**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 121-33-5 |Vanillin | 100 | 204-465-2 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: None Listed.
Risk Phrases: None Listed.
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Light sensitive.Moisture sensitive.
Potential Health Effects
Eye:
Dust may cause mechanical irritation. Low hazard for normal
industrial handling.
Skin:
Dust may cause mechanical irritation. May cause skin sensitization,
an allergic reaction, which becomes evident upon re-exposure to this
material. Low hazard for usual industrial handling.
Ingestion:
May cause irritation of the digestive tract.
Inhalation:
No hazard expected in normal industrial use. Dust is irritating to
the respiratory tract.
Chronic:
Not available.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid if irritation develops or persists. Wash clothing
before reuse. Flush skin with plenty of soap and water.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Treat
symptomatically and supportively. Get medical aid if irritation or
symptoms occur.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid if cough or other symptoms appear.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear.
Extinguishing Media:
In case of fire, use water, dry chemical, chemical foam, or
alcohol-resistant foam. Use agent most appropriate to extinguish
fire.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Clean up spills immediately, observing precautions in the Protective
Equipment section. Sweep up, then place into a suitable container for
disposal. Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use with adequate ventilation. Store protected
from light.
Storage:
Store in a cool, dry place. Store protected from moisture. Store
protected from light.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 121-33-5:
Russia: 1.5 mg/m3 TWA
Personal Protective Equipment
Eyes:
Wear safety glasses and chemical goggles if splashing
is possible.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Solid
Color: very slightly yellow
Odor: vanilla-like
pH: Not available.
Vapor Pressure: 1 mm Hg @ 107 deg C
Viscosity: Not applicable.
Boiling Point: 285 deg C
Freezing/Melting Point: 81-83 deg C
Autoignition Temperature: Not available.
Flash Point: 147 deg C ( 296.60 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: Not applicable.
Solubility in water: Slightly soluble in water.
Specific Gravity/Density: 1.05
Molecular Formula: C8H8O3
Molecular Weight: 152.0542
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, light, moisture.
Incompatibilities with Other Materials:
Strong oxidizing agents, strong bases, light, air, strong reducing
agents, moisture, bromine, perchloric acid, potassium t-butoxide,
t-chlorobenzene and sodium hydroxide, formic acid and thallium
nitrate.
Hazardous Decomposition Products:
Carbon monoxide, irritating and toxic fumes and gases, carbon
dioxide.
Hazardous Polymerization: Will not occur.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 121-33-5: YW5775000
LD50/LC50:
CAS# 121-33-5: Oral, mouse: LD50 = 3925 mg/kg; Oral, mouse: LD50 =
1480 mg/kg; Oral, rat: LD50 = 1580 mg/kg; Skin, rabbit: LD50 = >5010
mg/kg.
Carcinogenicity:
Vanillin -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Products which are considered hazardous for supply are classified as Special
Waste and the disposal of such chemicals is covered by regulations which may
vary according to location. Contact a specialist disposal company or the local
waste regulator for advice. Empty containers must be decontaminated before
returning for recycling.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
WGK (Water Danger/Protection)
CAS# 121-33-5: No information available.
Canada
CAS# 121-33-5 is listed on Canada's DSL List.
CAS# 121-33-5 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 121-33-5 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 2/10/1998 Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
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| 272-30-0 |
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Triton X-100
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N-Chlorosuccinimide, 98+%
| 128-09-6 |
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Trypsin
| 9002-07-7 |
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3-(Maleimidomethyl)-Proxyl, Free Radical
| 54060-41-2 |
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4-Nitro-O-Phenylenediamine, 95% (UV-VIS)
| 99-56-9 |
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(R)-(+)-1,1'-Bi-2-naphthol, 99%
| 18531-94-7 |
|
Calix[6]Arene, 99% (TLC)
| 96107-95-8 |
|
2-Methylene-3-quinuclidinone hydrochloride dihydrate, 97%
| 5832-55-3 |
|
Tungsten (VI) Oxide
| 1314-35-8 |
|
[Tetra(diphenoxyphosphoryl)]tetra-methylcalix[4]resorcinolarene, 98%
| 160399-36-0 |
|
Allantoin, 98%
| 97-59-6 |
|
Turpentine Oil
| 8006-64-2 |
|
2,6-Dichlorobenzonitrile, 97%
| 1194-65-6 |
|
Methyllithium, low chloride, 1.6 M in diethyl ether (+/- 5% w/v)
| 60-29-7 |
|
Uranine
| 518-47-8 |
|
Lauryl chloride, 99%
| 112-52-7 |
|
2-(3-Hydroxycarbonyl-2-nitrophenyl) malondialdehyde, 95%
| |
|
Ethyl 3,3-Dimethylaminoacrylate, 99+%
| 924-99-2 |
|
DL-4-Chloro-Alpha-Methylphenylacetic Acid, 98%
| 938-95-4 |
|
3-Amino-3-phenylpropionic acid, tech. 90+% remainder dl-phenylalanine
| 150-30-1 |
|
Diethylenetriaminepentaacetic Acid Pentasodium Salt (Techn) (40% in
| 140-01-2 |
|
4-Fluorophenyl isothiocyanate, 98%
| 1544-68-9 |
|
N,N'-Dicarboxymethyldiaza-18-Crown-6, 99+%
| 0-01-1 |
|
Urea
| 57-13-6 |
|
2,6-Dichlorostyrene, 98%
| 28469-92-3 |
|
3-Methyl-2-cyclopenten-1-one, 98%
| 2758-18-1 |
|
1-Methylpyrrolidine, 98%
| 120-94-5 |
|
2-Mercaptothiazoline, 98%
| 96-53-7 |
|
2,4-Dihydroxypyridine, 97%
| 626-03-9 |
|
4-Amino-1-Naphthalenecarbonitrille, 98%
| 58728-64-6 |
|
Diethyl 2-Bromoethylphosphonate, 97%
| 5324-30-1 |
|
Bis(4-Dimethylaminodithiobenzil)Nickel, Laser Grade, 99% (UV-Vis)
| 38465-55-3 |
|
1,1,1-Trifluoro-5,5-Dimethyl-2,4-Hexane-Dione, 99% (GC)
| 22767-90-4 |
|
1-Butanesulfonic acid, sodium salt, 98%
| 2386-54-1 |
|
Malonamide, 97%
| 108-13-4 |
|
Anisoin, 95%
| 119-52-8 |
|
Bismarck Brown Y (Cert)
| 10114-58-6 |
|
Methyl p-tolyl sulfone, 99+%
| 3185-99-7 |
|
Dl-phenylalanine-d11
| |
|
Methyl thioglycolate, 95%
| 2365-48-2 |
|
Vanadyl Sulfate
| 27774-13-6 |
|
6-Hydroxy-2,4,5-triaminopyrimidine Sulfate Hydrate, 98%
| 35011-47-3 |
|
1-Ethynylcyclopentanol, 98%
| 17356-19-3 |
|
Fast Red B Salt
| 27761-26-8 |
|
2-Fluoropyridine, 98%
| 372-48-5 |
|
Benzyl isothiocyanate, 98% (GC)
| 622-78-6 |
|
Cytosine Arabinoside Hydrochloride
| 69-74-9 |
|
Vanillin
| 121-33-5 |
|
2,3-Dimethylaniline, 99%
| 87-59-2 |
|
|