**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 112-21-0 |N,N'-Diethyl-2-Butene-1,4-Diamine | 97% | 203-946-4 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: None Listed.
Risk Phrases: None Listed.
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
The toxicological properties of this material have not been fully
investigated.
Potential Health Effects
Eye:
May cause eye irritation. May cause chemical conjunctivitis and
corneal damage.
Skin:
May cause irritation and dermatitis. May cause cyanosis of the
extremities.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea. May cause methemoglobinemia, cyanosis (bluish
discoloration of skin due to deficient oxygenation of the blood),
convulsions, and death. The toxicological properties of this
substance have not been fully investigated. May cause central nervous
system depression.
Inhalation:
May cause respiratory tract irritation. May cause methemoglobinemia,
cyanosis (bluish discoloration of skin due to deficient oxygenation
of the blood), convulsions, tachycardia, dyspnea (labored breathing),
and death. The toxicological properties of this substance have not
been fully investigated. Aspiration may lead to pulmonary edema.
Inhalation at high concentrations may cause CNS depression and
asphixiation.
Chronic:
May cause methemoglobinemia, which is characterized by
chocolate-brown colored blood, headache, weakness, dizziness, breath
shortness, cyanosis (bluish skin due to deficient oxygenation of
blood), rapid heart rate, unconsciousness and possible death. Effects
may be delayed.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and
drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If breathing
is difficult, give oxygen. Get medical aid. Do NOT use mouth-to-mouth
resuscitation. If breathing has ceased apply artificial respiration
using oxygen and a suitable mechanical device such as a bag and a
mask.
Notes to Physician:
For methemoglobinemia, administer oxygen alone or with Methylene
Blue depending on the methemoglobin concentration in the blood.
Antidote:
Methylene blue, alone or in combination with oxygen is indicated as
a treatment in nitrite induced methemoglobinemia.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Use water
spray to keep fire-exposed containers cool. Combustible liquid.
Vapors may be heavier than air. They can spread along the ground and
collect in low or confined areas. Containers may explode when heated.
Runoff from fire control or dilution water may cause pollution.
Extinguishing Media:
In case of fire, use water, dry chemical, chemical foam, or
alcohol-resistant foam. Use water spray to cool fire-exposed
containers. Use agent most appropriate to extinguish fire.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Avoid runoff into storm sewers and
ditches which lead to waterways. Clean up spills immediately,
observing precautions in the Protective Equipment section. Remove all
sources of ignition. Use a spark-proof tool. Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use only in a well-ventilated area. Avoid contact
with eyes, skin, and clothing. Empty containers retain product
residue, (liquid and/or vapor), and can be dangerous. Keep container
tightly closed. Keep away from heat, sparks and flame. Avoid
ingestion and inhalation. Do not pressurize, cut, weld, braze,
solder, drill, grind, or expose empty containers to heat, sparks or
open flames.
Storage:
Keep away from sources of ignition. Keep container closed when not
in use. Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 112-21-0:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to minimize
contact with skin.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: clear yellow
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 80.0 - 83.0 deg C @ 8.00mm Hg
Freezing/Melting Point: Not available.
Autoignition Temperature: Not applicable.
Flash Point: 73 deg C ( 163.40 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density: .8410g/cm3
Molecular Formula: C8H18N2
Molecular Weight: 142.24
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, ignition sources, excess heat, strong
oxidants.
Incompatibilities with Other Materials:
Acid anhydrides, acid chlorides, acids, carbon dioxide, oxidizing
agents.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, irritating and toxic fumes and
gases, carbon dioxide, nitrogen.
Hazardous Polymerization: Has not been reported
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 112-21-0 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
N,N'-Diethyl-2-Butene-1,4-Diamine -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 112-21-0: No information available.
Canada
CAS# 112-21-0 is listed on Canada's NDSL List.
