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MSDS 
:
 Allyl alcohol
CAS 
:
 107-18-6
SYNONYMS 
:
 3-Hydroxypropene; Propenol; Propenyl alcohol.
**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****

+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 107-18-6 |Allyl alcohol | 99 | 203-470-7 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: T N
Risk Phrases: 10 23/24/25 36/37/38 50

**** SECTION 3 - HAZARDS IDENTIFICATION ****

EMERGENCY OVERVIEW
Flammable. Toxic by inhalation, in contact with skin and if
swallowed. Irritating to eyes, respiratory system and skin. Very
toxic to aquatic organisms.

Potential Health Effects
Eye:
Causes severe eye irritation. Lachrymator (substance which
increases the flow of tears).
Skin:
Causes skin irritation. May be fatal if absorbed through the skin.
Ingestion:
Harmful if swallowed. Causes gastrointestinal irritation with
nausea, vomiting and diarrhea. May cause central nervous system
depression, characterized by excitement, followed by headache,
dizziness, drowsiness, and nausea. Advanced stages may cause
collapse, unconsciousness, coma and possible death due to respiratory
failure.
Inhalation:
May be fatal if inhaled. May cause severe irritation of the
respiratory tract with sore throat, coughing, shortness of breath
and delayed lung edema. May cause pulmonary edema and severe
respiratory disturbances. Vapors may cause dizziness or suffocation.
Chronic:
May cause liver and kidney damage. Effects may be delayed.

**** SECTION 4 - FIRST AID MEASURES ****

Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately. Do NOT allow victim to rub eyes or keep eyes closed.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes. Wash clothing before reuse.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen. Do NOT use mouth-to-mouth
resuscitation.
Notes to Physician:
Treat symptomatically and supportively.

**** SECTION 5 - FIRE FIGHTING MEASURES ****

General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Vapors may form an explosive mixture with air. Use
water spray to keep fire-exposed containers cool. Containers may
explode in the heat of a fire. Flammable liquid and vapor. Vapors are
heavier than air and may travel to a source of ignition and flash
back. Vapors can spread along the ground and collect in low or
confined areas.
Extinguishing Media:
For small fires, use dry chemical, carbon dioxide, water spray or
alcohol-resistant foam. For large fires, use water spray, fog, or
alcohol-resistant foam. Use water spray to cool fire-exposed
containers. Water may be ineffective. Do NOT use straight streams of
water.

**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****

General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Clean up spills immediately,
observing precautions in the Protective Equipment section. Remove all
sources of ignition. Use a spark-proof tool. Provide ventilation.
Approach spill from upwind. Use water spray to cool and disperse
vapors, protect personnel, and dilute spills to form nonflammable
mixtures. Control runoff and isolate discharged material for proper
disposal.

**** SECTION 7 - HANDLING and STORAGE ****

Handling:
Wash thoroughly after handling. Wash hands before eating. Use only
in a well-ventilated area. Ground and bond containers when
transferring material. Use spark-proof tools and explosion proof
equipment. Do not get in eyes, on skin, or on clothing. Empty
containers retain product residue, (liquid and/or vapor), and can be
dangerous. Keep away from heat, sparks and flame. Do not ingest or
inhale. Do not pressurize, cut, weld, braze, solder, drill, grind, or
expose empty containers to heat, sparks or open flames.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of
ignition. Store in a cool, dry, well-ventilated area away from
incompatible substances. Flammables-area.

**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****

Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate general or
local explosion-proof ventilation to keep airborne levels to
acceptable levels.
Exposure Limits
CAS# 107-18-6:
United Kingdom, WEL - TWA: 2 ppm TWA; 4.8 mg/m3 TWA
United Kingdom, WEL - STEL: 4 ppm STEL; 9.7 mg/m3 STEL
United States OSHA: 2 ppm TWA; 5 mg/m3 TWA
Belgium - TWA: 2 ppm VLE; 4.8 mg/m3 VLE
Belgium - STEL: 4 ppm VLE; 9.6 mg/m3 VLE
France - VME: 2 ppm VME; 5 mg/m3 VME
France - VLE: 4 ppm VLE; 10 mg/m3 VLE
Germany: 4.8 mg/m3 TWA
Germany: Skin absorber
Japan: 1 ppm OEL; 2.4 mg/m3 OEL
Malaysia: 0.5 ppm TWA; 1.2 mg/m3 TWA
Netherlands: 2 ppm MAC; 5 mg/m3 MAC
Spain: 2 ppm VLA-ED; 5 mg/m3 VLA-ED
Spain: 5 ppm VLA-EC; 12 mg/m3 VLA-EC

Personal Protective Equipment

Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.

