**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
|----------------|--------------------------------------|----------|-----------|
|----------------|--------------------------------------|----------|-----------|
| 4165-57-5 |Bromobenzene-d5 | >99 | 224-013-8 |
+----------------+--------------------------------------+----------+-----------+
Text for R-phrases: see Section 16
Hazard Symbols: XI N
Risk Phrases: 10 38 51/53
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Flammable. Irritating to skin. Toxic to aquatic organisms, may cause
long-term adverse effects in the aquatic environment.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation. May be absorbed through the skin in harmful
amounts. If absorbed, may cause liver injury.
Ingestion:
Causes gastrointestinal irritation with nausea, vomiting and
diarrhea. May cause central nervous system depression.
Inhalation:
Inhalation of high concentrations may cause central nervous system
effects characterized by nausea, headache, dizziness, unconsciousness
and coma. Causes respiratory tract irritation. May cause narcotic
effects in high concentration. May cause liver abnormalities. Vapors
may cause dizziness or suffocation. May cause blood changes.
Chronic:
Chronic exposure may cause liver damage.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical
aid.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Use water spray to keep fire-exposed containers
cool. Flammable liquid and vapor. Vapors are heavier than air and may
travel to a source of ignition and flash back. Vapors can spread
along the ground and collect in low or confined areas.
Extinguishing Media:
For small fires, use dry chemical, carbon dioxide, water spray or
alcohol-resistant foam. For large fires, use water spray, fog, or
alcohol-resistant foam. Water may be ineffective. Do NOT use
straight streams of water.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Clean up spills immediately,
observing precautions in the Protective Equipment section. Remove all
sources of ignition. Use a spark-proof tool. Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use with adequate ventilation. Ground and bond
containers when transferring material. Use spark-proof tools and
explosion proof equipment. Avoid contact with eyes, skin, and
clothing. Empty containers retain product residue, (liquid and/or
vapor), and can be dangerous. Keep container tightly closed. Keep
away from heat, sparks and flame. Do not pressurize, cut, weld,
braze, solder, drill, grind, or expose empty containers to heat,
sparks or open flames. Avoid breathing vapor or mist.
Storage:
Keep away from sources of ignition. Store in a tightly closed
container. Store in a cool, dry, well-ventilated area away from
incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low. Ventilation fans
and other electrical service must be non-sparking and have an
explosion-proof design.
Exposure Limits
CAS# 108-86-1:
Russia: 3 mg/m3 TWA
CAS# 4165-57-5:
Personal Protective Equipment
Eyes:
Wear chemical splash goggles.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: clear, colorless
Odor: pleasant odor
pH: Not applicable.
Vapor Pressure: 4.18 mm Hg @ 25 deg C
Viscosity: Not available.
Boiling Point: 53 deg C @ 23 mmHg
Freezing/Melting Point: Not available.
Autoignition Temperature: Not applicable.
Flash Point: 51 deg C ( 123.80 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: Insoluble.
Specific Gravity/Density: 1.5500 g/cm3
Molecular Formula: C6BrD5
Molecular Weight: 162.06
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable.
Conditions to Avoid:
Ignition sources, excess heat, confined spaces.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide, hydrogen bromide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 108-86-1: CY9000000
CAS# 4165-57-5 unlisted.
LD50/LC50:
CAS# 108-86-1: Inhalation, mouse: LC50 = 21 gm/m3/2H; Inhalation,
rat: LC50 = 20411 mg/m3; Oral, mouse: LD50 = 2700 mg/kg; Oral,
rabbit: LD50 = 3300 mg/kg; Oral, rat: LD50 = 2383 mg/kg.
CAS# 4165-57-5.
Carcinogenicity:
Bromobenzene -
Not listed by ACGIH, IARC, or NTP.
Bromobenzene-d5 -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Ecotoxicity:
Bacteria: Phytobacterium phosphoreum: EC50 = 9.46 mg/L; 30 minutes;
Microtox test; 15 degrees C
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: BROMOBENZENE
Hazard Class: 3
UN Number: 2514
Packing Group: III
IMO
Shipping Name: BROMOBENZENE
Hazard Class: 3.3
UN Number: 2514
Packing Group: III
RID/ADR
Shipping Name: BROMOBENZENE
Hazard Class: 3
UN Number: 2514
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI N
Risk Phrases:
R 10 Flammable.
R 38 Irritating to skin.
R 51/53 Toxic to aquatic organisms, may cause
long-term adverse effects in the aquatic environment.
Safety Phrases:
S 61 Avoid release to the environment. Refer to
special instructions/safety data sheets.
WGK (Water Danger/Protection)
CAS# 108-86-1: 2
CAS# 4165-57-5: No information available.
Canada
CAS# 108-86-1 is listed on Canada's DSL List.
CAS# 108-86-1 is not listed on Canada's Ingredient Disclosure List.
