**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 591-27-5 |3-Aminophenol | 99.0 | 209-711-2 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN N
Risk Phrases: 20/22 51/53
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful by inhalation and if swallowed. Toxic to aquatic organisms,
may cause long-term adverse effects in the aquatic environment.The
toxicological properties of this material have not been fully
investigated.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation.
Ingestion:
May cause irritation of the digestive tract. Causes gastrointestinal
irritation with nausea, vomiting and diarrhea. The toxicological
properties of this substance have not been fully investigated.
Inhalation:
May cause respiratory tract irritation. The toxicological properties
of this substance have not been fully investigated.
Chronic:
May cause reproductive and fetal effects.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid immediately. Flush skin with plenty of water for at
least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion.
Extinguishing Media:
In case of fire, use water, dry chemical, chemical foam, or
alcohol-resistant foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Clean up spills immediately, observing precautions in the Protective
Equipment section. Sweep up, then place into a suitable container for
disposal.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use with adequate ventilation. Avoid contact with
eyes, skin, and clothing. Avoid ingestion and inhalation.
Storage:
Store in a cool, dry place. Keep container closed when not in use.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use process enclosure, local exhaust ventilation, or other
engineering controls to control airborne levels.
Exposure Limits
CAS# 591-27-5:
Russia: 1 mg/m3 TWA
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves and clothing to
prevent skin exposure.
Clothing:
Wear appropriate protective clothing to minimize
contact with skin.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Solid
Color: green
Odor: None reported.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 164 deg C @ 11.00mm Hg
Freezing/Melting Point: 121 - 124 deg C
Autoignition Temperature: Not available.
Flash Point: 155 deg C ( 311.00 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: 3.5 g/100g (20 c)
Specific Gravity/Density:
Molecular Formula: C6H7NO
Molecular Weight: 109.13
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
None reported.
Incompatibilities with Other Materials:
Acids, acid chlorides, acid anhydrides, chloroformates, strong
oxidizing agents.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, irritating and toxic fumes and
gases, carbon dioxide, nitrogen.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 591-27-5: SJ4900000
LD50/LC50:
CAS# 591-27-5: Draize test, rabbit, eye: 100 mg/24H Moderate; Draize
test, rabbit, skin: 12500 ug/24H Mild; Inhalation, rat: LC50 = 1162
mg/m3; Oral, mouse: LD50 = 401 mg/kg; Oral, rat: LD50 = 924 mg/kg.
Carcinogenicity:
3-Aminophenol -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: AMINOPHENOLS
Hazard Class: 6.1
UN Number: 2512
Packing Group: III
IMO
Shipping Name: AMINOPHENOLS
Hazard Class: 6.1
UN Number: 2512
Packing Group: III
RID/ADR
Shipping Name: AMINOPHENOLS
Hazard Class: 6.1
UN Number: 2512
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN N
Risk Phrases:
R 20/22 Harmful by inhalation and if swallowed.
R 51/53 Toxic to aquatic organisms, may cause
long-term adverse effects in the aquatic environment.
Safety Phrases:
S 28A After contact with skin, wash immediately with
plenty of water.
S 61 Avoid release to the environment. Refer to
special instructions/safety data sheets.
WGK (Water Danger/Protection)
CAS# 591-27-5: 1
Canada
CAS# 591-27-5 is listed on Canada's DSL List.
