**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 50486-65-2 |n-(Tributyl)tinpyrrole | | unlisted |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: T N
Risk Phrases: 21 25 36/38 48/23/25 50/53
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful in contact with skin. Toxic if swallowed. Irritating to eyes
and skin. Toxic : danger of serious damage to health by prolonged
exposure through inhalation and if swallowed. Very toxic to aquatic
organisms, may cause long-term adverse effects in the aquatic
environment.The toxicological properties of this material have not
been fully investigated.Toxic.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation. Harmful if absorbed through the skin.
Ingestion:
Poison by ingestion. The toxicological properties of this substance
have not been fully investigated.
Inhalation:
The toxicological properties of this substance have not been fully
investigated. Toxic if inhaled.
Chronic:
Chronic inhalation and ingestion may cause effects similar to those
of acute inhalation and ingestion.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes.
Ingestion:
Get medical aid immediately. Wash mouth out with water.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on
skin, or on clothing. Use only in a chemical fume hood.
Storage:
Store in a cool, dry place. Store in a tightly closed container.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 50486-65-2:
United Kingdom, WEL - TWA: (listed as tin organic compounds): 0.1
mg/m3 TWA (except cyhexatin, as Sn)
United Kingdom, WEL - STEL: (listed as tin organic compounds): 0.
mg/m3 STEL (except cyhexatin, as Sn)
United States OSHA: 0.1 mg/m3 TWA (as Sn) (listed under Tin orga
compounds).
Belgium - TWA: (listed as tin organic compounds): 0.1 mg/m3 VLE (
Sn)
Belgium - STEL: (listed as tin organic compounds): 0.2 mg/m3 VLE
Sn)
France - VME: (listed as tin organic compounds): 0.1 mg/m3 VME (a
Sn)
France - VLE: (listed as tin organic compounds): 0.2 mg/m3 VLE (a
Sn)
Germany: (listed as tin organic compounds): 0.1 mg/m3 VME (as Sn)
Germany: (listed as tin organic compounds): Skin absorber
Malaysia: (listed as tin organic compounds): 0.1 mg/m3 TWA (as Sn
Netherlands: (listed as tin organic compounds): 0.2 mg/m3 STEL (a
Sn)
Netherlands: (listed as tin organic compounds): 0.1 mg/m3 MAC (as
Spain: (listed as tin organic compounds): 0.1 mg/m3 VLA-ED (as Sn
Spain: (listed as tin organic compounds): 0.2 mg/m3 VLA-EC (as Sn
Personal Protective Equipment
Eyes:
Not available.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Solid
Color: Not available.
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula:
Molecular Weight: 355.91
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Not available.
Conditions to Avoid:
Incompatible materials.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide, tin/tin oxides.
Hazardous Polymerization: Has not been reported
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 50486-65-2 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
n-(Tributyl)tinpyrrole -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: ORGANOTIN COMPOUND, SOLID, N.O.S.
Hazard Class: 6.1
UN Number: 3146
Packing Group: III
IMO
Shipping Name: ORGANOTIN COMPOUND, SOLID, N.O.S.
Hazard Class: 6.1
UN Number: 3146
Packing Group: III
RID/ADR
Shipping Name: ORGANOTIN COMPOUND, SOLID, N.O.S.
Hazard Class: 6.1
UN Number: 3146
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T N
Risk Phrases:
R 21 Harmful in contact with skin.
R 25 Toxic if swallowed.
R 36/38 Irritating to eyes and skin.
R 48/23/25 Toxic : danger of serious damage to
health by prolonged exposure through inhalation and if
swallowed.
R 50/53 Very toxic to aquatic organisms, may cause
long-term adverse effects in the aquatic environment.
Safety Phrases:
S 35 This material and its container must be
disposed of in a safe way.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
S 60 This material and its container must be
disposed of as hazardous waste.
S 61 Avoid release to the environment. Refer to
special instructions/safety data sheets.
