**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 2365-48-2 |Methyl thioglycolate | 95 | 219-121-7 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN
Risk Phrases: 22 36/38
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful if swallowed. Irritating to eyes and skin.Stench.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation.
Ingestion:
Harmful if swallowed.
Inhalation:
May cause respiratory tract irritation. Vapors may cause dizziness
or suffocation.
Chronic:
No information found.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid immediately. Flush skin with plenty of water for at
least 15 minutes while removing contaminated clothing and shoes.
Wash clothing before reuse.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical
aid immediately.
Inhalation:
Remove from exposure and move to fresh air immediately. If breathing
is difficult, give oxygen. Get medical aid. Do NOT use mouth-to-mouth
resuscitation. If breathing has ceased apply artificial respiration
using oxygen and a suitable mechanical device such as a bag and a
mask.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Vapors may form an explosive mixture with air.
During a fire, irritating and highly toxic gases may be generated by
thermal decomposition or combustion. Use water spray to keep
fire-exposed containers cool. Containers may explode in the heat of
a fire. Flammable liquid and vapor. Vapors are heavier than air and
may travel to a source of ignition and flash back. Vapors can spread
along the ground and collect in low or confined areas.
Extinguishing Media:
For small fires, use dry chemical, carbon dioxide, water spray or
alcohol-resistant foam. For large fires, use water spray, fog, or
alcohol-resistant foam. Water may be ineffective. Do NOT use
straight streams of water.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Clean up spills immediately,
observing precautions in the Protective Equipment section. Remove all
sources of ignition. Use a spark-proof tool. Provide ventilation. A
vapor suppressing foam may be used to reduce vapors.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Ground and bond containers when
transferring material. Use spark-proof tools and explosion proof
equipment. Avoid contact with eyes, skin, and clothing. Empty
containers retain product residue, (liquid and/or vapor), and can be
dangerous. Keep container tightly closed. Use only in a chemical
fume hood. Do not pressurize, cut, weld, braze, solder, drill, grind,
or expose empty containers to heat, sparks or open flames. Use only
with adequate ventilation. Keep away from heat, sparks and flame.
Avoid breathing vapor or mist.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of
ignition. Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances.
Flammables-area.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 2365-48-2:
Personal Protective Equipment
Eyes:
Wear chemical splash goggles.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: Not available.
Odor: stench
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 42 - 43 deg C @ 10 mmHg
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: 56 deg C ( 132.80 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: miscible
Specific Gravity/Density: 1.18 g/cm3
Molecular Formula: C3H6O2S
Molecular Weight: 106.14
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Ignition sources, excess heat.
Incompatibilities with Other Materials:
Strong oxidizing agents, strong bases.
Hazardous Decomposition Products:
Carbon monoxide, oxides of sulfur, carbon dioxide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 2365-48-2: AI7350000
LD50/LC50:
CAS# 2365-48-2: Oral, rat: LD50 = 84 mg/kg.
Carcinogenicity:
Methyl thioglycolate -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: MERCAPTANS, LIQUID, FLAMMABLE, TOXIC, N.O.S.
Hazard Class: 3
UN Number: 1228
Packing Group: III
IMO
Shipping Name: MERCAPTANS, LIQUID, FLAMMABLE, TOXIC, N.O.S.
Hazard Class: 3.3
UN Number: 1228
Packing Group: III
RID/ADR
Shipping Name: MERCAPTANS, LIQUID, FLAMMABLE, TOXIC, N.O.S.
Hazard Class: 3
UN Number: 1228
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 22 Harmful if swallowed.
R 36/38 Irritating to eyes and skin.
Safety Phrases:
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 2365-48-2: No information available.
Canada
CAS# 2365-48-2 is listed on Canada's DSL List.
