**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 592-45-0 |1,4-Hexadiene | 99 | 209-756-8 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XI F
Risk Phrases: 11 36/37
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Highly flammable. Irritating to eyes and respiratory system.
Potential Health Effects
Eye:
Causes eye irritation. May cause chemical conjunctivitis.
Skin:
Causes skin irritation.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea. May cause central nervous system effects.
Inhalation:
May cause respiratory tract irritation. Vapors may cause dizziness
or suffocation. Can produce delayed pulmonary edema.
Chronic:
Prolonged or repeated skin contact may cause dermatitis. Effects may
be delayed.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid. Do NOT induce vomiting. Give milk or water with activated
charcoal if available.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Vapors may form an explosive mixture with air.
Vapors can travel to a source of ignition and flash back. During a
fire, irritating and highly toxic gases may be generated by thermal
decomposition or combustion. Use water spray to keep fire-exposed
containers cool. Extremely flammable liquid and vapor. Water may be
ineffective. Material is lighter than water and a fire may be spread
by the use of water. Containers may explode in the heat of a fire.
Vapors may be heavier than air. They can spread along the ground and
collect in low or confined areas. Will be easily ignited by heat,
sparks or flame.
Extinguishing Media:
For small fires, use dry chemical, carbon dioxide, water spray or
alcohol-resistant foam. For large fires, use water spray, fog, or
alcohol-resistant foam. Use water spray to cool fire-exposed
containers. Water may be ineffective. This material is lighter than
water and insoluble in water. The fire could easily be spread by the
use of water in an area where the water cannot be contained. Use
agent most appropriate to extinguish fire. Do NOT use straight
streams of water.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Avoid runoff into storm sewers and
ditches which lead to waterways. Clean up spills immediately,
observing precautions in the Protective Equipment section. Remove all
sources of ignition. Use a spark-proof tool. Provide ventilation. A
vapor suppressing foam may be used to reduce vapors.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use only in a well-ventilated area. Ground and
bond containers when transferring material. Avoid contact with eyes,
skin, and clothing. Empty containers retain product residue, (liquid
and/or vapor), and can be dangerous. Keep container tightly closed.
Keep away from heat, sparks and flame. Avoid ingestion and
inhalation. Do not pressurize, cut, weld, braze, solder, drill,
grind, or expose empty containers to heat, sparks or open flames.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of
ignition. Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances.
Flammables-area. Keep refrigerated. (Store below 4C/39F.)
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate general or
local explosion-proof ventilation to keep airborne levels to
acceptable levels.
Exposure Limits
CAS# 592-45-0:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: clear, colorless
Odor: None reported.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 64.0 - 66.0 deg C @ 760 mmHg
Freezing/Melting Point: Not available.
Autoignition Temperature: Not applicable.
Flash Point: -25 deg C ( -13.00 deg F)
Explosion Limits, lower: 2.00 vol %
Explosion Limits, upper: 6.10 vol %
Decomposition Temperature:
Solubility in water: Insoluble.
Specific Gravity/Density: 0.7100 g/cm3
Molecular Formula: C6H10
Molecular Weight: 82.13
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable at room temperature in closed containers under normal storage
and handling conditions.
Conditions to Avoid:
Incompatible materials, ignition sources, excess heat, strong
oxidants.
Incompatibilities with Other Materials:
Oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, irritating and toxic fumes and gases, carbon
dioxide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 592-45-0 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
1,4-Hexadiene -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: HEXADIENE
Hazard Class: 3
UN Number: 2458
Packing Group: II
IMO
Shipping Name: HEXADIENES
Hazard Class: 3.1
UN Number: 2458
Packing Group: II
RID/ADR
Shipping Name: HEXADIENES
Hazard Class: 3
UN Number: 2458
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI F
Risk Phrases:
R 11 Highly flammable.
R 36/37 Irritating to eyes and respiratory system.
Safety Phrases:
S 16 Keep away from sources of ignition - No
smoking.
WGK (Water Danger/Protection)
CAS# 592-45-0: No information available.
Canada
CAS# 592-45-0 is listed on Canada's NDSL List.