CAS# 4165-57-5 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 108-86-1 is listed on the TSCA inventory.
CAS# 4165-57-5 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
Text for R-phrases from Section 2
MSDS Creation Date: 9/02/1997 Revision #8 Date: 5/06/2005
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
|
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| ALL MSDS PAGES IN THIS GROUP
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| 0-00-1 |
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Methyl Methacrylate-D8, 99.5 Atom % D, Stabilized with 100 ppm
| 0-00-1 |
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Methylcyclohexane-d14, 99.5 atom % D
| 108-87-2 |
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Ethylene Glycol-D6, 99 Atom % D
| 15054-86-1 |
|
Ethyl alcohol-d6, anhydrous, 99 Atom % D
| 64-17-5 |
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Methyl-d3 alcohol, 99.5 atom % D
| 67-56-1 |
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(S,S)-(+)-2,2-Dimethyl-5-Methylamino-4-Phenyl-1,3-Dioxane
| 0-00-1 |
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2,2-Dimethyl-1,3-Dioxan-5-One
| 74181-34-3 |
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1,2,2,6,6-Pentamethyl-4-Piperidinol
| 2403-89-6 |
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2,2'-Dithio(bis)benzothiazole
| 120-78-5 |
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Cyclopentadienylmolybdenum Tricarbonyl Sodium
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| 24356-01-2 |
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2-Methylcyclohexanol, P.A.; Mixture of Cis and Trans
| 583-59-5 |
|
1,2-Bis(dicyclohexylphosphino)ethane nickel(II) chloride
| 96555-88-3 |
|
1-Octene, 99+%
| 111-66-0 |
|
Lauric Acid, 99.8+% (GC)
| 143-07-7 |
|
Ethylenediaminetetraacetic Acid, Tripotassium Salt Dihydrate (Pract),
| 7732-18-5 |
|
alpha-Terpineol, 99%
| 98-55-5 |
|
Calcium bromide hydrate
| 7789-41-5 |
|
3-Hydroxy-N-Methylpiperidine, 97%
| 3554-74-3 |
|
2-Hydroxymethyl-12-Crown-4, Tech., 93% (gGC)
| 75507-26-5 |
|
Methyl(2E,4S)-(-)-4-(phenylmethoxy)pent-2-enoate
| 112489-57-3 |
|
Ethyl Isocyanoacetate, 97% (GC)
| 2999-46-4 |
|
N-Iodosuccinimide
| 516-12-1 |
|
3,5-Dichlorobenzotrifluoride
| 0-00-1 |
|
DL-Methionine, Feed Grade
| 59-51-8 |
|
2-Vinyl-1,3-dioxolane
| 3984-22-3 |
|
N-Glycine, E.P. Pyrogene Free
| 56-40-6 |
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D(-)-glutamine
| 5959-95-5 |
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4,5-Dihydroxynaphthalene-2,7-Disulfonic Acid, Disodium Salt
| 5808-22-0 |
|
Albumine Bovine, Fraction V (pH:7.0)
| 94349-60-7 |
|
n-Methyl-2,2,6,6-tetramethyl-4-piperidinol 99%
| 50-01-4 |
|
Ethyl cis-2-amino-1-cyclopentane carboxylate hydrochloride, 99%
| 142547-15-7 |
|
cis-2-(Benzyloxycarbonylamino)-1- cyclopentanecarboxylic acid
| |
|
3',4'-(Didodecyloxy)benzaldehyde, 99% (GC)
| 117241-25-5 |
|
2-Amino-1,2,3,4-Tetrahydronaphthalene-2- Carboxylic Acid
| 0-00-0 |
|
2,2',4'-Trichloroacetophenone, 99% (gc)
| 4252-78-2 |
|
3-Aminophenol, 99%
| 591-27-5 |
|
Alpha-Naphtholbenzein
| 6948-88-5 |
|
cis-2-Aminomethylcycloheptanol hydrochloride
| 0-00-0 |
|
n-(Tributyl)tinpyrrole
| 50486-65-2 |
|
2-Benzoyl-1-cyano-6,7-dimethoxy-1,2,3,4- tetrahydroisoquinoline
| |
|
Aluminum, Powder, -120 Mesh, 99,99%
| 7429-90-5 |
|
3-Amino-4-methylpentanoic acid
| 2458-12-0 |
|
3-Hydroxy-2,2-dimethyl-3-phenylpropionic- acid
| 0-00-0 |
|
(4S,2RS)-2,5,5-Trimethylthiazolidine-4- Carboxylic Acid
| 0-00-0 |
|
Bromobenzene-d5
| 108-86-1 |
|
3-Amino-1-phenoxy-2-propanol hydrochloride, 98%
| 4287-20-1 |
|
Tetrathiafulvalene, 99+%
| 31366-25-3 |
|
|