CAS# 112-21-0 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 112-21-0 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/02/1997 Revision #5 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Neodymium chloride hexahydrate, 99.99%
| 13477-89-9 |
|
4-Methylbenzophenone, 97%
| 134-84-9 |
|
4-Biphenylcarbonyl chloride, 98%
| 14002-51-8 |
|
1,4-Dicyanobenzene, 98%
| 623-26-7 |
|
2-Iodophenol
| 533-58-4 |
|
d-alpha-Tocopheryl acid succinate, 99+% (gc)
| 4345-03-3 |
|
2-Cyclopentylidenecyclopentanone, 97%
| 825-25-2 |
|
1,4-Dichloro-2-Iodobenzene, 98%
| 29682-41-5 |
|
6-P-Toluidine-2-Naphthalenesulfonic Acid, 99% (Titr.)
| 7724-15-4 |
|
N,N'-Diethyl-2-Butene-1,4-Diamine, 97%
| 112-21-0 |
|
1-Amino-5,6,7,8-tetrahydronaphthalene, tech., 90%
| 2217-41-6 |
|
N-Ethylbenzylamine, 97%
| 14321-27-8 |
|
Allyl phenoxyacetate, 98+%
| 7493-74-5 |
|
3-Nitrostyrene, 97%
| 586-39-0 |
|
Ruthenium on alumina powder (5% ru)
| |
|
Nipecotamide, 95%
| 4138-26-5 |
|
8-Hydroxy-7-(6-Sulfo-2-Naphthylazo)-5-Quinolinesulfonic Acid Disodium
| 56932-43-5 |
|
Molybdocene Dichloride
| 12184-22-4 |
|
1,2,3,5-Tetramethylbenzene, Tech., 85+%
| 527-53-7 |
|
Androsterone, 97%
| 53-41-8 |
|
1,3-Dimethyl-5-aminoadamantane hydrochloride
| 19982-08-2 |
|
4-Methoxyphenylhydrazine hydrochloride 98%
| 19501-58-7 |
|
2,4,6-Trichloropyrimidine, 99%
| 3764-01-0 |
|
1-Bromo-3-phenylpropane, 98%
| 637-59-2 |
|
Aluminum Tert-Butoxide, 98% (Grav.)
| 556-91-2 |
|
4-Aminothiophenol,96%
| 1193-02-8 |
|
1,2-Dimethyl-3-Hydroxy-4-Pyridone, 99+%
| 30652-11-0 |
|
1,1,1-Tris-(Hydroxymethyl)-Ethane, 97%
| 77-85-0 |
|
4-Benzoylpyridine, 98%
| 14548-46-0 |
|
tert-Butylchlorodiphenylsilane, 98%
| 58479-61-1 |
|
4,4'-Azodianiline, 95% (Titr.)
| 538-41-0 |
|
2-Methyl-5-nitroaniline, 99%
| 99-55-8 |
|
(s)-(-)-1-Benzylglycerol, 98%
| 17325-85-8 |
|
Maleimide, 98%
| 541-59-3 |
|
2-Chlorobenzoxazole, 99% (GC)
| 615-18-9 |
|
Methyl Thiocyanate, 99%
| 556-64-9 |
|
Alpha, 4-Dichloroanisole, 97%
| 21151-56-4 |
|
Lanthanum hexaboride, 99%
| 12008-21-8 |
|
Dl-methyl mandelate, 97%
| 4358-87-6 |
|
(5-z)-9-deoxy-6,9alpha-epoxy-PGF1alpha, sodium salt, 98%, stab. with
| 61849-14-7 |
|
(-)-2-Cyano-6-Phenyloxazolopiperidine, 99+%
| 88056-92-2 |
|
3,4-Dichloroaniline, 98%
| 95-76-1 |
|
Indole, 99+%
| 120-72-9 |
|
3-Methylbenzophenone, 99%
| 643-65-2 |
|
3-Hydroxy-6-Methyl-2-Nitropyridine, 99%
| 15128-90-2 |
|
1,1,3,3-Tetramethyl-2-thiourea, 98%
| 2782-91-4 |
|
1,2-Bis(2-aminophenoxy)-ethane-N,N,N', N'-tetraacetic acid
| 126824-24-6 |
|
6-Amino-5-nitroso-2-thiouracil, 99%
| 1672-48-6 |
|
N,N-Diethylaniline, 99%
| 91-66-7 |
|
Tetraethylammonium tetrafluoroborate, 99%
| 429-06-1 |
|
|