**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 2966-50-9 |Trifluoroacetic acid, silver salt | 98 | 221-004-0 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: T+
Risk Phrases: 28
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Very toxic if swallowed.The toxicological properties of this
material have not been fully investigated.Hygroscopic (absorbs
moisture from the air).Light sensitive.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation.
Ingestion:
May cause irritation of the digestive tract. May cause cardiac
disturbances. The toxicological properties of this substance have not
been fully investigated. May cause central nervous system depression.
Inhalation:
May cause respiratory tract irritation. The toxicological properties
of this substance have not been fully investigated. May cause cardiac
abnormalities. Inhalation at high concentrations may cause CNS
depression and asphixiation.
Chronic:
No information found.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid immediately. Do NOT induce vomiting. If conscious and alert,
rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Containers
may explode when heated. Non-combustible, substance itself does not
burn but may decompose upon heating to produce irritating, corrosive
and/or toxic fumes. Runoff from fire control or dilution water may
cause pollution.
Extinguishing Media:
Use water spray to cool fire-exposed containers. Substance is
noncombustible; use agent most appropriate to extinguish surrounding
fire.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container. Clean up spills immediately, observing precautions in the
Protective Equipment section. Avoid generating dusty conditions.
Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Minimize dust generation and
accumulation. Do not breathe dust, vapor, mist, or gas. Do not get in
eyes, on skin, or on clothing. Keep container tightly closed. Avoid
ingestion and inhalation. Store protected from light. Use only in a
chemical fume hood.
Storage:
Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances. Poison room
locked. Store protected from moisture. Store protected from light.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 2966-50-9:
Japan: (listed as silver compounds): 0.01 mg/m3 OEL (as Ag)
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to minimize
contact with skin.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Crystalline powder
Color: light beige to gray
Odor: odorless
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 257 - 260 deg C
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: >259 deg C
Solubility in water: soluble in water
Specific Gravity/Density:
Molecular Formula: CF3CO2Ag
Molecular Weight: 220.89
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures. Light sensitive.
Hygroscopic: absorbs moisture or water from the air.
Conditions to Avoid:
Incompatible materials, light, dust generation, excess heat, strong
oxidants, exposure to moist air or water.
Incompatibilities with Other Materials:
Moisture, oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, irritating and toxic fumes and gases, carbon
dioxide, hydrogen fluoride gas.
Hazardous Polymerization: Will not occur.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 2966-50-9 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Trifluoroacetic acid, silver salt -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: TOXIC SOLID, ORGANIC, N.O.S.*
Hazard Class: 6.1
UN Number: 2811
Packing Group: II
IMO
Shipping Name: TOXIC SOLID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2811
Packing Group: II
RID/ADR
Shipping Name: TOXIC SOLID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2811
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T+
Risk Phrases:
R 28 Very toxic if swallowed.
Safety Phrases:
S 20 When using do not eat or drink.
S 22 Do not breathe dust.
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 28A After contact with skin, wash immediately with
plenty of water.
S 37 Wear suitable gloves.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 2966-50-9: No information available.
Canada
CAS# 2966-50-9 is listed on Canada's DSL List.
CAS# 2966-50-9 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 2966-50-9 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/02/1997 Revision #7 Date: 10/10/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Diethylbenzene (Mixture of 1,2-1,3-and 1,4-Isomers, Sum Min. 95%)
| 25340-17-4 |
|
5-Ethyl-2-thiophenecarboxaldehyde, 98+%
| 36880-33-8 |
|
4-Amino-Heptafluorotoluene, 95% (GC)
| 0-00-1 |
|
Flavone, 99+% (TLC)
| 525-82-6 |
|
4-Bromo-1-Chloro-2-Fluorobenzene, 98+%
| 60811-18-9 |
|
2,6-Dibromoaniline, 97%
| 608-30-0 |
|
4-Epi-Oxytetracycline,"can be used as Secondary Standard"
| 35259-39-3 |
|
Polyvinylsulfuric acid potassium salt, 90% (elem.analysis, c, h, k
| 26837-42-3 |
|
1,8-Naphthalimide, 94%(tlc)
| 81-83-4 |
|
4-Bromo-1,1,2-trifluoro-1-butene
| 10493-44-4 |
|
Diethyl Sebacate, 90% (gc)
| 110-40-7 |
|
trans-3-Hexen-1-ol, 95% (gc)
| 928-97-2 |
|
Resorufin (pract)
| 635-78-9 |
|
Adenosine 5'-Monophosphate, 99%
| 61-19-8 |
|
l-(+)-Norleucine, 99+%
| 327-57-1 |
|
3,4-Difluoronitrobenzene, 99%
| 369-34-6 |
|
2-Ethylthiophene, 99%
| 872-55-9 |
|
Adenosine-2'-Monophosphate Hemihydrate, 99%
| 81012-86-4 |
|
Exton Albumin Reagent
| 97-05-2 |
|
n-Butylurea 99%
| 592-31-4 |
|
2,2-Dimethyl-4-ethenyl-1,3-dioxolane
| 83968-02-9 |
|
N-Methylbenzothiazole-2-Thione, 99%
| 2254-94-6 |
|
Pyrimidine, 99%
| 289-95-2 |
|
Palladium on 1/8" Alumina Pellets (0.5% Pd)
| 1314-08-5 |
|
Dimethyl (2-oxoheptyl)-phosphonate, 98%
| 36969-89-8 |
|
Trimethylacetyl chloride, 99%
| 3282-30-2 |
|
2-Cyclopenten-1-one ethylene ketal, 95%
| 695-56-7 |
|
Tetrazolium violet, 98+%
| 1719-71-7 |
|
2-Bromo-4-Fluorobenzoic acid, 98%
| 1006-41-3 |
|
5-Sulfoisophthalic acid monolithium salt, 98%
| 46728-75-0 |
|
Anhydrochlortetracycline Hydrochloride can be used as Secondary
| 4497-08-9 |
|
3-(Chlorosulfonyl)benzoic acid,98% (titr.)
| 4025-64-3 |
|
Tripiperidinophosphine oxide, 98%
| 4441-17-2 |
|
2,3,3-Trichlorotetrahydro-2H-Pyran, 97+%
| 0-00-1 |
|
1-Methoxy-2-Indanol, 98%
| 56175-44-1 |
|
4'-Methylacetophenone, 95%
| 122-00-9 |
|
1,4-Hexadiene (mixture of cis and trans), 99%
| 592-45-0 |
|
2-Nitrobenzenesulfonyl chloride, 94%
| 1694-92-4 |
|
2-Nitrophenyl-2-acetamido-2-deoxy-alpha-d- glucopyranoside, 99+%
| 10139-01-2 |
|
Phenyl chlorothionocarbonate, 99%
| 1005-56-7 |
|
5-Aminoorotic Acid, 99%
| 7164-43-4 |
|
L-(+)-alpha-Phenylglycine, 99%
| 2935-35-5 |
|
P-Phenylenedipropionic Acid, 98%
| 4251-21-2 |
|
2-(4-Chlorophenyl)-2-Methylpropionic Acid, 98%
| 6247-28-5 |
|
Cyclohexyl Isocyanate, 98%
| 3173-53-3 |
|
4-(Trifluoromethoxy)benzyl bromide, 99+%
| 50824-05-0 |
|
1,3-Diiodobenzene
| 626-00-6 |
|
Trimethyl borate, 99%
| 121-43-7 |
|
Trifluoroacetic acid, silver salt, 98%
| 2966-50-9 |
|
3-Nitro-2-pentanol, 99%
| 5447-99-4 |
|
|