CAS# 592-45-0 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 592-45-0 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/02/1997 Revision #5 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Diethylbenzene (Mixture of 1,2-1,3-and 1,4-Isomers, Sum Min. 95%)
| 25340-17-4 |
|
5-Ethyl-2-thiophenecarboxaldehyde, 98+%
| 36880-33-8 |
|
4-Amino-Heptafluorotoluene, 95% (GC)
| 0-00-1 |
|
Flavone, 99+% (TLC)
| 525-82-6 |
|
4-Bromo-1-Chloro-2-Fluorobenzene, 98+%
| 60811-18-9 |
|
2,6-Dibromoaniline, 97%
| 608-30-0 |
|
4-Epi-Oxytetracycline,"can be used as Secondary Standard"
| 35259-39-3 |
|
Polyvinylsulfuric acid potassium salt, 90% (elem.analysis, c, h, k
| 26837-42-3 |
|
1,8-Naphthalimide, 94%(tlc)
| 81-83-4 |
|
4-Bromo-1,1,2-trifluoro-1-butene
| 10493-44-4 |
|
Diethyl Sebacate, 90% (gc)
| 110-40-7 |
|
trans-3-Hexen-1-ol, 95% (gc)
| 928-97-2 |
|
Resorufin (pract)
| 635-78-9 |
|
Adenosine 5'-Monophosphate, 99%
| 61-19-8 |
|
l-(+)-Norleucine, 99+%
| 327-57-1 |
|
3,4-Difluoronitrobenzene, 99%
| 369-34-6 |
|
2-Ethylthiophene, 99%
| 872-55-9 |
|
Adenosine-2'-Monophosphate Hemihydrate, 99%
| 81012-86-4 |
|
Exton Albumin Reagent
| 97-05-2 |
|
n-Butylurea 99%
| 592-31-4 |
|
2,2-Dimethyl-4-ethenyl-1,3-dioxolane
| 83968-02-9 |
|
N-Methylbenzothiazole-2-Thione, 99%
| 2254-94-6 |
|
Pyrimidine, 99%
| 289-95-2 |
|
Palladium on 1/8" Alumina Pellets (0.5% Pd)
| 1314-08-5 |
|
Dimethyl (2-oxoheptyl)-phosphonate, 98%
| 36969-89-8 |
|
Trimethylacetyl chloride, 99%
| 3282-30-2 |
|
2-Cyclopenten-1-one ethylene ketal, 95%
| 695-56-7 |
|
Tetrazolium violet, 98+%
| 1719-71-7 |
|
2-Bromo-4-Fluorobenzoic acid, 98%
| 1006-41-3 |
|
5-Sulfoisophthalic acid monolithium salt, 98%
| 46728-75-0 |
|
Anhydrochlortetracycline Hydrochloride can be used as Secondary
| 4497-08-9 |
|
3-(Chlorosulfonyl)benzoic acid,98% (titr.)
| 4025-64-3 |
|
Tripiperidinophosphine oxide, 98%
| 4441-17-2 |
|
2,3,3-Trichlorotetrahydro-2H-Pyran, 97+%
| 0-00-1 |
|
1-Methoxy-2-Indanol, 98%
| 56175-44-1 |
|
4'-Methylacetophenone, 95%
| 122-00-9 |
|
1,4-Hexadiene (mixture of cis and trans), 99%
| 592-45-0 |
|
2-Nitrobenzenesulfonyl chloride, 94%
| 1694-92-4 |
|
2-Nitrophenyl-2-acetamido-2-deoxy-alpha-d- glucopyranoside, 99+%
| 10139-01-2 |
|
Phenyl chlorothionocarbonate, 99%
| 1005-56-7 |
|
5-Aminoorotic Acid, 99%
| 7164-43-4 |
|
L-(+)-alpha-Phenylglycine, 99%
| 2935-35-5 |
|
P-Phenylenedipropionic Acid, 98%
| 4251-21-2 |
|
2-(4-Chlorophenyl)-2-Methylpropionic Acid, 98%
| 6247-28-5 |
|
Cyclohexyl Isocyanate, 98%
| 3173-53-3 |
|
4-(Trifluoromethoxy)benzyl bromide, 99+%
| 50824-05-0 |
|
1,3-Diiodobenzene
| 626-00-6 |
|
Trimethyl borate, 99%
| 121-43-7 |
|
Trifluoroacetic acid, silver salt, 98%
| 2966-50-9 |
|
3-Nitro-2-pentanol, 99%
| 5447-99-4 |
|
|