**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 3115-68-2 |Tetrabutylphosphonium bromide | 98 | 221-487-8 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN
Risk Phrases: 21 36/37/38
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful in contact with skin. Irritating to eyes, respiratory system
and skin.Hygroscopic (absorbs moisture from the air).Toxic.
Potential Health Effects
Eye:
Causes severe eye irritation and possible burns.
Skin:
May be fatal if absorbed through the skin. Causes severe skin
irritation and possible burns.
Ingestion:
Causes gastrointestinal irritation with nausea, vomiting and
diarrhea. May be harmful if swallowed.
Inhalation:
May be harmful if inhaled. Causes irritation of the mucous membrane
and upper respiratory tract.
Chronic:
No information found.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid immediately. Do NOT induce vomiting. If conscious and alert,
rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. Do not use mouth-to-mouth resuscitation if victim
ingested or inhaled the substance; induce artificial respiration with
the aid of a pocket mask equipped with a one-way valve or other
proper respiratory medical device.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or appropriate foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Wash area with soap and water. Clean up spills immediately,
observing precautions in the Protective Equipment section. Sweep up,
then place into a suitable container for disposal. Avoid generating
dusty conditions. Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Use with adequate ventilation. Do
not get in eyes, on skin, or on clothing. Keep container tightly
closed. Do not ingest or inhale. Keep from contact with moist air and
steam. Do not breathe dust or fumes.
Storage:
Keep containers tightly closed. Store protected from moisture. Store
in a cool, dry area away from incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 3115-68-2:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Crystalline powder
Color: white to cream
Odor: None reported.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 100.00 - 103.00 deg C
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: Not available.
Solubility in water: ca 70% (forming syrup with 10-15%)
Specific Gravity/Density: Not available.
Molecular Formula: C16H36BrP
Molecular Weight: 339.33
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, moisture.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Phosphine, carbon monoxide, oxides of phosphorus, carbon dioxide,
hydrogen bromide, bromine fumes, palladium.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 3115-68-2: TA2417000
LD50/LC50:
CAS# 3115-68-2: Draize test, rabbit, eye: 100 uL/24H Severe; Draize
test, rabbit, skin: 500 mg Severe; Inhalation, rat: LC50 = >3
mg/m3/1H; Oral, rat: LD50 = 420 mg/kg; Skin, rabbit: LD50 = 197
mg/kg.
Carcinogenicity:
Tetrabutylphosphonium bromide -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Other
No information available.
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: TOXIC SOLID, ORGANIC, N.O.S.*
Hazard Class: 6.1
UN Number: 2811
Packing Group: III
IMO
Shipping Name: TOXIC SOLID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2811
Packing Group: III
RID/ADR
Shipping Name: TOXIC SOLID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2811
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 21 Harmful in contact with skin.
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 28A After contact with skin, wash immediately with
plenty of water.
WGK (Water Danger/Protection)
CAS# 3115-68-2: No information available.
Canada
CAS# 3115-68-2 is listed on Canada's DSL List.
CAS# 3115-68-2 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 3115-68-2 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 7/12/1999 Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
2,6-Pyridinedicarboxylic Acid Chloride, 97%
| 3739-94-4 |
|
OPD tablets, 120 mg/tablet
| 615-28-1 |
|
Tetrabutylphosphonium bromide, 98%
| 3115-68-2 |
|
2'-Deoxyguanosine 5'-Monophosphate, Sodium Salt Hydrate
| 52558-16-4 |
|
4-(Dimethylamino)pyridinium Bromide Perbromide
| 92976-81-3 |
|
Mercury(ii) thiocyanate, p.a.
| 592-85-8 |
|
Beta-Ionone, Synthetic, 96%
| 14901-07-6 |
|
Quercetin (Pract)
| 117-39-5 |
|
4-Chlorobenzotrichloride, 99%
| 5216-25-1 |
|
1-Iodopropane, 99%, Stabilized over Copper
| 107-08-4 |
|
2-Acetyl-1-methylpyrrole, 99%
| 932-16-1 |
|
4-Dimethylamino-4'-nitrostilbene
| 4584-57-0 |
|
Pentafluorothiophenol, 97%
| 771-62-0 |
|
1-(4-METHOXYPHENYL)-1-CYCLOPROPANE- CARBONITRILE
| 16728-00-0 |
|
Triphenylthioantimonate, 99%
| 28609-58-7 |
|
4-Methylthiazole, 99%
| 693-95-8 |
|
DL-2-Amino-1-Propanol, 98%
| 6168-72-5 |
|
2,5-Diphenyl-p-benzoquinone (pract), 93% (uv-vis)
| 844-51-9 |
|
4-Methylbenzyltriphenylphosphonium chloride, 99%
| 1530-37-6 |
|
L-(+)-Prolinol
| 23356-96-9 |
|
Prostaglandin VIII, 99%
| 0-01-1 |
|
Allyl alcohol
| 107-18-6 |
|
Phosphorus Tribromide, 99%
| 7789-60-8 |
|
5-Nitroisoquinoline, 98%
| 607-32-9 |
|
1,3-Acetonedicarboxylic acid, 96%
| 542-05-2 |
|
Pentacene, 98%
| 135-48-8 |
|
3,3'-Dimethoxybenzidine dihydrochloride, 99% (titr.)
| 20325-40-0 |
|
Diethyl Bis(hydroxymethyl)malonate, 95% (HPLC)
| 20605-01-0 |
|
P-Bromo-DL-Phenylalanine, 99%
| 14091-15-7 |
|
1,2-(Didodecyloxy)benzene, 98% (GC)
| 42244-53-1 |
|
p-Anisaldehyde, 99+%
| 123-11-5 |
|
Diazogen, 99%
| 80-11-5 |
|
2-Fluoro-4-Nitrotoluene, 98%
| 1427-07-2 |
|
Sodium triacetoxyborohydride
| 56553-60-7 |
|
Indole-2-carboxylic acid, 99%
| 1477-50-5 |
|
Pyridoxine Hydrochloride, 99% (Titr.)
| 58-56-0 |
|
2,6-Dichlorophenol
| 87-65-0 |
|
1,2-Butanediol, 98%
| 26171-83-5 |
|
2-(2-Aminoethoxy)ethanol, 98%
| 929-06-6 |
|
Poly(propylene Glycol), Average M.W. 425
| 25322-69-4 |
|
Valinomycin, 96% (HPLC)
| 2001-95-8 |
|
7-Amino-4-Methyl-1,8-Naphthyridin-2-ol, 98 %
| 1569-15-9 |
|
Benzyl butyrate, 98%
| 103-37-7 |
|
Lutetium oxide, 99.99%, -325 mesh
| 12032-20-1 |
|
P-Nitrophenyl Chloroformate, 96% (Titr.)
| 7693-46-1 |
|
Potassium sorbate, 99%
| 590-00-1 |
|
Phthalan, 97%
| 496-14-0 |
|
Cinnamyl Acetate, 99+%
| 103-54-8 |
|
Butyl Isocyanatoacetate, 98% (GC)
| 17046-22-9 |
|
Zirconyl(IV) chloride octahydrate, 98+%
| 7699-43-6 |
|
|