**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
|----------------|--------------------------------------|----------|-----------|
| 95-76-1 |3,4-Dichloroaniline | 98 | 202-448-4 |
|----------------|--------------------------------------|----------|-----------|
+----------------+--------------------------------------+----------+-----------+
Text for R-phrases: see Section 16
Hazard Symbols: T N
Risk Phrases: 23/24/25 33 50/53
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Toxic by inhalation, in contact with skin and if swallowed. Danger
of cumulative effects. Very toxic to aquatic organisms, may cause
long-term adverse effects in the aquatic environment.
Potential Health Effects
Eye:
Causes severe eye irritation and possible burns.
Skin:
May be harmful if absorbed through the skin. Causes severe skin
irritation and possible burns.
Ingestion:
May cause irritation of the digestive tract. May be harmful if
swallowed.
Inhalation:
Causes respiratory tract irritation.
Chronic:
No information found.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes. Wash clothing before reuse.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid immediately.
Inhalation:
Remove from exposure and move to fresh air immediately. If breathing
is difficult, give oxygen. Get medical aid. If breathing has ceased
apply artificial respiration using oxygen and a suitable mechanical
device such as a bag and a mask.
Notes to Physician:
Treat symptomatically and supportively.
Antidote:
Methylene blue, alone or in combination with oxygen is indicated as
a treatment in nitrite induced methemoglobinemia.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Use water spray to keep fire-exposed containers
cool. Approach fire from upwind to avoid hazardous vapors and toxic
decomposition products.
Extinguishing Media:
Water or foam may cause frothing. Use water spray, dry chemical,
carbon dioxide, or appropriate foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container. Avoid runoff into storm sewers and ditches which lead to
waterways. Clean up spills immediately, observing precautions in the
Protective Equipment section. Avoid generating dusty conditions.
Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use with adequate ventilation. Avoid contact with
eyes, skin, and clothing. Avoid breathing dust.
Storage:
Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances. Poison room
locked. Isolate from oxidizing materials and acids.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 95-76-1:
Russia: 0.5 mg/m3 TWA
CAS# 27134-27-6:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Crystals
Color: Fine, Light-Tan Cyrstals
Odor: None reported.
pH: Not available.
Vapor Pressure: .01 mm Hg @ 20 deg C
Viscosity: Not available.
Boiling Point: 272 deg C @ 760 mm Hg
Freezing/Melting Point: 69 - 73 deg C
Autoignition Temperature: 265 deg C ( 509.00 deg F)
Flash Point: 166 deg C ( 330.80 deg F)
Explosion Limits, lower: 2.80 vol %
Explosion Limits, upper: 7.20 vol %
Decomposition Temperature:
Solubility in water: Insoluble.
Specific Gravity/Density:
Molecular Formula: C6H5Cl2N
Molecular Weight: 162.02
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Dust generation, excess heat.
Incompatibilities with Other Materials:
Strong oxidizing agents, acids, acid anhydrides, acid chlorides.
Hazardous Decomposition Products:
Hydrogen chloride, nitrogen oxides, carbon monoxide, carbon dioxide,
aniline.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 95-76-1: BX2625000
CAS# 27134-27-6 unlisted.
LD50/LC50:
CAS# 95-76-1: Draize test, rabbit, eye: 250 ug/24H Severe; Draize
test, rabbit, eye: 10 mg Mild; Draize test, rabbit, skin: 2 mg/24H
Severe; Oral, mouse: LD50 = 740 mg/kg; Oral, rabbit: LD50 = 675
mg/kg; Oral, rat: LD50 = 545 mg/kg.
CAS# 27134-27-6.
CAS# 62-53-3: Dermal, rabbit: 820 ul/kg. The toxicity of this
product is partially based on the hazards associated with aniline.
Carcinogenicity:
3,4-Dichloroaniline -
Not listed by ACGIH, IARC, or NTP.
Dichloroaniline -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Ecotoxicity:
Fish: Fathead Minnow: 8.06 mg/L; 96 hr; LC50Fish: Fathead Minnow: 7.0
mg/L; 96 hr; LC50Fish: Fathead Minnow: 6.7 mg/L; 96 hr; EC50Daphnia:
Water Flea: 7.6 x 10-6 mol/L; 96 hr; LC50Migration and decomposition
in soil and flax plants: residues of 150-200 ug/kg were found in
seeds indicating a fairly high persistence of 3,4-Dichloraniline.;
Estimated Log BCF Value = 1.81 from recommended regression-derived
equation. This value is not indicative of significant
bioconcentration in aquatic organisms.; Approximated Koc Value = 300
using an appropriate regression-derived equation. This value suggests
medium soil mobility.
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: DICHLOROANILINES, SOLID
Hazard Class: 6.1
UN Number: 1590
Packing Group: II
IMO
Shipping Name: DICHLOROANILINES, SOLID
Hazard Class: 6.1
UN Number: 1590
Packing Group: II
RID/ADR
Shipping Name: DICHLOROANILINES
Hazard Class: 6.1
UN Number: 1590
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T N
Risk Phrases:
R 23/24/25 Toxic by inhalation, in contact with skin
and if swallowed.
R 33 Danger of cumulative effects.
R 50/53 Very toxic to aquatic organisms, may cause
long-term adverse effects in the aquatic environment.
