use Grade, Residue Free
| 75-09-2 |
|
Ethyl Acetate, Electronic use Grade, Residue Free
| 141-78-6 |
|
N-Hexane, Electronic Use Grade, Residue Free
| 110-54-3 |
|
Methyl alcohol, electronic use grade, residue free
| 67-56-1 |
|
2-Butanone, Electronic Use Grade, Residue Free
| 78-93-3 |
|
4-Methyl-2-Pentanone, Electronic Use Grade, Residue Free
| 108-10-1 |
|
Isopropanol, Electronic use Grade, Residue Free
| 67-63-0 |
|
Xylenes mixed, electronic use grade, residue free
| 1330-20-7 |
|
5-Fluorocytosine, 98%
| 2022-85-7 |
|
A23187 (Free Acid)
| 52665-69-7 |
|
A23187(Mixed Calcium-Magnesium Salt)
| 52665-69-7 |
|
Aluminum (Metallic, Powder)
| 7429-90-5 |
|
A23187, 4-Bromo
| 76455-82-8 |
|
Hydroxyurea, 98%
| 127-07-1 |
|
AEBSF Hydrochloride
| 30827-99-7 |
|
Calmidazolium chloride
| 57265-65-3 |
|
Calpain Inhibitor I
| 110044-82-1 |
|
Calpain Inhibitor II
| 136632-32-1 |
|
Calpeptin
| 117591-20-5 |
|
Calphostin C
| 121263-19-2 |
|
Capsazepine
| 138977-28-3 |
|
Creatine Phosphate Disodium Salt Tetrahydrate, 99%
| 922-32-7 |
|
D-LUCIFERIN
| 2591-17-5 |
|
D-LUCIFERIN SODIUM SALT MONOHYDRATE
| 103404-75-7 |
|
4-Nitrophenyl-Beta-D-Glucuronide
| 10344-94-2 |
|
4-NITROPHENYL-ALPHA-D-MANNOPYRANOSIDE HYDRATE, 99%
| 10357-27-4 |
|
Dichloromethane, CP, Stabilized With ca 0.2% Ethanol
| 75-09-2 |
|
Tris(2-butoxyethyl)phosphate 98%
| 78-51-3 |
|
D-Ribose-5-Phosphate Disodium Salt Hydrate, 95%
| 18265-46-8 |
|
Diiodomethane, 99+%
| 75-11-6 |
|
2-Phenylethyl-Beta-D-Thiogalactoside
| 63407-54-5 |
|
|