CAS# 591-27-5 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 591-27-5 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/02/1997 Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
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| 0-00-1 |
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Methyl Methacrylate-D8, 99.5 Atom % D, Stabilized with 100 ppm
| 0-00-1 |
|
Methylcyclohexane-d14, 99.5 atom % D
| 108-87-2 |
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Ethylene Glycol-D6, 99 Atom % D
| 15054-86-1 |
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Ethyl alcohol-d6, anhydrous, 99 Atom % D
| 64-17-5 |
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Methyl-d3 alcohol, 99.5 atom % D
| 67-56-1 |
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(S,S)-(+)-2,2-Dimethyl-5-Methylamino-4-Phenyl-1,3-Dioxane
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2,2-Dimethyl-1,3-Dioxan-5-One
| 74181-34-3 |
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1,2,2,6,6-Pentamethyl-4-Piperidinol
| 2403-89-6 |
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2,2'-Dithio(bis)benzothiazole
| 120-78-5 |
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Acridine Orange, ca. 55%
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Cyclopentadienylmolybdenum Tricarbonyl Sodium
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Tetrabenzylzirconium
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2-Methylcyclohexanol, P.A.; Mixture of Cis and Trans
| 583-59-5 |
|
1,2-Bis(dicyclohexylphosphino)ethane nickel(II) chloride
| 96555-88-3 |
|
1-Octene, 99+%
| 111-66-0 |
|
Lauric Acid, 99.8+% (GC)
| 143-07-7 |
|
Ethylenediaminetetraacetic Acid, Tripotassium Salt Dihydrate (Pract),
| 7732-18-5 |
|
alpha-Terpineol, 99%
| 98-55-5 |
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Calcium bromide hydrate
| 7789-41-5 |
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3-Hydroxy-N-Methylpiperidine, 97%
| 3554-74-3 |
|
2-Hydroxymethyl-12-Crown-4, Tech., 93% (gGC)
| 75507-26-5 |
|
Methyl(2E,4S)-(-)-4-(phenylmethoxy)pent-2-enoate
| 112489-57-3 |
|
Ethyl Isocyanoacetate, 97% (GC)
| 2999-46-4 |
|
N-Iodosuccinimide
| 516-12-1 |
|
3,5-Dichlorobenzotrifluoride
| 0-00-1 |
|
DL-Methionine, Feed Grade
| 59-51-8 |
|
2-Vinyl-1,3-dioxolane
| 3984-22-3 |
|
N-Glycine, E.P. Pyrogene Free
| 56-40-6 |
|
D(-)-glutamine
| 5959-95-5 |
|
4,5-Dihydroxynaphthalene-2,7-Disulfonic Acid, Disodium Salt
| 5808-22-0 |
|
Albumine Bovine, Fraction V (pH:7.0)
| 94349-60-7 |
|
n-Methyl-2,2,6,6-tetramethyl-4-piperidinol 99%
| 50-01-4 |
|
Ethyl cis-2-amino-1-cyclopentane carboxylate hydrochloride, 99%
| 142547-15-7 |
|
cis-2-(Benzyloxycarbonylamino)-1- cyclopentanecarboxylic acid
| |
|
3',4'-(Didodecyloxy)benzaldehyde, 99% (GC)
| 117241-25-5 |
|
2-Amino-1,2,3,4-Tetrahydronaphthalene-2- Carboxylic Acid
| 0-00-0 |
|
2,2',4'-Trichloroacetophenone, 99% (gc)
| 4252-78-2 |
|
3-Aminophenol, 99%
| 591-27-5 |
|
Alpha-Naphtholbenzein
| 6948-88-5 |
|
cis-2-Aminomethylcycloheptanol hydrochloride
| 0-00-0 |
|
n-(Tributyl)tinpyrrole
| 50486-65-2 |
|
2-Benzoyl-1-cyano-6,7-dimethoxy-1,2,3,4- tetrahydroisoquinoline
| |
|
Aluminum, Powder, -120 Mesh, 99,99%
| 7429-90-5 |
|
3-Amino-4-methylpentanoic acid
| 2458-12-0 |
|
3-Hydroxy-2,2-dimethyl-3-phenylpropionic- acid
| 0-00-0 |
|
(4S,2RS)-2,5,5-Trimethylthiazolidine-4- Carboxylic Acid
| 0-00-0 |
|
Bromobenzene-d5
| 108-86-1 |
|
3-Amino-1-phenoxy-2-propanol hydrochloride, 98%
| 4287-20-1 |
|
Tetrathiafulvalene, 99+%
| 31366-25-3 |
|
|