Safety Phrases:
S 28A After contact with skin, wash immediately with
plenty of water.
S 36/37 Wear suitable protective clothing and
gloves.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
S 60 This material and its container must be
disposed of as hazardous waste.
S 61 Avoid release to the environment. Refer to
special instructions/safety data sheets.
WGK (Water Danger/Protection)
CAS# 95-76-1: 3
CAS# 27134-27-6: No information available.
Canada
CAS# 95-76-1 is listed on Canada's DSL List.
CAS# 95-76-1 is listed on Canada's Ingredient Disclosure List.
CAS# 27134-27-6 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 95-76-1 is listed on the TSCA inventory.
CAS# 27134-27-6 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
Text for R-phrases from Section 2
MSDS Creation Date: 11/02/1998 Revision #3 Date: 5/09/2002
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Neodymium chloride hexahydrate, 99.99%
| 13477-89-9 |
|
4-Methylbenzophenone, 97%
| 134-84-9 |
|
4-Biphenylcarbonyl chloride, 98%
| 14002-51-8 |
|
1,4-Dicyanobenzene, 98%
| 623-26-7 |
|
2-Iodophenol
| 533-58-4 |
|
d-alpha-Tocopheryl acid succinate, 99+% (gc)
| 4345-03-3 |
|
2-Cyclopentylidenecyclopentanone, 97%
| 825-25-2 |
|
1,4-Dichloro-2-Iodobenzene, 98%
| 29682-41-5 |
|
6-P-Toluidine-2-Naphthalenesulfonic Acid, 99% (Titr.)
| 7724-15-4 |
|
N,N'-Diethyl-2-Butene-1,4-Diamine, 97%
| 112-21-0 |
|
1-Amino-5,6,7,8-tetrahydronaphthalene, tech., 90%
| 2217-41-6 |
|
N-Ethylbenzylamine, 97%
| 14321-27-8 |
|
Allyl phenoxyacetate, 98+%
| 7493-74-5 |
|
3-Nitrostyrene, 97%
| 586-39-0 |
|
Ruthenium on alumina powder (5% ru)
| |
|
Nipecotamide, 95%
| 4138-26-5 |
|
8-Hydroxy-7-(6-Sulfo-2-Naphthylazo)-5-Quinolinesulfonic Acid Disodium
| 56932-43-5 |
|
Molybdocene Dichloride
| 12184-22-4 |
|
1,2,3,5-Tetramethylbenzene, Tech., 85+%
| 527-53-7 |
|
Androsterone, 97%
| 53-41-8 |
|
1,3-Dimethyl-5-aminoadamantane hydrochloride
| 19982-08-2 |
|
4-Methoxyphenylhydrazine hydrochloride 98%
| 19501-58-7 |
|
2,4,6-Trichloropyrimidine, 99%
| 3764-01-0 |
|
1-Bromo-3-phenylpropane, 98%
| 637-59-2 |
|
Aluminum Tert-Butoxide, 98% (Grav.)
| 556-91-2 |
|
4-Aminothiophenol,96%
| 1193-02-8 |
|
1,2-Dimethyl-3-Hydroxy-4-Pyridone, 99+%
| 30652-11-0 |
|
1,1,1-Tris-(Hydroxymethyl)-Ethane, 97%
| 77-85-0 |
|
4-Benzoylpyridine, 98%
| 14548-46-0 |
|
tert-Butylchlorodiphenylsilane, 98%
| 58479-61-1 |
|
4,4'-Azodianiline, 95% (Titr.)
| 538-41-0 |
|
2-Methyl-5-nitroaniline, 99%
| 99-55-8 |
|
(s)-(-)-1-Benzylglycerol, 98%
| 17325-85-8 |
|
Maleimide, 98%
| 541-59-3 |
|
2-Chlorobenzoxazole, 99% (GC)
| 615-18-9 |
|
Methyl Thiocyanate, 99%
| 556-64-9 |
|
Alpha, 4-Dichloroanisole, 97%
| 21151-56-4 |
|
Lanthanum hexaboride, 99%
| 12008-21-8 |
|
Dl-methyl mandelate, 97%
| 4358-87-6 |
|
(5-z)-9-deoxy-6,9alpha-epoxy-PGF1alpha, sodium salt, 98%, stab. with
| 61849-14-7 |
|
(-)-2-Cyano-6-Phenyloxazolopiperidine, 99+%
| 88056-92-2 |
|
3,4-Dichloroaniline, 98%
| 95-76-1 |
|
Indole, 99+%
| 120-72-9 |
|
3-Methylbenzophenone, 99%
| 643-65-2 |
|
3-Hydroxy-6-Methyl-2-Nitropyridine, 99%
| 15128-90-2 |
|
1,1,3,3-Tetramethyl-2-thiourea, 98%
| 2782-91-4 |
|
1,2-Bis(2-aminophenoxy)-ethane-N,N,N', N'-tetraacetic acid
| 126824-24-6 |
|
6-Amino-5-nitroso-2-thiouracil, 99%
| 1672-48-6 |
|
N,N-Diethylaniline, 99%
| 91-66-7 |
|
Tetraethylammonium tetrafluoroborate, 99%
| 429-06-1 |
|
|