WGK (Water Danger/Protection)
CAS# 50486-65-2: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 50486-65-2 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 50486-65-2 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 4/05/1997 Revision #2 Date: 9/20/2004
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Cumene-d12, 99 atom % D
| 0-00-1 |
|
Methyl Methacrylate-D8, 99.5 Atom % D, Stabilized with 100 ppm
| 0-00-1 |
|
Methylcyclohexane-d14, 99.5 atom % D
| 108-87-2 |
|
Ethylene Glycol-D6, 99 Atom % D
| 15054-86-1 |
|
Ethyl alcohol-d6, anhydrous, 99 Atom % D
| 64-17-5 |
|
Methyl-d3 alcohol, 99.5 atom % D
| 67-56-1 |
|
(S,S)-(+)-2,2-Dimethyl-5-Methylamino-4-Phenyl-1,3-Dioxane
| 0-00-1 |
|
2,2-Dimethyl-1,3-Dioxan-5-One
| 74181-34-3 |
|
1,2,2,6,6-Pentamethyl-4-Piperidinol
| 2403-89-6 |
|
2,2'-Dithio(bis)benzothiazole
| 120-78-5 |
|
Acridine Orange, ca. 55%
| 10127-02-3 |
|
Cyclopentadienylmolybdenum Tricarbonyl Sodium
| 12107-35-6 |
|
Tetrabenzylzirconium
| 24356-01-2 |
|
2-Methylcyclohexanol, P.A.; Mixture of Cis and Trans
| 583-59-5 |
|
1,2-Bis(dicyclohexylphosphino)ethane nickel(II) chloride
| 96555-88-3 |
|
1-Octene, 99+%
| 111-66-0 |
|
Lauric Acid, 99.8+% (GC)
| 143-07-7 |
|
Ethylenediaminetetraacetic Acid, Tripotassium Salt Dihydrate (Pract),
| 7732-18-5 |
|
alpha-Terpineol, 99%
| 98-55-5 |
|
Calcium bromide hydrate
| 7789-41-5 |
|
3-Hydroxy-N-Methylpiperidine, 97%
| 3554-74-3 |
|
2-Hydroxymethyl-12-Crown-4, Tech., 93% (gGC)
| 75507-26-5 |
|
Methyl(2E,4S)-(-)-4-(phenylmethoxy)pent-2-enoate
| 112489-57-3 |
|
Ethyl Isocyanoacetate, 97% (GC)
| 2999-46-4 |
|
N-Iodosuccinimide
| 516-12-1 |
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3,5-Dichlorobenzotrifluoride
| 0-00-1 |
|
DL-Methionine, Feed Grade
| 59-51-8 |
|
2-Vinyl-1,3-dioxolane
| 3984-22-3 |
|
N-Glycine, E.P. Pyrogene Free
| 56-40-6 |
|
D(-)-glutamine
| 5959-95-5 |
|
4,5-Dihydroxynaphthalene-2,7-Disulfonic Acid, Disodium Salt
| 5808-22-0 |
|
Albumine Bovine, Fraction V (pH:7.0)
| 94349-60-7 |
|
n-Methyl-2,2,6,6-tetramethyl-4-piperidinol 99%
| 50-01-4 |
|
Ethyl cis-2-amino-1-cyclopentane carboxylate hydrochloride, 99%
| 142547-15-7 |
|
cis-2-(Benzyloxycarbonylamino)-1- cyclopentanecarboxylic acid
| |
|
3',4'-(Didodecyloxy)benzaldehyde, 99% (GC)
| 117241-25-5 |
|
2-Amino-1,2,3,4-Tetrahydronaphthalene-2- Carboxylic Acid
| 0-00-0 |
|
2,2',4'-Trichloroacetophenone, 99% (gc)
| 4252-78-2 |
|
3-Aminophenol, 99%
| 591-27-5 |
|
Alpha-Naphtholbenzein
| 6948-88-5 |
|
cis-2-Aminomethylcycloheptanol hydrochloride
| 0-00-0 |
|
n-(Tributyl)tinpyrrole
| 50486-65-2 |
|
2-Benzoyl-1-cyano-6,7-dimethoxy-1,2,3,4- tetrahydroisoquinoline
| |
|
Aluminum, Powder, -120 Mesh, 99,99%
| 7429-90-5 |
|
3-Amino-4-methylpentanoic acid
| 2458-12-0 |
|
3-Hydroxy-2,2-dimethyl-3-phenylpropionic- acid
| 0-00-0 |
|
(4S,2RS)-2,5,5-Trimethylthiazolidine-4- Carboxylic Acid
| 0-00-0 |
|
Bromobenzene-d5
| 108-86-1 |
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3-Amino-1-phenoxy-2-propanol hydrochloride, 98%
| 4287-20-1 |
|
Tetrathiafulvalene, 99+%
| 31366-25-3 |
|
|