**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****

Physical State: Liquid
Color: clear, colorless
Odor: pungent odor - mustard-like
pH: Not available.
Vapor Pressure: 17 mm Hg @ 20 deg C
Viscosity: Not available.
Boiling Point: 97 deg C
Freezing/Melting Point: -129 deg C
Autoignition Temperature: 378 deg C ( 712.40 deg F)
Flash Point: 21 deg C ( 69.80 deg F)
Explosion Limits, lower: 2.5%
Explosion Limits, upper: 18.0%
Decomposition Temperature: Not available.
Solubility in water: Soluble.
Specific Gravity/Density: 0.85
Molecular Formula: C3H6O
Molecular Weight: 58.08

**** SECTION 10 - STABILITY AND REACTIVITY ****

Chemical Stability:
May polymerize.
Conditions to Avoid:
Ignition sources, excess heat, confined spaces.
Incompatibilities with Other Materials:
Metals, strong oxidizing agents, strong acids, amines, peroxides,
polymerization catalysts.
Hazardous Decomposition Products:
Carbon monoxide, irritating and toxic fumes and gases, carbon
dioxide.
Hazardous Polymerization: Will occur.

**** SECTION 11 - TOXICOLOGICAL INFORMATION ****

RTECS#:
CAS# 107-18-6: BA5075000
LD50/LC50:
CAS# 107-18-6: Draize test, rabbit, eye: 20 mg Severe; Inhalation,
mouse: LC50 = 500 mg/m3/2H; Inhalation, mouse: LC50 = 500 mg/m3/2H;
Inhalation, rat: LC50 = 76 ppm/8H; Oral, mouse: LD50 = 96 mg/kg;
Oral, mouse: LD50 = 75 mg/kg; Oral, rabbit: LD50 = 52 mg/kg; Oral,
rat: LD50 = 64 mg/kg; Skin, rabbit: LD50 = 45 mg/kg.
Carcinogenicity:
Allyl alcohol -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.

**** SECTION 12 - ECOLOGICAL INFORMATION ****

Ecotoxicity:
Fish: Goldfish: LC50 = 1 mg/L; 24 Hr.; UnspecifiedBacteria:
Phytobacterium phosphoreum: EC50 = 216-608 mg/L; 5,15,30 Minutes;
Microtox test

**** SECTION 13 - DISPOSAL CONSIDERATIONS ****

Dispose of in a manner consistent with federal, state, and local regulations.

**** SECTION 14 - TRANSPORT INFORMATION ****

IATA
Shipping Name: ALLYL ALCOHOL
Hazard Class: 6.1 (3)
UN Number: 1098
Packing Group:
IMO
Shipping Name: ALLYL ALCOHOL
Hazard Class: 6.1 (3)
UN Number: 1098
Packing Group: I
RID/ADR
Shipping Name: ALLYL ALCOHOL
Hazard Class: 6.1
UN Number: 1098
Packing group: I
USA RQ: CAS# 107-18-6: 100 lb final RQ; 45.4 kg final RQ

**** SECTION 15 - REGULATORY INFORMATION ****

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T N
Risk Phrases:
R 10 Flammable.
R 23/24/25 Toxic by inhalation, in contact with skin
and if swallowed.
R 36/37/38 Irritating to eyes, respiratory system
and skin.
R 50 Very toxic to aquatic organisms.
Safety Phrases:
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 38 In case of insufficient ventilation, wear
suitable respiratory equipment.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
S 61 Avoid release to the environment. Refer to
special instructions/safety data sheets.
WGK (Water Danger/Protection)
CAS# 107-18-6: 2
Canada
CAS# 107-18-6 is listed on Canada's DSL List.
CAS# 107-18-6 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 107-18-6 is listed on the TSCA inventory.

**** SECTION 16 - ADDITIONAL INFORMATION ****

MSDS Creation Date: 5/10/1999 Revision #6 Date: 3/01/2005

The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
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