**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 8006-64-2 |Turpentine | 100.0 | 232-350-7 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN F N
Risk Phrases: 10 20/21/22 36/38 43 51/53 65
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Flammable. Harmful by inhalation, in contact with skin and if
swallowed. Irritating to eyes and skin. May cause sensitization by
skin contact. Toxic to aquatic organisms, may cause long-term adverse
effects in the aquatic environment. Harmful: may cause lung damage if
swallowed.Flammable liquid.
Potential Health Effects
Eye:
Contact with eyes may cause severe irritation, and possible eye
burns.
Skin:
Causes skin irritation. May cause skin sensitization, an allergic
reaction, which becomes evident upon re-exposure to this material.
Ingestion:
Causes gastrointestinal irritation with nausea, vomiting and
diarrhea. May cause kidney damage. May cause central nervous system
depression, characterized by excitement, followed by headache,
dizziness, drowsiness, and nausea. Advanced stages may cause
collapse, unconsciousness, coma and possible death due to
respiratory failure. Aspiration of material into the lungs may cause
chemical pneumonitis, which may be fatal.
Inhalation:
May cause respiratory tract irritation. Aspiration may cause
respiratory swelling and pneumonitis.
Chronic:
Not available.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Flush skin with plenty of water for at least 15 minutes while
removing contaminated clothing and shoes. Get medical aid if
irritation develops or persists.
Ingestion:
Do not induce vomiting. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Flammable Liquid. Can release vapors that form
explosive mixtures at temperatures above the flashpoint.
Extinguishing Media:
Use water fog, dry chemical, carbon dioxide, or regular foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Use a spark-proof tool.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Wash hands before eating. Use only
in a well-ventilated area. Ground and bond containers when
transferring material. Use spark-proof tools and explosion proof
equipment. Avoid contact with skin and eyes. Empty containers retain
product residue, (liquid and/or vapor), and can be dangerous. Avoid
ingestion and inhalation. Do not ingest or inhale. Do not
pressurize, cut, weld, braze, solder, drill, grind, or expose empty
containers to heat, sparks or open flames.
Storage:
Keep away from sources of ignition. Store in a cool place in the
original container and protect from sunlight. Store in a tightly
closed container.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use adequate general or local explosion-proof ventilation to keep
airborne levels to acceptable levels.
Exposure Limits
CAS# 8006-64-2:
United Kingdom, WEL - TWA: 100 ppm TWA; 566 mg/m3 TWA
United Kingdom, WEL - STEL: 150 ppm STEL; 850 mg/m3 STEL
United States OSHA: 100 ppm TWA; 560 mg/m3 TWA
Belgium - TWA: 100 ppm VLE; 564 mg/m3 VLE
France - VME: 100 ppm VME; 560 mg/m3 VME
Germany: 100 ppm TWA; 560 mg/m3 TWA
Germany: Skin absorber
Japan: 50 ppm OEL; 280 mg/m3 OEL
Malaysia: 100 ppm TWA; 556 mg/m3 TWA
Netherlands: 100 ppm MAC; 560 mg/m3 MAC
Russia: 300 mg/m3 TWA
Spain: 100 ppm VLA-ED; 567 mg/m3 VLA-ED
Spain: 150 ppm VLA-EC; 850 mg/m3 VLA-EC
Personal Protective Equipment
Eyes:
Wear chemical splash goggles.
Skin:
Wear appropriate gloves to prevent skin exposure.
Clothing:
Wear appropriate gloves to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: colorless
Odor: disagreeable odor
pH: Not available.
Vapor Pressure: 577 mm Hg
Viscosity: Not available.
Boiling Point: 309-338 F (154-170 C)
Freezing/Melting Point: -58 - -76 F (-50 - -60 C)
Autoignition Temperature: 488 deg F ( 253.33 deg C)
Flash Point: 95 deg F ( 35.00 deg C)
Explosion Limits, lower: 0.8% v/v
Explosion Limits, upper: None reported
Decomposition Temperature: Not available.
Solubility in water: Insoluble in water
Specific Gravity/Density: 0.86 at 59 F
Molecular Formula: C10H16
Molecular Weight: 136.112
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Ignition sources, exposure to air, excess heat.
Incompatibilities with Other Materials:
Calcium hypochlorite, chlorine, chromic anhydride, chromyl chloride,
hexachloromelamine, stannic chloride, and trichloromelamine.
Hazardous Decomposition Products:
Carbon monoxide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 8006-64-2: YO8400000
LD50/LC50:
CAS# 8006-64-2: Draize test, rabbit, skin: 500 uL Severe;
Inhalation, mouse: LC50 = 29 mg/m3/2H; Inhalation, mouse: LC50 =
30000 mg/m3; Inhalation, rat: LC50 = 12 gm/m3/6H; Inhalation, rat:
LC50 = 16600 mg/m3/2H; Inhalation, rat: LC50 = 13700 mg/m3/4H; Oral,
rat: LD50 = 5760 mg/kg.
Carcinogenicity:
Turpentine -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Other
No information available.
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Products which are considered hazardous for supply are classified as Special
Waste and the disposal of such chemicals is covered by regulations which may
vary according to location. Contact a specialist disposal company or the local
waste regulator for advice. Empty containers must be decontaminated before
returning for recycling.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: TURPENTINE
Hazard Class: 3
UN Number: 1299
Packing Group: III
IMO
Shipping Name: TURPENTINE
Hazard Class: 3
UN Number: 1299
Packing Group: III
RID/ADR
Shipping Name: TURPENTINE
Hazard Class: 3
UN Number: 1299
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN F N
Risk Phrases:
R 10 Flammable.
R 20/21/22 Harmful by inhalation, in contact with
skin and if swallowed.
R 36/38 Irritating to eyes and skin.
R 43 May cause sensitization by skin contact.
R 51/53 Toxic to aquatic organisms, may cause
long-term adverse effects in the aquatic environment.
R 65 Harmful: may cause lung damage if swallowed.
Safety Phrases:
S 36/37 Wear suitable protective clothing and
gloves.
S 46 If swallowed, seek medical advice immediately
and show this container or label.
S 61 Avoid release to the environment. Refer to
special instructions/safety data sheets.
S 62 If swallowed, do not induce vomiting: seek
medical advice immediately and show this container or
label.
WGK (Water Danger/Protection)
CAS# 8006-64-2: No information available.
Canada
CAS# 8006-64-2 is listed on Canada's DSL List.
CAS# 8006-64-2 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 8006-64-2 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 12/12/1997 Revision #4 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|