**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 50824-05-0 |4-(Trifluoromethoxy)benzyl bromide | 99+ | unlisted |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: C
Risk Phrases: 34
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Causes burns.Corrosive.Moisture sensitive.Lachrymator (substance
which increases the flow of tears).
Potential Health Effects
Eye:
Causes eye burns. Lachrymator (substance which increases the flow
of tears). May cause chemical conjunctivitis and corneal damage.
Skin:
Causes skin burns. May cause skin rash (in milder cases), and cold
and clammy skin with cyanosis or pale color.
Ingestion:
May cause severe and permanent damage to the digestive tract. Causes
gastrointestinal tract burns. May cause perforation of the digestive
tract. May cause systemic effects.
Inhalation:
Causes chemical burns to the respiratory tract. Inhalation may be
fatal as a result of spasm, inflammation, edema of the larynx and
bronchi, chemical pneumonitis and pulmonary edema. May cause
systemic effects. May cause burning sensation, coughing, wheezing,
laryngitis, shortness of breath, headache, nausea, and vomiting.
Chronic:
Effects may be delayed.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately. Do NOT allow victim to rub eyes or keep eyes closed.
Extensive irrigation with water is required (at least 30 minutes).
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes. Wash clothing before reuse. Destroy contaminated shoes.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid immediately. Do NOT induce vomiting. If conscious and alert,
rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If breathing is difficult, give oxygen. Do not use
mouth-to-mouth resuscitation if victim ingested or inhaled the
substance; induce artificial respiration with the aid of a pocket
mask equipped with a one-way valve or other proper respiratory
medical device.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Vapors may
be heavier than air. They can spread along the ground and collect
in low or confined areas.
Extinguishing Media:
In case of fire, use water, dry chemical, chemical foam, or
alcohol-resistant foam. Do NOT get water inside containers.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Clean up spills immediately, observing precautions in the Protective
Equipment section. Cover with sand, dry lime or soda ash and place in
a closed container for disposal. Provide ventilation. Do not get
water inside containers.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use only in a well-ventilated area. Do not get in
eyes, on skin, or on clothing. Keep container tightly closed. Do not
ingest or inhale. Do not allow contact with water. Use only in a
chemical fume hood. Discard contaminated shoes. Keep from contact
with moist air and steam.
Storage:
Store in a cool, dry, well-ventilated area away from incompatible
substances. Corrosives area. Keep containers tightly closed. Store
protected from moisture.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 50824-05-0:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Clear liquid
Color: clear faint yellow
Odor: None reported.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 82.0 - 84.0 deg C @ 10.00mmHg
Freezing/Melting Point: Not available.
Autoignition Temperature: Not applicable.
Flash Point: 94 deg C ( 201.20 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: Not available.
Solubility in water: Not available.
Specific Gravity/Density: 1.5838g/cm3
Molecular Formula: C8H6BrF3O
Molecular Weight: 255.03
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures. Moisture sensitive.
Conditions to Avoid:
Incompatible materials, moisture, strong oxidants.
Incompatibilities with Other Materials:
Strong oxidizing agents, strong bases, moisture.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide, hydrogen fluoride gas, hydrogen
bromide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 50824-05-0 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
4-(Trifluoromethoxy)benzyl bromide -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S.*
Hazard Class: 8
UN Number: 3265
Packing Group: III
IMO
Shipping Name: CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S.
Hazard Class: 8
UN Number: 3265
Packing Group: III
RID/ADR
Shipping Name: CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S.
Hazard Class: 8
UN Number: 3265
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 34 Causes burns.
Safety Phrases:
S 25 Avoid contact with eyes.
