**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 2999-46-4 |Ethyl Isocyanoacetate | 97 | 221-077-9 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN
Risk Phrases: 20/21/22
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful by inhalation, in contact with skin and if swallowed.Light
sensitive.Moisture sensitive.Lachrymator (substance which increases
the flow of tears).
Potential Health Effects
Eye:
Causes eye irritation. Lachrymator (substance which increases the
flow of tears). May cause chemical conjunctivitis and corneal
damage.
Skin:
Causes skin irritation. Organic isocyanates can cause local
irritation and allergic reactions. May cause irritation and
dermatitis. May cause cyanosis of the extremities.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea. The toxicological properties of this substance have not
been fully investigated.
Inhalation:
Causes respiratory tract irritation. The toxicological properties of
this substance have not been fully investigated. At high
concentrations, isocyanates affect mucous membranes of the
respiratory tract and may lead to fatal pulmonary edema. Exposure to
low and often even unmeasurable isocyanate concentration results in
sensitization. Can produce delayed pulmonary edema. Inhalation at
high concentrations may cause CNS depression and asphixiation.
Chronic:
Effects may be delayed. Chronic overexposure to isocyanates has been
reported to cause lung damage, including decreased lung fuction,
which may be permanent.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid. Do
NOT allow victim to rub eyes or keep eyes closed.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and
drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid. Do NOT use mouth-to-mouth
resuscitation. If breathing has ceased apply artificial respiration
using oxygen and a suitable mechanical device such as a bag and a
mask.
Notes to Physician:
Treat symptomatically and supportively.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Use water
spray to keep fire-exposed containers cool. Combustible liquid.
Vapors may be heavier than air. They can spread along the ground and
collect in low or confined areas. Containers may explode when heated.
Extinguishing Media:
In case of fire, use water, dry chemical, chemical foam, or
alcohol-resistant foam. Use water spray to cool fire-exposed
containers. Do NOT get water inside containers.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Avoid runoff into storm sewers and
ditches which lead to waterways. Clean up spills immediately,
observing precautions in the Protective Equipment section. Remove all
sources of ignition. Use a spark-proof tool. Provide ventilation. Do
not get water inside containers.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Use only in a well-ventilated area.
Avoid contact with eyes, skin, and clothing. Empty containers retain
product residue, (liquid and/or vapor), and can be dangerous. Keep
container tightly closed. Keep away from heat, sparks and flame.
Avoid ingestion and inhalation. Use with adequate ventilation. Store
protected from light. Do not allow contact with water. Do not
pressurize, cut, weld, braze, solder, drill, grind, or expose empty
containers to heat, sparks or open flames. Keep from contact with
moist air and steam.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of
ignition. Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances. Keep
refrigerated. (Store below 4C/39F.) Store protected from moisture.
Store protected from light.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 2999-46-4:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: colorless
Odor: bitter
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 194 - 196 deg C @ 760.00mm Hg
Freezing/Melting Point: Not available.
Autoignition Temperature: Not applicable.
Flash Point: 84 deg C ( 183.20 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: Negligible.
Specific Gravity/Density: 1.0350g/cm3
Molecular Formula: C5H7NO2
Molecular Weight: 113.12
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable at room temperature in closed containers under normal storage
and handling conditions.
Conditions to Avoid:
Incompatible materials, light, ignition sources, moisture, excess
heat.
Incompatibilities with Other Materials:
Moisture, strong oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, oxides of nitrogen, irritating and toxic fumes and
gases, carbon dioxide.
Hazardous Polymerization: Has not been reported
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 2999-46-4 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Ethyl Isocyanoacetate -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: TOXIC LIQUID, ORGANIC, N.O.S.*
Hazard Class: 6.1
UN Number: 2810
Packing Group: III
IMO
Shipping Name: TOXIC LIQUID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2810
Packing Group: III
RID/ADR
Shipping Name: TOXIC LIQUID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2810
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 20/21/22 Harmful by inhalation, in contact with
skin and if swallowed.
Safety Phrases:
S 28A After contact with skin, wash immediately with
plenty of water.
S 36/37 Wear suitable protective clothing and
gloves.
S 37 Wear suitable gloves.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 2999-46-4: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 2999-46-4 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 2999-46-4 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 4/05/1997 Revision #9 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
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| ALL MSDS PAGES IN THIS GROUP
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Methyl Methacrylate-D8, 99.5 Atom % D, Stabilized with 100 ppm
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Methylcyclohexane-d14, 99.5 atom % D
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Ethylene Glycol-D6, 99 Atom % D
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Ethyl alcohol-d6, anhydrous, 99 Atom % D
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Methyl-d3 alcohol, 99.5 atom % D
| 67-56-1 |
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(S,S)-(+)-2,2-Dimethyl-5-Methylamino-4-Phenyl-1,3-Dioxane
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2,2-Dimethyl-1,3-Dioxan-5-One
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1,2,2,6,6-Pentamethyl-4-Piperidinol
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2,2'-Dithio(bis)benzothiazole
| 120-78-5 |
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|
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| 96555-88-3 |
|
1-Octene, 99+%
| 111-66-0 |
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Lauric Acid, 99.8+% (GC)
| 143-07-7 |
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Ethylenediaminetetraacetic Acid, Tripotassium Salt Dihydrate (Pract),
| 7732-18-5 |
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alpha-Terpineol, 99%
| 98-55-5 |
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Calcium bromide hydrate
| 7789-41-5 |
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3-Hydroxy-N-Methylpiperidine, 97%
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3,5-Dichlorobenzotrifluoride
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DL-Methionine, Feed Grade
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2-Vinyl-1,3-dioxolane
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Albumine Bovine, Fraction V (pH:7.0)
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n-Methyl-2,2,6,6-tetramethyl-4-piperidinol 99%
| 50-01-4 |
|
Ethyl cis-2-amino-1-cyclopentane carboxylate hydrochloride, 99%
| 142547-15-7 |
|
cis-2-(Benzyloxycarbonylamino)-1- cyclopentanecarboxylic acid
| |
|
3',4'-(Didodecyloxy)benzaldehyde, 99% (GC)
| 117241-25-5 |
|
2-Amino-1,2,3,4-Tetrahydronaphthalene-2- Carboxylic Acid
| 0-00-0 |
|
2,2',4'-Trichloroacetophenone, 99% (gc)
| 4252-78-2 |
|
3-Aminophenol, 99%
| 591-27-5 |
|
Alpha-Naphtholbenzein
| 6948-88-5 |
|
cis-2-Aminomethylcycloheptanol hydrochloride
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| 50486-65-2 |
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2-Benzoyl-1-cyano-6,7-dimethoxy-1,2,3,4- tetrahydroisoquinoline
| |
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Aluminum, Powder, -120 Mesh, 99,99%
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| 0-00-0 |
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| 0-00-0 |
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Bromobenzene-d5
| 108-86-1 |
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Tetrathiafulvalene, 99+%
| 31366-25-3 |
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