**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 122-00-9 |4'-Methylacetophenone | 95 | 204-514-8 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN
Risk Phrases: 22
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful if swallowed.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea. May be harmful if swallowed.
Inhalation:
May cause respiratory tract irritation. Material has a very low
vapor pressure and inhalation exposures are not expected unless
material is heated or misted.
Chronic:
Prolonged or repeated skin contact may cause defatting and
dermatitis.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
In case of contact, immediately flush eyes with plenty of water for
at least 15 minutes. Get medical aid.
Skin:
In case of contact, flush skin with plenty of water. Remove
contaminated clothing and shoes. Get medical aid if irritation
develops and persists. Wash clothing before reuse.
Ingestion:
If swallowed, do not induce vomiting unless directed to do so by
medical personnel. Never give anything by mouth to an unconscious
person. Get medical aid.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial
respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Use water
spray to keep fire-exposed containers cool. Combustible liquid and
vapor.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or appropriate foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Clean up spills immediately,
observing precautions in the Protective Equipment section. Remove all
sources of ignition. Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Avoid contact with eyes, skin, and clothing. Empty
containers retain product residue, (liquid and/or vapor), and can be
dangerous. Keep container tightly closed. Avoid ingestion and
inhalation. Do not pressurize, cut, weld, braze, solder, drill,
grind, or expose empty containers to heat, sparks or open flames.
Use only with adequate ventilation. Keep away from heat and flame.
Avoid breathing spray or mist.
Storage:
Keep away from sources of ignition. Store in a tightly closed
container. Store in a cool, dry, well-ventilated area away from
incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 122-00-9:
Personal Protective Equipment
Eyes:
Wear chemical splash goggles.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: clear, colorless to pale yellow
Odor: sweetish odor
pH: Not available.
Vapor Pressure: 0.221 mm Hg @ 25 deg C
Viscosity: Not available.
Boiling Point: 226 deg C @ 760 mm Hg
Freezing/Melting Point: -19 deg C
Autoignition Temperature: Not available.
Flash Point: 92 deg C ( 197.60 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: 0.37 g/l (15C)
Specific Gravity/Density: 1.005 g/cm3
Molecular Formula: C9H10O
Molecular Weight: 134.18
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Ignition sources, excess heat.
Incompatibilities with Other Materials:
Strong oxidizing agents, strong reducing agents, strong bases.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 122-00-9: AM9463000
LD50/LC50:
CAS# 122-00-9: Draize test, rabbit, skin: 500 mg/24H Mild; Oral,
rat: LD50 = 1400 mg/kg.
Carcinogenicity:
4'-Methylacetophenone -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Ecotoxicity:
Daphnia: Daphnia: 31 mg/l; 48H; EC50
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 22 Harmful if swallowed.
Safety Phrases:
WGK (Water Danger/Protection)
CAS# 122-00-9: 2
Canada
CAS# 122-00-9 is listed on Canada's DSL List.
CAS# 122-00-9 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 122-00-9 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 7/24/1998 Revision #3 Date: 8/08/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Diethylbenzene (Mixture of 1,2-1,3-and 1,4-Isomers, Sum Min. 95%)
| 25340-17-4 |
|
5-Ethyl-2-thiophenecarboxaldehyde, 98+%
| 36880-33-8 |
|
4-Amino-Heptafluorotoluene, 95% (GC)
| 0-00-1 |
|
Flavone, 99+% (TLC)
| 525-82-6 |
|
4-Bromo-1-Chloro-2-Fluorobenzene, 98+%
| 60811-18-9 |
|
2,6-Dibromoaniline, 97%
| 608-30-0 |
|
4-Epi-Oxytetracycline,"can be used as Secondary Standard"
| 35259-39-3 |
|
Polyvinylsulfuric acid potassium salt, 90% (elem.analysis, c, h, k
| 26837-42-3 |
|
1,8-Naphthalimide, 94%(tlc)
| 81-83-4 |
|
4-Bromo-1,1,2-trifluoro-1-butene
| 10493-44-4 |
|
Diethyl Sebacate, 90% (gc)
| 110-40-7 |
|
trans-3-Hexen-1-ol, 95% (gc)
| 928-97-2 |
|
Resorufin (pract)
| 635-78-9 |
|
Adenosine 5'-Monophosphate, 99%
| 61-19-8 |
|
l-(+)-Norleucine, 99+%
| 327-57-1 |
|
3,4-Difluoronitrobenzene, 99%
| 369-34-6 |
|
2-Ethylthiophene, 99%
| 872-55-9 |
|
Adenosine-2'-Monophosphate Hemihydrate, 99%
| 81012-86-4 |
|
Exton Albumin Reagent
| 97-05-2 |
|
n-Butylurea 99%
| 592-31-4 |
|
2,2-Dimethyl-4-ethenyl-1,3-dioxolane
| 83968-02-9 |
|
N-Methylbenzothiazole-2-Thione, 99%
| 2254-94-6 |
|
Pyrimidine, 99%
| 289-95-2 |
|
Palladium on 1/8" Alumina Pellets (0.5% Pd)
| 1314-08-5 |
|
Dimethyl (2-oxoheptyl)-phosphonate, 98%
| 36969-89-8 |
|
Trimethylacetyl chloride, 99%
| 3282-30-2 |
|
2-Cyclopenten-1-one ethylene ketal, 95%
| 695-56-7 |
|
Tetrazolium violet, 98+%
| 1719-71-7 |
|
2-Bromo-4-Fluorobenzoic acid, 98%
| 1006-41-3 |
|
5-Sulfoisophthalic acid monolithium salt, 98%
| 46728-75-0 |
|
Anhydrochlortetracycline Hydrochloride can be used as Secondary
| 4497-08-9 |
|
3-(Chlorosulfonyl)benzoic acid,98% (titr.)
| 4025-64-3 |
|
Tripiperidinophosphine oxide, 98%
| 4441-17-2 |
|
2,3,3-Trichlorotetrahydro-2H-Pyran, 97+%
| 0-00-1 |
|
1-Methoxy-2-Indanol, 98%
| 56175-44-1 |
|
4'-Methylacetophenone, 95%
| 122-00-9 |
|
1,4-Hexadiene (mixture of cis and trans), 99%
| 592-45-0 |
|
2-Nitrobenzenesulfonyl chloride, 94%
| 1694-92-4 |
|
2-Nitrophenyl-2-acetamido-2-deoxy-alpha-d- glucopyranoside, 99+%
| 10139-01-2 |
|
Phenyl chlorothionocarbonate, 99%
| 1005-56-7 |
|
5-Aminoorotic Acid, 99%
| 7164-43-4 |
|
L-(+)-alpha-Phenylglycine, 99%
| 2935-35-5 |
|
P-Phenylenedipropionic Acid, 98%
| 4251-21-2 |
|
2-(4-Chlorophenyl)-2-Methylpropionic Acid, 98%
| 6247-28-5 |
|
Cyclohexyl Isocyanate, 98%
| 3173-53-3 |
|
4-(Trifluoromethoxy)benzyl bromide, 99+%
| 50824-05-0 |
|
1,3-Diiodobenzene
| 626-00-6 |
|
Trimethyl borate, 99%
| 121-43-7 |
|
Trifluoroacetic acid, silver salt, 98%
| 2966-50-9 |
|
3-Nitro-2-pentanol, 99%
| 5447-99-4 |
|
|