CAS# 2365-48-2 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 2365-48-2 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 11/23/1998 Revision #5 Date: 10/05/2004
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
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Benzo[b]selenophene, 99%
| 272-30-0 |
|
Triton X-100
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N-Chlorosuccinimide, 98+%
| 128-09-6 |
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Trypsin
| 9002-07-7 |
|
3-(Maleimidomethyl)-Proxyl, Free Radical
| 54060-41-2 |
|
4-Nitro-O-Phenylenediamine, 95% (UV-VIS)
| 99-56-9 |
|
(R)-(+)-1,1'-Bi-2-naphthol, 99%
| 18531-94-7 |
|
Calix[6]Arene, 99% (TLC)
| 96107-95-8 |
|
2-Methylene-3-quinuclidinone hydrochloride dihydrate, 97%
| 5832-55-3 |
|
Tungsten (VI) Oxide
| 1314-35-8 |
|
[Tetra(diphenoxyphosphoryl)]tetra-methylcalix[4]resorcinolarene, 98%
| 160399-36-0 |
|
Allantoin, 98%
| 97-59-6 |
|
Turpentine Oil
| 8006-64-2 |
|
2,6-Dichlorobenzonitrile, 97%
| 1194-65-6 |
|
Methyllithium, low chloride, 1.6 M in diethyl ether (+/- 5% w/v)
| 60-29-7 |
|
Uranine
| 518-47-8 |
|
Lauryl chloride, 99%
| 112-52-7 |
|
2-(3-Hydroxycarbonyl-2-nitrophenyl) malondialdehyde, 95%
| |
|
Ethyl 3,3-Dimethylaminoacrylate, 99+%
| 924-99-2 |
|
DL-4-Chloro-Alpha-Methylphenylacetic Acid, 98%
| 938-95-4 |
|
3-Amino-3-phenylpropionic acid, tech. 90+% remainder dl-phenylalanine
| 150-30-1 |
|
Diethylenetriaminepentaacetic Acid Pentasodium Salt (Techn) (40% in
| 140-01-2 |
|
4-Fluorophenyl isothiocyanate, 98%
| 1544-68-9 |
|
N,N'-Dicarboxymethyldiaza-18-Crown-6, 99+%
| 0-01-1 |
|
Urea
| 57-13-6 |
|
2,6-Dichlorostyrene, 98%
| 28469-92-3 |
|
3-Methyl-2-cyclopenten-1-one, 98%
| 2758-18-1 |
|
1-Methylpyrrolidine, 98%
| 120-94-5 |
|
2-Mercaptothiazoline, 98%
| 96-53-7 |
|
2,4-Dihydroxypyridine, 97%
| 626-03-9 |
|
4-Amino-1-Naphthalenecarbonitrille, 98%
| 58728-64-6 |
|
Diethyl 2-Bromoethylphosphonate, 97%
| 5324-30-1 |
|
Bis(4-Dimethylaminodithiobenzil)Nickel, Laser Grade, 99% (UV-Vis)
| 38465-55-3 |
|
1,1,1-Trifluoro-5,5-Dimethyl-2,4-Hexane-Dione, 99% (GC)
| 22767-90-4 |
|
1-Butanesulfonic acid, sodium salt, 98%
| 2386-54-1 |
|
Malonamide, 97%
| 108-13-4 |
|
Anisoin, 95%
| 119-52-8 |
|
Bismarck Brown Y (Cert)
| 10114-58-6 |
|
Methyl p-tolyl sulfone, 99+%
| 3185-99-7 |
|
Dl-phenylalanine-d11
| |
|
Methyl thioglycolate, 95%
| 2365-48-2 |
|
Vanadyl Sulfate
| 27774-13-6 |
|
6-Hydroxy-2,4,5-triaminopyrimidine Sulfate Hydrate, 98%
| 35011-47-3 |
|
1-Ethynylcyclopentanol, 98%
| 17356-19-3 |
|
Fast Red B Salt
| 27761-26-8 |
|
2-Fluoropyridine, 98%
| 372-48-5 |
|
Benzyl isothiocyanate, 98% (GC)
| 622-78-6 |
|
Cytosine Arabinoside Hydrochloride
| 69-74-9 |
|
Vanillin
| 121-33-5 |
|
2,3-Dimethylaniline, 99%
| 87-59-2 |
|
|