**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 56553-60-7 |Sodium triacetoxyborohydride | 97 | unlisted |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: F C
Risk Phrases: 14/15 34
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Reacts violently with water liberating extremely flammable gases.
Causes burns.Water-reactive.
Potential Health Effects
Eye:
Causes eye burns.
Skin:
Causes skin burns.
Ingestion:
Causes gastrointestinal tract burns.
Inhalation:
Causes chemical burns to the respiratory tract.
Chronic:
Chronic inhalation and ingestion may cause effects similar to those
of acute inhalation and ingestion.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately. Do NOT allow victim to rub eyes or keep eyes closed.
Extensive irrigation with water is required (at least 30 minutes).
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes. Wash clothing before reuse. Destroy contaminated shoes.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If breathing is difficult, give oxygen. Do NOT use
mouth-to-mouth resuscitation. If breathing has ceased apply
artificial respiration using oxygen and a suitable mechanical device
such as a bag and a mask.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Reacts with
water to form explosive hydrogen gas.
Extinguishing Media:
Do NOT use halogenated agents. Use approved class D extinguishing
agents or smother with dry sand, clay, or sodium bicarbonate. Do NOT
use water, carbon dioxide, or foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container. Clean up spills immediately, observing precautions in the
Protective Equipment section. Remove all sources of ignition.
Provide ventilation. Do not expose spill to water. Use only
non-sparking tools and equipment.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use with adequate ventilation. Minimize dust
generation and accumulation. Do not breathe dust, vapor, mist, or
gas. Do not get in eyes, on skin, or on clothing. Keep container
tightly closed. Keep away from heat, sparks and flame. Discard
contaminated shoes. Product evolves acetic acid when exposed to water
or humid air.
Storage:
Keep away from sources of ignition. Keep container closed when not
in use. Store in a tightly closed container. Water free area.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 56553-60-7:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Powder
Color: white
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 114 - 118 deg C(dec)
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: 114 - 118 deg C
Solubility in water: reacts
Specific Gravity/Density:
Molecular Formula: C6H10BNaO6
Molecular Weight: 211.94
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Water contact produces hydrogen gas.
Conditions to Avoid:
High temperatures, ignition sources, contact with water, excess heat.
Incompatibilities with Other Materials:
Water, strong oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide, oxides of boron, acetic acid,
hydrogen gas.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 56553-60-7 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Sodium triacetoxyborohydride -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: WATER-REACTIVE SOLID, CORROSIVE, N.O.S.*
Hazard Class: 4.3 (8)
UN Number: 3131
Packing Group: II
IMO
Shipping Name: WATER-REACTIVE SOLID, CORROSIVE, N.O.S.
Hazard Class: 4.3 (8)
UN Number: 3131
Packing Group: II
RID/ADR
Shipping Name: WATER-REACTIVE SOLID, CORROSIVE, N.O.S.
Hazard Class: 4.3 (8)
UN Number: 3131
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: F C
Risk Phrases:
R 14/15 Reacts violently with water liberating
extremely flammable gases.
R 34 Causes burns.
Safety Phrases:
S 7/8 Keep container tightly closed and dry.
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 56553-60-7: No information available.
Canada
CAS# 56553-60-7 is listed on Canada's NDSL List.
CAS# 56553-60-7 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 56553-60-7 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 2/03/1999 Revision #3 Date: 3/18/2005
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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4-Chlorobenzotrichloride, 99%
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| 1530-37-6 |
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L-(+)-Prolinol
| 23356-96-9 |
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Prostaglandin VIII, 99%
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Allyl alcohol
| 107-18-6 |
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Phosphorus Tribromide, 99%
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5-Nitroisoquinoline, 98%
| 607-32-9 |
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1,3-Acetonedicarboxylic acid, 96%
| 542-05-2 |
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Pentacene, 98%
| 135-48-8 |
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3,3'-Dimethoxybenzidine dihydrochloride, 99% (titr.)
| 20325-40-0 |
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Diethyl Bis(hydroxymethyl)malonate, 95% (HPLC)
| 20605-01-0 |
|
P-Bromo-DL-Phenylalanine, 99%
| 14091-15-7 |
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1,2-(Didodecyloxy)benzene, 98% (GC)
| 42244-53-1 |
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p-Anisaldehyde, 99+%
| 123-11-5 |
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Diazogen, 99%
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2-Fluoro-4-Nitrotoluene, 98%
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Sodium triacetoxyborohydride
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2,6-Dichlorophenol
| 87-65-0 |
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2-(2-Aminoethoxy)ethanol, 98%
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