**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
|----------------|--------------------------------------|----------|-----------|
| 1314-08-5 |Palladiummonoxide | | 215-218-3 |
|----------------|--------------------------------------|----------|-----------|
| 1344-28-1 |Aluminum oxide | Balance | 215-691-6 |
|----------------|--------------------------------------|----------|-----------|
| 7440-05-3 |Palladium | 0.5 | 231-115-6 |
+----------------+--------------------------------------+----------+-----------+
Text for R-phrases: see Section 16
Hazard Symbols: None Listed.
Risk Phrases: None Listed.
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Hygroscopic (absorbs moisture from the air).The toxicological
properties of this material have not been fully investigated.
Potential Health Effects
Eye:
Dust may cause mechanical irritation. Causes redness and pain.
Skin:
Dust may cause mechanical irritation. May cause skin sensitization,
an allergic reaction, which becomes evident upon re-exposure to this
material. May cause contact dermatitis.
Ingestion:
Ingestion of large amounts may cause gastrointestinal irritation.
May cause bone marrow damage. Aluminum may be readily absorbed from
the gastrointestinal tract.
Inhalation:
Dust is irritating to the respiratory tract. May cause chemical
bronchitis with coughing and difficulty in breathing. May cause lung
damage.
Chronic:
Chronic inhalation of fine dusts may cause lung damage. Animal
studies have reported the development of tumors. Chronic ingestion of
aluminum oxide may produce loss of appetite, hemolysis, renal
deposition and bone marrow damage
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Immediately flush skin with plenty of water for at
least 15 minutes while removing contaminated clothing and shoes.
Wash clothing before reuse.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical
aid. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
Deferoxamine has been used to treat dialysis encephalopathy and
osteomalacia and used to diagnose aluminum related osteodystrophy.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Dust can be
an explosion hazard when exposed to heat or flame. This material in
sufficient quantity and reduced particle size is capable of creating
a dust explosion.
Extinguishing Media:
Use extinguishing media most appropriate for the surrounding fire.
Use water spray, dry chemical, carbon dioxide, or appropriate foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Reduce airborne dust and prevent scattering by moistening with
water. Clean up spills immediately, observing precautions in the
Protective Equipment section. Sweep up, then place into a suitable
container for disposal. Avoid generating dusty conditions. Provide
ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use only in a well-ventilated area. Minimize dust
generation and accumulation. Avoid breathing dust, vapor, mist, or
gas. Avoid contact with eyes, skin, and clothing. Keep container
tightly closed. Avoid ingestion and inhalation.
Storage:
Keep container closed when not in use. Store in a tightly closed
container. Store in a cool, dry, well-ventilated area away from
incompatible substances. Store protected from moisture.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
If user operations generate dust, fume, or mist, use ventilation to
keep exposure to airborne contaminants below the exposure limits.
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Wet processing methods
may be used to reduce dust generation.
Exposure Limits
CAS# 1314-08-5:
CAS# 1344-28-1:
United States OSHA: 15 mg/m3 TWA (total dust); 5 mg/m3 TWA
(respirable fraction)
Belgium - TWA: 10 mg/m3 VLE (as Al)
France - VME: 10 mg/m3 VME
Japan: 0.5 mg/m3 OEL (respirable dust); 2 mg/m3 OEL (total dust)
Malaysia: 10 mg/m3 TWA (particulate matter containing no asbestos
<1% crystalline sili
Netherlands: 10 mg/m3 MAC
Spain: 10 mg/m3 VLA-ED
CAS# 7440-05-3:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Pellets
Color: grey
Odor: None reported.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: 2000 deg C
Solubility in water: insoluble
Specific Gravity/Density:
Molecular Formula: Not applicable.
Molecular Weight: 106.42
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures. Volatile at high
temperatures.
Conditions to Avoid:
Incompatible materials, dust generation, excess heat, strong
oxidants, exposure to moist air or water.
Incompatibilities with Other Materials:
Strong oxidizing agents, strong acids, strong bases, alcohols,
chlorine trifluoride, ethylene oxide, halocarbons, halogens, oxygen
difluoride, phosphorus, sodium nitrate, sulfur, vinyl acetate,
hydrogen peroxides, sodium tetrahydroborate, arsenic, isopropyl
alcohol, heat, moisture, hydrogen bromide gas, formic acid.
Hazardous Decomposition Products:
Hydrogen chloride, phosgene, oxides of sulfur, oxides of phosphorus,
irritating and toxic fumes and gases, hydrogen gas, aluminum fumes.
Hazardous Polymerization: Will not occur.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 1314-08-5 unlisted.
CAS# 1344-28-1: BD1200000
CAS# 7440-05-3: RT3480500 RT3593400
LD50/LC50:
Not available.
Not available.
Not available.
Carcinogenicity:
Palladiummonoxide -
Not listed by ACGIH, IARC, or NTP.
Aluminum oxide -
Not listed by ACGIH, IARC, or NTP.
Palladium -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 1314-08-5: 1
CAS# 1344-28-1: 0
CAS# 7440-05-3: 0
Canada
CAS# 1314-08-5 is listed on Canada's DSL List.
CAS# 1344-28-1 is listed on Canada's DSL List.
CAS# 7440-05-3 is listed on Canada's DSL List.
CAS# 1314-08-5 is not listed on Canada's Ingredient Disclosure List.
CAS# 1344-28-1 is listed on Canada's Ingredient Disclosure List.
CAS# 7440-05-3 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 1314-08-5 is listed on the TSCA inventory.
CAS# 1344-28-1 is listed on the TSCA inventory.
CAS# 7440-05-3 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
Text for R-phrases from Section 2
MSDS Creation Date: 8/12/1998 Revision #3 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
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