S 28A After contact with skin, wash immediately with
plenty of water.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
WGK (Water Danger/Protection)
CAS# 50824-05-0: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 50824-05-0 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 50824-05-0 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/02/1997 Revision #5 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Diethylbenzene (Mixture of 1,2-1,3-and 1,4-Isomers, Sum Min. 95%)
| 25340-17-4 |
|
5-Ethyl-2-thiophenecarboxaldehyde, 98+%
| 36880-33-8 |
|
4-Amino-Heptafluorotoluene, 95% (GC)
| 0-00-1 |
|
Flavone, 99+% (TLC)
| 525-82-6 |
|
4-Bromo-1-Chloro-2-Fluorobenzene, 98+%
| 60811-18-9 |
|
2,6-Dibromoaniline, 97%
| 608-30-0 |
|
4-Epi-Oxytetracycline,"can be used as Secondary Standard"
| 35259-39-3 |
|
Polyvinylsulfuric acid potassium salt, 90% (elem.analysis, c, h, k
| 26837-42-3 |
|
1,8-Naphthalimide, 94%(tlc)
| 81-83-4 |
|
4-Bromo-1,1,2-trifluoro-1-butene
| 10493-44-4 |
|
Diethyl Sebacate, 90% (gc)
| 110-40-7 |
|
trans-3-Hexen-1-ol, 95% (gc)
| 928-97-2 |
|
Resorufin (pract)
| 635-78-9 |
|
Adenosine 5'-Monophosphate, 99%
| 61-19-8 |
|
l-(+)-Norleucine, 99+%
| 327-57-1 |
|
3,4-Difluoronitrobenzene, 99%
| 369-34-6 |
|
2-Ethylthiophene, 99%
| 872-55-9 |
|
Adenosine-2'-Monophosphate Hemihydrate, 99%
| 81012-86-4 |
|
Exton Albumin Reagent
| 97-05-2 |
|
n-Butylurea 99%
| 592-31-4 |
|
2,2-Dimethyl-4-ethenyl-1,3-dioxolane
| 83968-02-9 |
|
N-Methylbenzothiazole-2-Thione, 99%
| 2254-94-6 |
|
Pyrimidine, 99%
| 289-95-2 |
|
Palladium on 1/8" Alumina Pellets (0.5% Pd)
| 1314-08-5 |
|
Dimethyl (2-oxoheptyl)-phosphonate, 98%
| 36969-89-8 |
|
Trimethylacetyl chloride, 99%
| 3282-30-2 |
|
2-Cyclopenten-1-one ethylene ketal, 95%
| 695-56-7 |
|
Tetrazolium violet, 98+%
| 1719-71-7 |
|
2-Bromo-4-Fluorobenzoic acid, 98%
| 1006-41-3 |
|
5-Sulfoisophthalic acid monolithium salt, 98%
| 46728-75-0 |
|
Anhydrochlortetracycline Hydrochloride can be used as Secondary
| 4497-08-9 |
|
3-(Chlorosulfonyl)benzoic acid,98% (titr.)
| 4025-64-3 |
|
Tripiperidinophosphine oxide, 98%
| 4441-17-2 |
|
2,3,3-Trichlorotetrahydro-2H-Pyran, 97+%
| 0-00-1 |
|
1-Methoxy-2-Indanol, 98%
| 56175-44-1 |
|
4'-Methylacetophenone, 95%
| 122-00-9 |
|
1,4-Hexadiene (mixture of cis and trans), 99%
| 592-45-0 |
|
2-Nitrobenzenesulfonyl chloride, 94%
| 1694-92-4 |
|
2-Nitrophenyl-2-acetamido-2-deoxy-alpha-d- glucopyranoside, 99+%
| 10139-01-2 |
|
Phenyl chlorothionocarbonate, 99%
| 1005-56-7 |
|
5-Aminoorotic Acid, 99%
| 7164-43-4 |
|
L-(+)-alpha-Phenylglycine, 99%
| 2935-35-5 |
|
P-Phenylenedipropionic Acid, 98%
| 4251-21-2 |
|
2-(4-Chlorophenyl)-2-Methylpropionic Acid, 98%
| 6247-28-5 |
|
Cyclohexyl Isocyanate, 98%
| 3173-53-3 |
|
4-(Trifluoromethoxy)benzyl bromide, 99+%
| 50824-05-0 |
|
1,3-Diiodobenzene
| 626-00-6 |
|
Trimethyl borate, 99%
| 121-43-7 |
|
Trifluoroacetic acid, silver salt, 98%
| 2966-50-9 |
|
3-Nitro-2-pentanol, 99%
| 5447-99-4 |
|
|