**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 1544-68-9 |Benzene, 1-fluoro-4-isothiocyanato- | 98 | 216-280-4 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN
Risk Phrases: 20/21 36
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful by inhalation and in contact with skin. Irritating to eyes.
Potential Health Effects
Eye:
Causes eye irritation. May cause chemical conjunctivitis.
Skin:
Causes skin irritation.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea.
Inhalation:
Causes respiratory tract irritation. Can produce delayed pulmonary
edema.
Chronic:
Effects may be delayed.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and
drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid. Do NOT use mouth-to-mouth
resuscitation.
Notes to Physician:
Treat symptomatically and supportively.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or appropriate foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Clean up spills immediately, observing precautions in the Protective
Equipment section. Sweep up, then place into a suitable container for
disposal. Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Remove contaminated clothing and wash before reuse. Avoid contact
with eyes, skin, and clothing. Avoid ingestion and inhalation. Use
with adequate ventilation. Wash clothing before reuse.
Storage:
Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances. Keep
refrigerated. (Store below 4C/39F.)
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 1544-68-9:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Solid
Color: not available
Odor: none reported
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 228 deg C @ 760.00mm Hg
Freezing/Melting Point: 26.00 - 28.00 deg C
Autoignition Temperature: Not applicable.
Flash Point: 89 deg C ( 192.20 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: Not available.
Solubility in water: Not available.
Specific Gravity/Density: Not available.
Molecular Formula: C7H4FNS
Molecular Weight: 153.17
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable at room temperature in closed containers under normal storage
and handling conditions.
Conditions to Avoid:
Incompatible materials, excess heat.
Incompatibilities with Other Materials:
Alcohols, acids, amines, strong bases, strong oxidizing agents, heat.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, oxides of sulfur, carbon dioxide,
hydrogen fluoride gas.
Hazardous Polymerization: Has not been reported
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 1544-68-9: NX8760000
LD50/LC50:
Not available.
Carcinogenicity:
Benzene, 1-fluoro-4-isothiocyanato- -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: TEAR GAS SUBSTANCE, LIQUID, N.O.S.*
Hazard Class: 6.1
UN Number: 1693
Packing Group: II
IMO
Shipping Name: TEAR GAS SUBSTANCE, LIQUID, N.O.S.
Hazard Class: 6.1
UN Number: 1693
Packing Group: II
RID/ADR
Shipping Name: TEAR GAS SUBSTANCE, LIQUID, N.O.S.
Hazard Class: 6.1
UN Number: 1693
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 20/21 Harmful by inhalation and in contact with
skin.
R 36 Irritating to eyes.
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 1544-68-9: No information available.
Canada
CAS# 1544-68-9 is listed on Canada's NDSL List.
CAS# 1544-68-9 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 1544-68-9 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/02/1997 Revision #4 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
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| ALL MSDS PAGES IN THIS GROUP
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Trypsin
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(R)-(+)-1,1'-Bi-2-naphthol, 99%
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2-Methylene-3-quinuclidinone hydrochloride dihydrate, 97%
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[Tetra(diphenoxyphosphoryl)]tetra-methylcalix[4]resorcinolarene, 98%
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Turpentine Oil
| 8006-64-2 |
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2,6-Dichlorobenzonitrile, 97%
| 1194-65-6 |
|
Methyllithium, low chloride, 1.6 M in diethyl ether (+/- 5% w/v)
| 60-29-7 |
|
Uranine
| 518-47-8 |
|
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| 112-52-7 |
|
2-(3-Hydroxycarbonyl-2-nitrophenyl) malondialdehyde, 95%
| |
|
Ethyl 3,3-Dimethylaminoacrylate, 99+%
| 924-99-2 |
|
DL-4-Chloro-Alpha-Methylphenylacetic Acid, 98%
| 938-95-4 |
|
3-Amino-3-phenylpropionic acid, tech. 90+% remainder dl-phenylalanine
| 150-30-1 |
|
Diethylenetriaminepentaacetic Acid Pentasodium Salt (Techn) (40% in
| 140-01-2 |
|
4-Fluorophenyl isothiocyanate, 98%
| 1544-68-9 |
|
N,N'-Dicarboxymethyldiaza-18-Crown-6, 99+%
| 0-01-1 |
|
Urea
| 57-13-6 |
|
2,6-Dichlorostyrene, 98%
| 28469-92-3 |
|
3-Methyl-2-cyclopenten-1-one, 98%
| 2758-18-1 |
|
1-Methylpyrrolidine, 98%
| 120-94-5 |
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2-Mercaptothiazoline, 98%
| 96-53-7 |
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2,4-Dihydroxypyridine, 97%
| 626-03-9 |
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4-Amino-1-Naphthalenecarbonitrille, 98%
| 58728-64-6 |
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Diethyl 2-Bromoethylphosphonate, 97%
| 5324-30-1 |
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| 38465-55-3 |
|
1,1,1-Trifluoro-5,5-Dimethyl-2,4-Hexane-Dione, 99% (GC)
| 22767-90-4 |
|
1-Butanesulfonic acid, sodium salt, 98%
| 2386-54-1 |
|
Malonamide, 97%
| 108-13-4 |
|
Anisoin, 95%
| 119-52-8 |
|
Bismarck Brown Y (Cert)
| 10114-58-6 |
|
Methyl p-tolyl sulfone, 99+%
| 3185-99-7 |
|
Dl-phenylalanine-d11
| |
|
Methyl thioglycolate, 95%
| 2365-48-2 |
|
Vanadyl Sulfate
| 27774-13-6 |
|
6-Hydroxy-2,4,5-triaminopyrimidine Sulfate Hydrate, 98%
| 35011-47-3 |
|
1-Ethynylcyclopentanol, 98%
| 17356-19-3 |
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Fast Red B Salt
| 27761-26-8 |
|
2-Fluoropyridine, 98%
| 372-48-5 |
|
Benzyl isothiocyanate, 98% (GC)
| 622-78-6 |
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| 69-74-9 |
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Vanillin
| 121-33-5 |
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2,3-Dimethylaniline, 99%
| 87-59-2 |
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